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Preparation method and application method of high niobium-titanium-aluminum based porous composite filter membrane

A porous composite material, high niobium titanium aluminum technology, applied in the fields of filtration treatment, chemical instruments and methods, water/sludge/sewage treatment, etc. Wide range, improved processing efficiency, good repeatability

Active Publication Date: 2018-05-18
UNIV OF SCI & TECH BEIJING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the function of the product has been greatly improved after modification with nanomaterials, these nanomaterials modified with various functional groups will be directly exposed to air, water and soil in large quantities after use, thus entering the biological chain and finally entering the human body , destroy human organs and cause human death
[0003] However, since nano-pollution is a newly proposed new concept, its risk to environmental safety has not yet attracted great attention from all walks of life.
At present, the combination of physical sedimentation and chemical flocculation sedimentation is mainly used to remove nano-pollutants in water, but the efficiency is low, and a large amount of chemical reagents are required, and the application cost is too high
In addition, at present, nano-pollution is not yet used as a pollutant discharge indicator, so whether the discharged treated water contains nano-materials is not taken seriously.

Method used

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  • Preparation method and application method of high niobium-titanium-aluminum based porous composite filter membrane
  • Preparation method and application method of high niobium-titanium-aluminum based porous composite filter membrane
  • Preparation method and application method of high niobium-titanium-aluminum based porous composite filter membrane

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] (1) Titanium, aluminum, and niobium powders weighed according to the atomic ratio of 44:48:6 are mixed and then added with 1-8wt% nanometer silicon dioxide / zirconia / yttrium trioxide / magnesia / zinc oxide Nano zirconia, then put the mixed powder into the ball mill, add appropriate amount of small steel balls, control the speed of the ball mill to 120rpm, and the mixing time is 24h, fully mix the blended powder.

[0036] (2) After mixing the raw material powder evenly, press the powder by molding method. The specific implementation method is: take out 4-8g of the blended powder and carry out compression molding. The pressing pressure is 20-40 tons, and finally a film with good shape is obtained. compact.

[0037] (3) Perform a three-stage sintering process on the pressed film, and control the heating rate to prevent cracking and deformation of the sample. The entire process uses a tantalum heating furnace for vacuum sintering to ensure as little oxygen as possible in the fu...

Embodiment 2

[0043] (1) Titanium powder and niobium powder weighed according to the ratio of atomic ratio 8:1, after mixing, add 1-8wt% nanometer silicon dioxide / zirconia / yttrium trioxide / magnesia / zinc oxide nanometer Zirconia, and then put the mixed powder into the ball mill, add an appropriate amount of small steel balls, control the speed of the ball mill to 50-200rpm, and the mixing time is 10-48h to fully mix and blend the powder.

[0044] (2) After the raw material powder is mixed evenly, the mixed powder is evenly sprayed onto a 0.15cm thick aluminum foil by cold spraying method, and the thickness of the sprayed mixed powder is controlled by controlling the spraying time.

[0045] (3) A three-stage sintering process is carried out on the above-mentioned prepared samples, and the heating rate is controlled to prevent cracking and deformation of the samples. The whole process uses a tantalum heating furnace for vacuum sintering to ensure as little oxygen as possible in the furnace cavi...

Embodiment 3

[0050] (1) According to the titanium powder and niobium powder weighed according to the ratio of atomic ratio 45:6, after mixing, add 1-8wt% nano silicon dioxide / zirconia / yttrium trioxide / magnesia / zinc oxide nano Zirconium dioxide, then put the mixed powder into a ball mill, add an appropriate amount of small steel balls, control the speed of the ball mill to 120rpm, and the mixing time is 24h, and fully mix and blend the powder.

[0051] (2) After the raw material powder is mixed evenly, the mixed powder is evenly sprayed onto a 0.2 cm thick aluminum foil by chemical vapor deposition, and the deposition thickness is controlled by controlling the deposition time.

[0052] (3) A three-stage sintering process is carried out on the above-mentioned prepared samples, and the heating rate is controlled to prevent cracking and deformation of the samples. The whole process uses a tantalum heating furnace for vacuum sintering to ensure as little oxygen as possible in the furnace cavity....

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Abstract

The invention discloses a preparation method and an application method of a high niobium-titanium-aluminum based porous composite filter membrane and belongs to the field of water pollution control. According to the preparation method and the application method, by controlling a sintering temperature of a blended powder of titanium, aluminum, niobium and a nanometer oxide, the chemical reaction iscontrolled, and thus controllable equipment a series of composite membranes is realized; as for the composite membranes, as multiple nanometer pore canals and bulges are constructed on the surface ofan original matrix, and when a certain external pressure is applied to the original matrix, the nanometer pore canals and the bulges greatly hinder nanometer pollutants from passing through the composite membranes, and water molecules can penetrate through the composite membranes through deformation; and the high niobium-titanium-aluminum based porous composite filter membrane can remarkably improve the treatment efficiency of the nanometer pollutants and is hopeful to be widely applied to the field of sewage treatment. According to the technical scheme of the invention, the high niobium-titanium-aluminum based porous composite filter membrane is novel and reasonable in design, good in repeatability and very wide in application range of the nanometer pollutants which can be treated.

Description

technical field [0001] The invention belongs to the field of water pollution prevention and control, and in particular relates to a preparation and application method of a high-niobium-titanium-aluminum-based porous composite filter membrane. Background technique [0002] Nanopollutants are a general term for harmful substances produced during the manufacture or use of nanomaterials. Usually we refer to materials with a particle size between 0.1 and 100 nm as nanomaterials, which is roughly equivalent to the scale where 10 to 100 atoms are closely arranged together. Due to the five unique properties of nanoparticles, such as small size effect, surface effect, quantum size effect, macroscopic quantum tunneling effect, and dielectric confinement effect, the properties of nanomaterials in terms of melting point, vapor pressure, optical properties, chemical reactivity, magnetism, Nanotechnology is called the most promising technology in the 21st century because of its unique ph...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B22F1/00B22F3/11C02F1/00C02F1/44
CPCB22F1/0003B22F3/11C02F1/001C02F1/44
Inventor 林均品桂万元梁永锋刘梦迪
Owner UNIV OF SCI & TECH BEIJING