Preparation method of special antibacterial wool fiber for wool hat
A wool fiber and hat technology, which is applied in the field of preparation of antibacterial wool fiber for wool hats, can solve the problems of easy breeding of bacteria, threats to human health and the environment, and the lack of antibacterial function of wool
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Embodiment 1
[0020] A kind of preparation method of special antibacterial wool fiber for wool hat proposed by the present invention comprises the following steps:
[0021] S1, soak the wool fiber in acetone, dry it after washing, then add in the mixed aqueous solution of sodium cyanate and hydrogen peroxide, dry it after soaking, then carry out ultraviolet light irradiation treatment to get the pretreated wool fiber;
[0022] S2. Add thiourea, urea, and butyl titanate to absolute ethanol and mix evenly, adjust the pH value to 2, add deionized water and stir until the Tyndall effect appears, let stand and age for 2 hours, dry and grind at 550°C Calcined at low temperature for 2 hours to obtain modified nano-titanium dioxide; add chitosan to acetic acid aqueous solution, adjust the pH value to 2, add modified nano-titanium dioxide, adjust the pH value of the system to 11 after stirring evenly, heat up to 75 ° C, add glutaraldehyde, After static reaction for 3 hours, modified chitosan was obt...
Embodiment 2
[0026] A kind of preparation method of special antibacterial wool fiber for wool hat proposed by the present invention comprises the following steps:
[0027] S1, soak the wool fiber in acetone, dry it after washing, then add in the mixed aqueous solution of sodium cyanate and hydrogen peroxide, dry it after soaking, then carry out ultraviolet light irradiation treatment to get the pretreated wool fiber;
[0028] S2. Add thiourea, urea, and butyl titanate to absolute ethanol and mix evenly, adjust the pH value to 3, add deionized water and stir until the Tyndall effect appears, leave it to age for 4 hours, dry and grind at 500°C Calcined at low temperature for 3 hours to obtain modified nano-titanium dioxide; add chitosan to acetic acid aqueous solution, adjust the pH value to 1, add modified nano-titanium dioxide, adjust the pH value of the system to 12 after stirring evenly, raise the temperature to 65 ° C, add glutaraldehyde, After static reaction for 5 hours, modified chit...
Embodiment 3
[0032] A kind of preparation method of special antibacterial wool fiber for wool hat proposed by the present invention comprises the following steps:
[0033] S1. Immerse the wool fiber in acetone, dry it after washing, then add the mixed aqueous solution of sodium cyanate and hydrogen peroxide, dry it after soaking, and then perform ultraviolet light irradiation treatment to obtain pretreated wool fiber; wherein, cyanide In the mixed aqueous solution of sodium cyanate and hydrogen peroxide, the mass concentration of sodium cyanate is 3.5g / L, and the mass concentration of hydrogen peroxide is 1.5g / L; In the process of ultraviolet light irradiation treatment, the intensity of ultraviolet light is 1500mW / cm 2 , the irradiation time is 60min;
[0034] S2. Add thiourea, urea, and butyl titanate to absolute ethanol and mix evenly, wherein the weight ratio of thiourea, urea, and butyl titanate is 12:25:120, adjust the pH to 3, and add deionized Stir with water until the Tyndall e...
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