Refining agent for waste aluminum to improve performance of aluminum castings

A technology of refining agent and aluminum casting, which is applied in the field of refining agent for waste aluminum, can solve the problems of inability to obtain chemical composition, high proportion of oxide impurities, and affecting the performance of aluminum castings, so as to shorten refining time, increase mechanical properties, reduce micro porosity effect

Inactive Publication Date: 2018-06-19
安徽玉成光华铝业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The secondary aluminum industry has become an indispensable and important part of the development of the aluminum industry. Nearly 12 million tons of various aluminum scraps are processed into secondary aluminum alloys every year in the world, and the technology for preparing high-performance aluminum alloys from secondary aluminum is aluminum processing. Technological progress is inevitable. The biggest technical obstacle in the production of high-performance products from waste aluminum is the inability to obtain suitable chemical components. The raw materials of different aluminum alloys are effectively classified. Even the imported waste aluminum raw materials are also a mixture of raw materials with different chemical components. At the same time, there are many combinations of iron, copper and other metals in the recycled aluminum alloy parts or It is a composite product, so most of the waste aluminum raw materials contain high content of non-aluminum elements, such as the content of iron usually reaches 0.8%, the content of silicon reaches 4%, and the content of copper exceeds 1%. Therefore, according to the conventional production process After smelting, ingot casting and deformation processing, it is difficult to produce aluminum alloy products whose chemical composition meets the standard requirements from waste aluminum raw materials. Covering agents, slag-removing agents, slag-removing agents, refining agents, etc. are needed in the aluminum alloy smelting process. When the temperature of aluminum reaches 720°C, a refining agent needs to be added. The refining agent used in the traditional scrap aluminum manufacturing process will cause the porosity of the finished product to be high, and pores will be generated on the surface of the casting, and the proportion of oxide impurities is also high, which affects Properties of Aluminum Castings

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0011] A refining agent for waste aluminum that improves the performance of aluminum castings, comprising the following raw materials in parts by weight: 4 parts of modified graphene, 8 parts of nano-calcium nitride, 3 parts of titanium dioxide, 2 parts of ammonium fluoroborate, and 1.2 parts of hematilite powder part, 0.6 part of alumina, 0.2 part of sulfur, 5 parts of hydrogen-type mordenite powder, and 0.2 part of magnesium aluminum silicate; wherein the modified graphene is modified by 2-hydroxypropyltrimethylammonium chloride chitosan Modified agent obtained.

[0012] Wherein, the hematilite powder is obtained from calcium nitrate and zinc nitrate modified zeolite powder; the mass ratio of hydrogen-type mordenite powder silica / alumina is 22.3, the specific surface area is 514M² / G, sodium oxide - 10 m, the water content at absorption balance is 14.7wt%; the preparation method of the refining agent is, after mixing the raw materials, ball milling for 8 minutes under a nitro...

Embodiment 2

[0015] A refining agent for waste aluminum that improves the performance of aluminum castings, comprising the following raw materials in parts by weight: 3 parts of modified graphene, 6 parts of nano-calcium nitride, 2 parts of titanium dioxide, 3 parts of ammonium fluoroborate, and 0.8 parts of hematilite powder part, 0.4 part of alumina, 0.1 part of sulfur, 6 parts of hydrogen-type mordenite powder, and 0.1 part of magnesium aluminum silicate; wherein the modified graphene is modified by 2-hydroxypropyltrimethylammonium chloride chitosan Modified agent obtained.

[0016] Wherein, the hematilite powder is obtained from calcium nitrate and zinc nitrate modified zeolite powder; the mass ratio of hydrogen-type mordenite powder silica / alumina is 22.3, the specific surface area is 514M² / G, sodium oxide - 10 m, the water content at absorption equilibrium is 14.7wt%; the preparation method of the refining agent is, after mixing the raw materials, ball milling for 10 minutes under a ...

Embodiment 3

[0019] A refining agent for waste aluminum to improve the performance of aluminum castings, comprising the following raw materials in parts by weight: 6 parts of modified graphene, 10 parts of nano-calcium nitride, 4 parts of titanium dioxide, 1 part of ammonium fluoroborate, and 1.6 parts of hematilite powder part, 0.8 part of alumina, 0.3 part of sulfur, 4 parts of hydrogen-type mordenite powder, and 0.3 part of magnesium aluminum silicate; wherein the modified graphene is modified by 2-hydroxypropyltrimethylammonium chloride chitosan Modified agent obtained.

[0020] Wherein, the hematilite powder is obtained from calcium nitrate and zinc nitrate modified zeolite powder; the mass ratio of hydrogen-type mordenite powder silica / alumina is 22.3, the specific surface area is 514M² / G, sodium oxide - 10 m, the water content at absorption equilibrium is 14.7wt%; the preparation method of the refining agent is as follows: after mixing the raw materials, they are ball milled for 6 m...

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Abstract

The invention belongs to the technical field of waste aluminum smelting refining agents, and particularly relates to a refining agent for waste aluminum to improve the performance of aluminum castings. The refining agent comprises, by weight, 3-6 parts of modified graphite, 6-10 parts of nanometer calcium nitride, 2-4 parts of titanium dioxide, 1-3 parts of ammonium tetraborate, 0.8-1.6 parts of stellerite powders, 0.4-0.8 parts of aluminum oxide, 0.1-0.3 parts of sulphur, 4-6 parts of H-mordenite powders, and 0.1-0.3 parts of aluminum magnesium silicate; the modified graphite is modified by 2-hydroxypropyltrimethyl ammonium chloride chitosan as a modifying agent. Compared with the prior art, the refining agent for the waste aluminum to improve the performance of the aluminum castings hasthe advantages that the refining agent can obtain high-quality waste aluminum alloy molten fluid and reduce the microporosity of the obtained castings, and mechanical properties of the refining agentcan also be increased significantly.

Description

technical field [0001] The invention belongs to the technical field of refining agents for smelting waste aluminum, and in particular relates to a refining agent for waste aluminum that improves the performance of aluminum castings. Background technique [0002] The secondary aluminum industry has become an indispensable and important part of the development of the aluminum industry. Nearly 12 million tons of various aluminum scraps are processed into secondary aluminum alloys every year in the world, and the technology for preparing high-performance aluminum alloys from secondary aluminum is aluminum processing. Technological progress is inevitable. The biggest technical obstacle in the production of high-performance products from waste aluminum is the inability to obtain suitable chemical components. The raw materials of different aluminum alloys are effectively classified. Even the imported waste aluminum raw materials are also a mixture of raw materials with different ch...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C1/06C22C1/02C22C21/00C22B21/06C22B9/10
CPCC22C1/06C22B9/10C22B21/06C22C1/026C22C21/00
Inventor 何启华
Owner 安徽玉成光华铝业有限公司
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