Modified composition of corrosion-resistant sealing ring and preparation method thereof
A sealing ring and corrosion-resistant technology, which is applied in the field of modified compositions for corrosion-resistant sealing rings and its preparation, can solve the problems that the corrosion resistance of seals is difficult to meet the above requirements, and the sealing rings are difficult to satisfy acid resistance or alkali resistance at the same time, etc. To achieve the effect of simple process, improved corrosion resistance and easy availability of raw materials
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[0013] The invention provides a method for preparing a modified composition of a corrosion-resistant sealing ring, the preparation method comprising:
[0014] 1) Contact reaction of carbon fiber, cyclodextrin, silane coupling agent and water, and then filter and dry the filter cake to obtain modified carbon fiber;
[0015] 2) Perform hydrothermal reaction of modified carbon fiber, silver salt, zinc salt, urea and water, then filter to take filter cake, and finally calcine in the presence of protective gas to obtain composite carbon fiber;
[0016] 3) Mix composite carbon fibers, shell powder, attapulgite, silicon carbide, and rare earth oxides to prepare a modified composition for corrosion-resistant sealing rings.
[0017] In step 1) of the present invention, the amount of each material can be selected within a wide range, but in order to make the modified composition further improve the corrosion resistance of the sealing ring, preferably, in step 1), carbon fiber, The weig...
Embodiment 1
[0031] 1) Contact reaction of carbon fiber, cyclodextrin, silane coupling agent (vinyltriethoxysilane) and water in a weight ratio of 30:13:8:100 (reaction temperature is 70°C, reaction time is 4h) , and then filtered to take the filter cake and dry it (drying temperature is 110°C, drying time is 5h) to obtain modified carbon fiber;
[0032] 2) The modified carbon fiber, silver salt (silver nitrate), zinc salt (zinc nitrate), urea and water are subjected to hydrothermal reaction according to the weight ratio of 50:7:13:18:280 (reaction temperature is 170°C, The reaction time is 12h), then filter to take the filter cake, and finally calcine in the presence of protective gas (helium) (from 20°C at 4.8°C / min to 380°C and keep it for 40min, then at 1.8°C / min to cool down to 260°C and heat preservation for 1.8h, and finally naturally cooled to 18°C) to obtain composite carbon fibers;
[0033] 3) Mix composite carbon fiber, shell powder, attapulgite, silicon carbide, and rare earth...
Embodiment 2
[0035] 1) Contact reaction of carbon fiber, cyclodextrin, silane coupling agent (vinyltrimethoxysilane) and water according to the weight ratio of 30:10:5:80 (reaction temperature is 65°C, reaction time is 5h), Then filter the filter cake and dry it (drying temperature is 100°C, drying time is 6h) to obtain modified carbon fiber;
[0036] 2) The modified carbon fiber, silver salt (silver nitrate), zinc salt (zinc chloride), urea and water are subjected to hydrothermal reaction according to the weight ratio of 50:5:10:15:200 (the reaction temperature is 160°C , the reaction time is 16h), then filter to take the filter cake, and finally calcine in the presence of protective gas (nitrogen) (from 15°C at 4.5°C / min to 350°C and keep it for 30min, then at 1.5°C / min to cool down to 200°C and heat preservation for 1.5h, and finally naturally cooled to 15°C) to obtain composite carbon fibers;
[0037] 3) Mix composite carbon fiber, shell powder, attapulgite, silicon carbide, and rare ...
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