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Ceramic glaze and porcelain

A technology for ceramic glaze and raw materials, applied in the field of ceramics, can solve the problems of short service life of porcelain, not smooth glaze surface, easy cracking of the glaze surface, etc., and achieve the effect of natural and beautiful surface texture, smooth and flat glaze surface, and not easy to crack.

Inactive Publication Date: 2019-01-01
中山市大盛文化传播有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among the ceramic products currently on the market, many of them have the problem that the glaze is easy to crack. The main reason is that the glaze is not smooth enough and the modulus of rupture is low. Many small micro-cracks and pits were found, because these micro-cracks and pits will gradually develop into larger cracks during the use of the porcelain, resulting in a shorter service life and lower economic value of these porcelains

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] The raw material ratio of ceramic glaze is as follows by mass: glass powder 43%, calcined zinc oxide 16%, quartz 11%, titanium dioxide 8%, talcum powder 3.7%, 8# frit 0.28%, copper oxide 3%, oxide 1% iron, 4% manganese oxide, 0.02% methyl cellulose, 4% potassium feldspar, 6% glaze mud, and the glaze mud is black mud.

[0015] The process steps of adopting the present embodiment to make porcelain are:

[0016] (1) Get china clay to make mud base and dry the mud base;

[0017] (2) The mass ratio of water and ceramic glaze is 0.57-0.65:1, water is mixed with ceramic glaze, and ground to obtain glaze slurry;

[0018] (3) filter the glaze slurry, and sieve out the particles therein;

[0019] (4) Spraying the filtered glaze slurry onto the dried mud body to obtain the porcelain body;

[0020] (5) Put the porcelain body into the kiln for stage-by-stage firing. The first stage: Leave a gap of 3 to 5 cm on the kiln cover, open the chimney on the top of the kiln, and use oxida...

Embodiment 2

[0026] The raw material ratio of ceramic glaze is as follows by mass: glass powder 32%, calcined zinc oxide 26%, quartz 10%, titanium dioxide 14%, talcum powder 4%, 8# frit 0.37%, copper oxide 2%, oxide Iron 0.6%, manganese oxide 2.5%, methyl cellulose 0.03%, potassium feldspar 3%, glaze mud 5.5%, described glaze mud is the mixture of black mud and bentonite, and the mass ratio of black mud and bentonite is 1:1. The process steps of making porcelain in this embodiment are the same as in Embodiment 1.

[0027] After firing the porcelain in this embodiment, the Mohs hardness of the glaze is 5, and the modulus of rupture reaches 85.3 MPa. When the glaze is observed under a microscope with a power of 200 times, the crystal pattern of the glaze is intact and there are almost no microcracks.

Embodiment 3

[0029] The raw material ratio of ceramic glaze is as follows by mass: glass powder 31%, calcined zinc oxide 21%, quartz 18%, titanium dioxide 10%, talcum powder 3%, 8# frit 0.2%, copper oxide 2.4%, oxide Iron 0.7%, manganese oxide 3%, methyl cellulose 0.03%, potassium feldspar 3.3%, glaze mud 5%, bovine bone ash 0.8%, lion mountain ash 0.25%, vanadium pentoxide 0.05%, barium carbonate 0.02% , zirconium silicate 0.05%, star vermilion 0.7%, straw ash 0.5%, and the described glaze mud is black mud. The process steps of making porcelain in this embodiment are the same as in Embodiment 1.

[0030] After the porcelain in this embodiment is fired and molded, the glazed surface is observed under a microscope at 200 times, and the crystal flower on the glazed surface is intact, with almost no microcracks; the Mohs hardness of the glazed surface reaches 7, and the modulus of rupture is 71.9MPa, and the implementation Compared with Example 1 and Example 2, the hardness is significantly ...

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Abstract

The invention discloses a ceramic glaze and porcelain prepared by using the same. The ceramic glaze is prepared from the following raw materials in percentage by mass: 31-43 percent of glass powder, 16-26 percent of zinc oxide, 10-18 percent of quartz, 7-14 percent of titanium dioxide, 3-6 percent of talcum powder, 0.2-0.5 percent of frit, 1.5-3 percent of copper oxide, 0.6-1.5 percent of ferric oxide, 2.5-4 percent of manganese oxide, 0.02-0.04 percent of methylcellulose, 2-4 percent of potassium feldspar and 5-7 percent of mud for glaze, wherein the mud for glaze is black clay, bentonite ora mixture of the black clay and the bentonite. For the porcelain prepared by sintering by adopting a formula provided by the invention, the glaze surface is smooth and flat, and the textures on the surface are natural and beautiful; by observing the glaze surface under a 200 power microscope, the glaze surface is perfect in crystal flower without a microcrack nearly, has the Moh's hardness of 5-7and the rupture modulus capable of reaching 85.3 MPa and is difficult to crack, and the porcelain has a relatively long service life and a relatively high economic value.

Description

technical field [0001] The invention relates to the technical field of ceramics, in particular to a ceramic glaze and porcelain made using the ceramic glaze. Background technique [0002] As an important category of inorganic non-metallic materials, ceramic materials have achieved great development. Structural ceramics are widely used in the fields of metallurgy, mining and aerospace due to their high mechanical strength, high hardness, corrosion resistance and other advantages. Among the ceramic products currently on the market, many of them have the problem that the glaze is easy to crack. The main reason is that the glaze is not smooth enough and the modulus of rupture is low. Many small micro-cracks and pits were found, because these micro-cracks and pits will gradually develop into larger cracks during the use of porcelain, resulting in a shorter service life and lower economic value of these porcelains. Contents of the invention [0003] In view of this, it is nece...

Claims

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Application Information

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IPC IPC(8): C03C8/20C04B41/86
CPCC03C8/20C04B41/5022C04B41/86C04B41/4539C04B41/0072
Inventor 崔俊谭来辉唐子龙
Owner 中山市大盛文化传播有限公司