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A kind of preparation method of glass fiber sizing agent

The technology of glass fiber and sizing agent is applied in the field of preparation of glass fiber sizing agent, which can solve the problems of reducing the economic benefit of glass fiber, sticking filaments of spools, and easily damaged fibers, etc., and achieves uniform adsorption surface and lower surface energy. , the effect of easy adsorption

Active Publication Date: 2021-03-30
九江鑫星玻纤材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the sizing agent used for 7781# glass fiber cloth generally adopts epoxy aqueous solution series, and the lubricant is in the form of emulsion. This kind of sizing agent is easy to cause the line wheel to stick to the original wire during the wire drawing process, resulting in high shutdown rate and easy fiber damage. Disadvantages, which reduce the economic benefits of glass fiber producers

Method used

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  • A kind of preparation method of glass fiber sizing agent

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A preparation method of glass fiber sizing, the specific steps are as follows:

[0021] Step 1, configure the hydrolysis solution: Stir the glacial acetic acid and soft water evenly to obtain the hydrolysis solution. The mass ratio of glacial acetic acid and soft water is 1.6:997;

[0022] Step 2, configure the dispersion: add r-methacryloxypropyltrimethoxysilane to the hydrolysis solution and ultrasonically oscillate evenly, the quality of r-methacryloxypropyltrimethoxysilane and hydrolysis solution The ratio is 2.3:995, obtains dispersion liquid;

[0023] Step 3, configure the lubricant liquid: mix soft water, disodium ethoxylated alcohol sulfosuccinate, polyethylene glycol and cationic film according to the mass ratio of 86:2.6:3.8:6.6 and stir evenly at a speed of 120rpm to obtain a lubricant liquid;

[0024] Step 4, configure the mixed solution: add the binder, lubricant liquid, antistatic agent and epoxy emulsion to the dispersion in turn and stir for 36 minutes...

Embodiment 2

[0027] A preparation method of glass fiber sizing, the specific steps are as follows:

[0028] Step 1, configure the hydrolysis solution: Stir the glacial acetic acid and soft water evenly to obtain the hydrolysis solution, the mass ratio of glacial acetic acid and soft water is 1:499;

[0029] Step 2, configure the dispersion: add the coupling agent to the hydrolysis solution and oscillate uniformly, the power of the ultrasonic oscillation is 175W, the frequency of the ultrasonic oscillation is 38KHz, the mass ratio of the coupling agent to the hydrolysis solution is 3:997, and the obtained Dispersions;

[0030] Step 3, configure the lubricant liquid: mix soft water, disodium ethoxylated alcohol sulfosuccinate, polyethylene glycol and cationic film according to the mass ratio of 89:3:4:7 and stir evenly at a speed of 135rpm to obtain a lubricant liquid;

[0031] Step 4, configure the mixed solution: add vinyl acetate-acrylate, lubricant liquid, lithium chloride and bispheno...

Embodiment 3

[0038] A preparation method of glass fiber sizing, the specific steps are as follows:

[0039] Step 1, configure the hydrolysis solution: Stir the glacial acetic acid and soft water evenly to obtain the hydrolysis solution. The mass ratio of glacial acetic acid and soft water is 3:999;

[0040] Step 2, configure the dispersion: add r-methacryloxypropyltrimethoxysilane to the hydrolysis solution and oscillate evenly with ultrasonic waves. The power of ultrasonic oscillations is 190W, and the frequency of ultrasonic oscillations is 36-40KHz. The mass ratio of acryloyloxypropyltrimethoxysilane and the hydrolysis solution is 4.5:998 to obtain a dispersion;

[0041] Step 3, configure the lubricant liquid: mix soft water, disodium ethoxylated alcohol sulfosuccinate, polyethylene glycol and cationic film according to the mass ratio of 91:3.5:4.4:7.5 and stir at a speed of 90rpm to obtain a lubricant liquid;

[0042] Step 4, configure the mixed solution: add vinyl acetate-acrylate, ...

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Abstract

The invention discloses a preparation method of a glass fiber impregnating agent. The method includes the following specific steps of 1, preparing a hydrolysis solution; 2, preparing a dispersion liquid; 3, preparing a lubricant liquid; 4, preparing a mixed solution, wherein a bonding agent, the lubricant liquid, an antistatic agent and an epoxy emulsion are sequentially added into the dispersionliquid and stirred; 5, conducting dilution and homogenizing, wherein the mixed solution is added into soft water to obtain a diluent, and the diluent is placed in a homogenizer for being stirred and refined uniformly to obtain a finished product. The lubricant is processed from an emulsion to the liquid and then added, an active water molecule additive is added into the impregnating agent, and thesolution is added into the homogenizer, so that the effect of adjusting the performance of epoxy aqueous solution series is achieved, the surface energy of an interface between glass fiber monofilaments and the impregnating agent is reduced, the adsorption of the raw filaments is easier in an impregnating process, the adsorption surface is more uniform, the disadvantages of high shutdown rate andeasy damage of fibers are avoided, and economic benefits of a producer can be increased.

Description

technical field [0001] The invention relates to the field of glass fiber production, in particular to a preparation method of a glass fiber sizing agent. Background technique [0002] Glass fiber is an inorganic non-metallic material with superior performance. Glass fiber products have excellent strength, rigidity, portability, corrosion resistance, durability, weather resistance and other characteristics. It is made of glass balls or waste glass. Manufactured by high-temperature melting, wire drawing, winding, weaving and other processes, the diameter of its single filament is several microns to more than 20 microns, which is equivalent to 1 / 20-1 / 5 of a hair. Fiber precursors are composed of hundreds or even thousands of monofilaments, and are widely used in construction, transportation, electronics, electrical, chemical metallurgy, environmental protection, national defense and other fields. Sizing agents are a key factor in the production of these products. [0003] At ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C25/465C03C25/36
CPCC03C25/36C03C25/465
Inventor 刘敏奕周威
Owner 九江鑫星玻纤材料有限公司
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