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Low-foam type glufosinate ammonium auxiliary agent and preparation technology thereof

A technology of glufosinate adjuvant and fatty acyldiethanolamine phosphate, which is applied in the direction of herbicides, algicides, biocides, biocides, etc., can solve the problems of long drug effect time, achieve significant adhesion performance, increase Good adhesion time and long-lasting effect

Inactive Publication Date: 2018-09-04
江苏凯元科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In view of the good application prospects of glufosinate-ammonium pesticides, it is also very important to study its important component-adjuvant; the adjuvant itself has no biological activity, but it is an indispensable and important component in the formulation or application process; the adjuvant The role of the auxiliaries is to improve the physical and chemical properties of the pesticides, which can exert the efficacy of the pesticides to a large extent or provide safer and more efficient construction methods; The direction of serialization is developed to meet the needs of processing different formulations of pesticide varieties; among them, the tackifier is an additive that can increase the adhesion of glufosinate-ammonium to solid surfaces, improve the ability of pesticides to resist washing by rain, and improve the lasting effect. property; at present, the drug effect time of glufosinate-ammonium sold on the market is not too long, therefore, it is very necessary to research and invent an auxiliary agent that can improve drug effect and prolong drug effect time

Method used

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  • Low-foam type glufosinate ammonium auxiliary agent and preparation technology thereof

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Experimental program
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preparation example Construction

[0018] A kind of preparation technology of low-foaming type glufosinate adjuvant mainly comprises the following steps:

[0019] Step 1. Add deionized water into the reactor, start stirring, add weighed fatty alcohol polyoxyethylene ether and coconut oil fatty acyldiethanolamine phosphate, stir and heat to 60°C to obtain material a;

[0020] Step 2, adding methyl stearate polyoxyethylene ether, heating and stirring to obtain material b;

[0021] Step 3: Add disodium cocoyl monoethanolamide sulfosuccinate monosodium DMSS and PEG (polyethylene glycol), make up deionized water, and stir evenly to obtain a low-foaming glufosinate additive.

[0022] The present invention has implementation:

Embodiment 1

[0024] Take the following weight materials: the first step, add deionized water to the reaction kettle, start stirring, add 8% fatty alcohol polyoxyethylene ether and 10% coconut oil fatty acyldiethanolamine phosphate, stir and heat to 60°C; in the second step, add 25% of methyl stearate polyoxyethylene ether, heat and stir uniformly; in the third step, add 5% of cocoic acid monoethanolamide sulfosuccinic acid monosodium disodium DMSS, After adding 1% polyethylene glycol, make up deionized water and stir evenly.

[0025] pH measurement method:

[0026] Weigh 1.0 g of the product of Example 1 and put it into a beaker, add deionized water to 100 g, stir evenly, and measure the pH value with a pH meter.

[0027] Viscosity determination method:

[0028] Equipment: rotational viscometer; the liquid to be measured is placed in a beaker or a straight container with a diameter of not less than 70 mm, the temperature of the liquid to be measured is accurately controlled, and the prot...

Embodiment 2

[0033]Take the following weight materials: the first step, add deionized water to the reaction kettle, start stirring, add 10% fatty alcohol polyoxyethylene ether and 12% coconut oil fatty acyldiethanolamine phosphate, stir and heat to 60°C; in the second step, add 30% methyl stearate polyoxyethylene ether, heat and stir evenly; in the third step, add 8% cocoic acid monoethanolamide sulfosuccinic acid monosodium disodium DMSS, After adding 1% polyethylene glycol, add deionized water and stir evenly.

[0034] The pH value of the low-foaming glufosinate adjuvant prepared by this formula was measured to be 5.6, the viscosity to be 375mPa.s, and the surface tension to be 16.1mN / m.

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Abstract

The invention discloses a low-foam type glufosinate ammonium auxiliary agent and a preparation technology thereof. The low-foam type glufosinate ammonium auxiliary agent is prepared from the followingsubstances in percentage by mass: 5 to 20 percent of fatty alcohol polyoxyethylene ether, 5 to 15 percent of coconut oil fatty acyl diethanol amine phosphate, 20 to 50 percent of methyl stearate polyoxyethylene ether, 1 to 20 percent of disodium cocoyl monoethanolamide sulfosuccinate DMSS, 1 to 5 percent of PEG (Polyethylene Glycol) and the balance of de-ionized water; reasonable ratios and a reasonable preparation method are adopted, and surfactants with different functional groups including carboxyl, an ether group and the like are compounded under the condition that an original function ofherbicide is not damaged, and are concatenated at the optimal ratio, so that each surfactant can play a role better under the action of other surfactants; the attachment time of glufosinate ammoniumon crops can be prolonged, and the low-foam type glufosinate ammonium auxiliary agent has good permeation, wetting, adhesion and emulsification capabilities, a strong rainwater washing resisting capability and the like.

Description

technical field [0001] The invention relates to the technical field of herbicide auxiliaries, in particular to a low-foaming glufosinate adjuvant with strong rain washing resistance and good long-lasting effect and a preparation process thereof. Background technique [0002] Glufosinate-ammonium is a non-conductive herbicide with high efficiency, low toxicity, and environmental friendliness. It is easy to degrade in the soil, safe for crops, not easy to drift, has a wide herbicidal spectrum, high activity, and low dosage, which is environmentally friendly. The pressure is low, and it is the second largest herbicide-tolerant genetically modified crop in the world after glyphosate; especially with the rapid development of genetically modified technology, the planting of genetically modified herbicide-resistant crops has intensified this year, and the use of herbicide-tolerant Substantial increase; glufosinate-ammonium is an excellent killing herbicide, very suitable for resist...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A01N25/30A01N57/20A01P13/00
CPCA01N25/30A01N57/20
Inventor 刘阳生朱极何华雄展红明
Owner 江苏凯元科技有限公司
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