Preparation method and application method of high niobium-titanium-aluminum based porous composite filter membrane
A porous composite material, high niobium titanium aluminum technology, applied in the fields of filtration treatment, chemical instruments and methods, water/sludge/sewage treatment, etc. Wide range, improved processing efficiency, good repeatability
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Embodiment 1
[0035] (1) Titanium, aluminum, and niobium powders weighed according to the atomic ratio of 44:48:6 are mixed and then added with 1-8wt% nanometer silicon dioxide / zirconia / yttrium trioxide / magnesia / zinc oxide Nano zirconia, then put the mixed powder into the ball mill, add appropriate amount of small steel balls, control the speed of the ball mill to 120rpm, and the mixing time is 24h, fully mix the blended powder.
[0036] (2) After mixing the raw material powder evenly, press the powder by molding method. The specific implementation method is: take out 4-8g of the blended powder and carry out compression molding. The pressing pressure is 20-40 tons, and finally a film with good shape is obtained. compact.
[0037] (3) Perform a three-stage sintering process on the pressed film, and control the heating rate to prevent cracking and deformation of the sample. The entire process uses a tantalum heating furnace for vacuum sintering to ensure as little oxygen as possible in the fu...
Embodiment 2
[0043] (1) Titanium powder and niobium powder weighed according to the ratio of atomic ratio 8:1, after mixing, add 1-8wt% nanometer silicon dioxide / zirconia / yttrium trioxide / magnesia / zinc oxide nanometer Zirconia, and then put the mixed powder into the ball mill, add an appropriate amount of small steel balls, control the speed of the ball mill to 50-200rpm, and the mixing time is 10-48h to fully mix and blend the powder.
[0044] (2) After the raw material powder is mixed evenly, the mixed powder is evenly sprayed onto a 0.15cm thick aluminum foil by cold spraying method, and the thickness of the sprayed mixed powder is controlled by controlling the spraying time.
[0045] (3) A three-stage sintering process is carried out on the above-mentioned prepared samples, and the heating rate is controlled to prevent cracking and deformation of the samples. The whole process uses a tantalum heating furnace for vacuum sintering to ensure as little oxygen as possible in the furnace cavi...
Embodiment 3
[0050] (1) According to the titanium powder and niobium powder weighed according to the ratio of atomic ratio 45:6, after mixing, add 1-8wt% nano silicon dioxide / zirconia / yttrium trioxide / magnesia / zinc oxide nano Zirconium dioxide, then put the mixed powder into a ball mill, add an appropriate amount of small steel balls, control the speed of the ball mill to 120rpm, and the mixing time is 24h, and fully mix and blend the powder.
[0051] (2) After the raw material powder is mixed evenly, the mixed powder is evenly sprayed onto a 0.2 cm thick aluminum foil by chemical vapor deposition, and the deposition thickness is controlled by controlling the deposition time.
[0052] (3) A three-stage sintering process is carried out on the above-mentioned prepared samples, and the heating rate is controlled to prevent cracking and deformation of the samples. The whole process uses a tantalum heating furnace for vacuum sintering to ensure as little oxygen as possible in the furnace cavity....
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Abstract
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