The invention relates to a
diffusion technology adopted in the process of manufacturing a physical
metallurgical silicon solar cell, in particular to a
diffusion technology for prolonging the minority
carrier lifetime of a
metallurgical silicon wafer. The
diffusion technology is characterized by comprising the following steps: (1) propelling a
quartz boat at the low temperature and raising the temperature preliminarily; (2) introducing
nitrogen carried with
phosphorus oxychloride and diffusing generated
phosphorus atoms; (3) advancing at the constant temperature; (4) cooling and withdrawing the
quartz boat. The technology has the benefits as follows: 1, spraying type diffusion is adopted, so as to save the
phosphorus source as well as improve the uniformity of diffusion
junction depth, and the technology is suitable for high
sheet resistance; 2, according to the characteristics of physical
metallurgical silicon, two-sided phosphorus is adopted in gettering to enhance the gettering effect and prolong the minority
carrier lifetime of the
silicon wafer; 3, the diffusion technology is effectively improved via the coordination of temperature and time; 4, the proportions of introduced
oxygen and introduced
raw material are controlled to reduce the defects caused by direct diffusion and improve the
junction depth of a PN junction, the surface
passivation effect can be further improved, and the short-circuit current and the open-circuit
voltage are increased, so that the conversion efficiency and the yield of the metallurgical
silicon solar cell are further improved.