The invention relates to a two-step diffusion pretreatment method for casting single-crystal or polycrystal silicon wafers, which comprises the following steps of A, pickling, B, depositing PSG at high temperature, C, primary impurity removal, D, depositing PSG at low temperature, and E, secondary impurity removal. The invention aims to provide a two-step diffusion pretreatment method for casting single-crystal or polycrystalline silicon wafers, which is suitable for effective passivation of the cast single-crystal or polycrystalline silicon wafer, and can reduce defect density in and on the surface of the silicon wafer, reduce recombination of current carriers, improve passivation level and transmission level of the current carriers, therefore, solar cell production can be carried out on the cast single-crystal or polycrystal silicon wafer according to the existing high-efficiency cell piece manufacturing process, and high cell conversion efficiency is obtained.