Cable material for new energy automobile and preparation method of cable material
A new energy vehicle and cable technology, which is applied in the field of new energy vehicle cable materials and its preparation, can solve the problems of high surface hardness, poor aging resistance, and difficult processing and molding, and achieve good performance stability, good weather resistance, Effects that are not highly dependent on the device
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Embodiment 1
[0027] A preparation method for a cable material for a new energy vehicle, comprising the steps of:
[0028] ⅠDissolve 10g of 1-methallyl-2-(2-hydroxy-5-methylphenyl)benzothiazole, 1510g of quaternary ammonium salt, and 20g of acrylonitrile in 150g of dimethyl sulfoxide, and add Add 0.3 g of azobisisobutyronitrile, stir and react under a nitrogen atmosphere at 60°C for 4 hours, then precipitate in water, wash the precipitated polymer with ether for 4 times, and dry in a vacuum oven at 75°C for 18 Hour, obtain benzotriazole-based polyolefin;
[0029] Ⅱ Add 13.8g of 4,4'-diaminostilbene-2,2'-disulfonic acid, 10g of 9-fluorenone-2,7-dicarboxylic acid, 2-(7-benzotriazole oxide) -N,N,N',N'-tetramethylurea hexafluorophosphate 4g, N,N-diisopropylethylamine 2g, 4-dimethylaminopyridine 2g were dissolved in dimethyl sulfoxide 100g to form a solution , then put the solution into the reaction kettle, replace the air in the kettle with nitrogen, react at 80°C for 2 hours under normal pre...
Embodiment 2
[0033] A preparation method for a cable material for a new energy vehicle, comprising the steps of:
[0034] ⅠDissolve 1-methallyl-2-(2-hydroxyl-5-methylphenyl)benzothiazole 10g, quaternary ammonium salt-1510g, and acrylonitrile 20g in 170g of N-methylpyrrolidone, and add to Add 0.35 g of azobisisoheptanonitrile, stir and react for 5 hours under a helium atmosphere at 65°C, then precipitate in water, wash the precipitated polymer with ether for 5 times, and then place it in a vacuum oven at 78°C Bake for 20 hours to obtain benzotriazole-based polyolefin;
[0035]Ⅱ Add 13.8g of 4,4'-diaminostilbene-2,2'-disulfonic acid, 10g of 9-fluorenone-2,7-dicarboxylic acid, 2-(7-benzotriazole oxide) -N,N,N',N'-tetramethylurea hexafluorophosphate 4.5g, N,N-diisopropylethylamine 2.3g, 4-dimethylaminopyridine 2g dissolved in dimethyl sulfoxide 125g Form a solution, then add the solution to the reaction kettle, replace the air in the kettle with nitrogen, react at 83°C for 2.3 hours under no...
Embodiment 3
[0039] A preparation method for a cable material for a new energy vehicle, comprising the steps of:
[0040] ⅠDissolve 10g of 1-methallyl-2-(2-hydroxy-5-methylphenyl)benzothiazole, 1510g of quaternary ammonium salt, and 20g of acrylonitrile in 180g of N,N-dimethylformamide 0.4 g of azobisisobutyronitrile was added thereto, stirred and reacted for 5 hours in a neon atmosphere at 70°C, and then precipitated in water, and the precipitated polymer was washed 6 times with diethyl ether, and then placed in an 80°C Bake in a vacuum oven for 21 hours to obtain a benzotriazole-based polyolefin;
[0041] Ⅱ Add 13.8g of 4,4'-diaminostilbene-2,2'-disulfonic acid, 10g of 9-fluorenone-2,7-dicarboxylic acid, 2-(7-benzotriazole oxide) -N,N,N',N'-tetramethylurea hexafluorophosphate 5g, N,N-diisopropylethylamine 2.6g, 4-dimethylaminopyridine 2g dissolved in dimethyl sulfoxide 140g to form Solution, then add the solution into the reaction kettle, replace the air in the kettle with nitrogen, re...
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