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Epitaxial wafer manufacturing method and epitaxial wafer

A manufacturing method and wafer technology, applied in semiconductor/solid-state device manufacturing, electrical components, circuits, etc., can solve problems such as the occurrence of particles, the reduction of oxygen precipitates, and the increase of workload.

Active Publication Date: 2021-10-22
SUMCO CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] However, in the case of external gettering, there are problems such as an increase in cost due to an increase in the number of steps, and appearance of particles from the portion where distortion is applied, warping of the wafer due to processing, etc.
Intrinsic gettering, on the other hand, requires the presence of some degree of oxygen, but this may create defects that are detrimental to the formation of power devices
In addition, heat treatment is required to effectively make the groove, which also increases the workload
In addition, in the case of an epitaxial wafer, in the process of forming the epitaxial layer, it becomes a high temperature of 1050 to 1200°C, so the oxygen precipitates that should have become nuclei of micro defects in the wafer substrate will shrink and disappear, making it difficult to Grooves are formed in the subsequent heat treatment
Therefore, existing methods for intrinsic gettering cannot be effectively utilized

Method used

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  • Epitaxial wafer manufacturing method and epitaxial wafer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] In order to examine the effect of nitrogen doping, the following two experiments were carried out. The conditions for single crystal growth were as follows: 50 kg of high-purity polycrystalline silicon was melted in a quartz crucible, boron was used as a dopant, and the pulling speed of a single crystal with a diameter of 150 mm and a crystal orientation was set to 0.6 mm / min.

[0057] First of all, in the first step, in order to highlight the effect of nitrogen addition, when the single crystal grows to the bottom right 300mm stage, nitrogen flow is put into the furnace at 10L / min to continue growing in this state, and increase the nitrogen in the single crystal. Next, in order to easily estimate the amount of nitrogen doping, nitrogen is not added in the form of gas during pulling, but the silicon wafer with a clear amount of nitrogen to form the nitride film is melted together with high-purity polysilicon as the raw material to grow nitrogen. Doping amount is 10 12...

Embodiment 2

[0062] In Example 1, for slave doping with 10 14 atoms / cm 3 The epitaxial layer with a thickness of about 5 μm was formed at a deposition temperature of 1150° C. on a wafer obtained from a single crystal of nitrogen. The obtained wafer test piece was subjected to selective etching for 5 minutes using a photoetching solution, and the defect density on the surface of the epitaxial layer and the defect density on the cross section were measured with an optical microscope.

[0063] image 3 , shows the results of density measurement of surface and cross-sectional defects at positions in the direction from the center of the test piece toward the outer periphery. According to this, it can be seen that after the epitaxial layer is formed on the wafer made of the single crystal doped with nitrogen, the cross section of the single crystal in the lower layer has been observed 10 4 piece / cm 2 It has been confirmed that oxygen precipitates do not easily disappear even when a high-temp...

Embodiment 3

[0065] Taking two types of p-type wafer substrates with a resistivity of 10Ωcm or 0.008Ωcm, high resistance or low resistance, respectively, a single crystal undoped with nitrogen and doped with 10 12 、10 13 or 10 14 atoms / cm 3 Eight kinds of single crystals of nitrogen were cut out from wafer substrates, and an epitaxial layer with a thickness of 5 μm was formed at a deposition temperature of 1150° C. to form an epitaxial wafer.

[0066] At 3ppm Cu(NO 3 ) 2 After contaminating the surface of these wafers with a spin coater in an aqueous solution, a model heat treatment assumed in the power device manufacturing process was performed in dry oxygen, and changes in the gettering effect accompanying the heat treatment were investigated.

[0067] Figure 4 Indicates the temperature and time conditions of the pattern heat treatment. In the process shown in the figure, the wafer was taken out at three time points shown as A, B, and C, and the effect of gettering accompanying th...

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Abstract

The invention provides a method that can exert the gettering ability brought by crystal defects and has a defect density of 10 on the surface of the epitaxial layer. 2 piece / cm 2 The following epitaxial wafer manufacturing method. The manufacturing method of this epitaxial wafer is characterized in that it includes: a single crystal silicon growth step, and grows a doped silicon crystal by the Czochralski single crystal pulling method 11 atoms / cm 3 ~4.5×10 15 atoms / cm 3 single crystal silicon of nitrogen; a single crystal silicon cutting process, cutting out a silicon wafer from the single crystal silicon; and an epitaxial layer forming process, using the above silicon wafer as a substrate, and forming a single crystal silicon on the substrate by vapor phase growth The epitaxial layer is an epitaxial layer, and the epitaxial layer is formed at a temperature ranging from 1050° C. to 1200° C. in the step of forming the epitaxial layer.

Description

technical field [0001] The invention of the present application relates to a method for manufacturing a high-quality wafer with a low surface defect density, that is, an epitaxial wafer, and the epitaxial wafer. Background technique [0002] With the popularization of portable communication terminals including smart phones, the integration and high density of integrated circuit components (power devices) of silicon semiconductors is increasing year by year, and the quality requirements for silicon wafers forming power devices are becoming more and more stringent. . That is, as circuits become thinner with higher integration densities, in the so-called power device active regions where power devices are formed using wafers, changes that cause increases in leakage current and shorten the lifetime of carriers are more strictly restricted than before. Impurities such as crystal defects and metal-based elements other than dopants. [0003] Conventionally, a substrate (wafer) cu...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L21/02H01L21/322
CPCH01L21/02381H01L21/3221
Inventor 浅山英一宝来正隆村上浩纪久保高行
Owner SUMCO CORP
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