Azo pigment, colorant for color filter, coloring composition for color filter, and color filter

A color filter and coloring composition technology, applied in the field of color filters, can solve the problems of insufficient brightness, poor spectral shape, and low spectral transmittance, and achieve good storage stability and fastness Excellent, low stain migration effect

Active Publication Date: 2022-05-13
TOYO INK SC HOLD CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, because the spectral transmittance of C.I. Pigment Red 177 is lower than that of C.I. Pigment Red 254, the spectral shape is not good, so there is a disadvantage that the brightness will decrease with the addition of C.I. Pigment Red 177
However, the methods of Patent Documents 1 to 3 cannot obtain sufficient brightness, and further improvement is required.

Method used

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  • Azo pigment, colorant for color filter, coloring composition for color filter, and color filter
  • Azo pigment, colorant for color filter, coloring composition for color filter, and color filter
  • Azo pigment, colorant for color filter, coloring composition for color filter, and color filter

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0315] (Manufacture of Azo Pigment 1)

[0316]

[0317] After adding 185 parts of base compound [B-1] to 1500 parts of N-methylpyrrolidone, 294 parts of 35% hydrochloric acid were added, and it cooled to -2-0 degreeC. After adding 208 parts of 25% sodium nitrite aqueous solution to this solution, it stirred for 30 minutes, maintaining at 0-5 degreeC, and prepared the diazonium solution. Separately, a coupling agent solution composed of 167 parts of coupling agent compound [C-1], 316 parts of 25% sodium hydroxide solution, and 1500 parts of methanol was prepared. The prepared diazonium solution and coupling agent solution were dropped into 1000 parts of acetic acid buffer solution of pH 5.4 at the same time for 10 minutes. After the dropwise addition was completed, after stirring at room temperature for 30 minutes, further, while maintaining stirring at 80° C., the precipitated reactant was filtered off, washed with hot water, and dried to obtain 343 parts of azo pigment 1 ...

Embodiment 2

[0321] (Manufacture of Azo Pigment 2)

[0322] In place of 185 parts of the basic compound [B-1] used in the production of the azo pigment 1, 169 parts of the basic compound [B-2] were used, and the same operation as the production of the azo pigment 1 was performed. , 337 parts of Azo Pigment 2 were obtained (yield: 98.1%). Based on the results of TOF-MS mass spectrometry and elemental analysis, it was identified as azo pigment 2.

[0323] Azo Pigment 2

[0324]

Embodiment 3

[0326] (Manufacture of Azo Pigment 3)

[0327] In place of 185 parts of the basic compound [B-1] used in the production of the azo pigment 1, 210 parts of the basic compound [B-3] were used, and the same operation as the production of the azo pigment 1 was performed. , 371 parts of Azo Pigment 3 were obtained (yield: 96.7%). Based on the results of TOF-MS mass spectrometry and elemental analysis, it was identified as azo pigment 3.

[0328] Azo Pigment 3

[0329]

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Abstract

The object of the present invention is to provide a coloring composition for color filters, which not only has excellent fastness such as heat resistance and light resistance, has less foreign matter in the coating film, and has good storage stability, but also has high brightness and contrast, and expresses The film thickness becomes thinner for the same color. The aforementioned problems are solved by an azo pigment composed of a compound represented by the following general formula (1) or (2). In general formula (1), R 1 represents a halogen atom, an optionally substituted alkyl group, an optionally substituted alkoxy group, or an optionally substituted aryloxy group. R 2 and R 3 Each independently represents a hydrogen atom, an alkyl group which may have a substituent, or a phenyl group which may have a substituent. x 1 ~X 4 independently represent a hydrogen atom, an alkyl group that may have a substituent, an alkoxy group that may have a substituent, a hydroxyl group, a cyano group, a nitro group, a carboxyl group, a sulfo group or a halogen atom,

Description

technical field [0001] The present invention relates to a colorant for color filters (Color Filter) used in the manufacture of color filters used in color liquid crystal display devices and color solid-state imaging devices, etc., a coloring composition, and a color filter formed using the same . Background technique [0002] A liquid crystal display device is a display device in which a liquid crystal layer sandwiched between two polarizers adjusts the degree of polarization of light transmitted through the first polarizer and controls the amount of light transmitted through the second polarizer to display. As a mainstream liquid crystal display device, a twisted nematic (TN) type liquid crystal is used. Another representative method of liquid crystal display devices is the in-plane switching (In-Plane Switching, IPS) method in which a pair of electrodes are provided on a substrate on one side and an electric field is applied in a direction parallel to the substrate, so th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09B33/147G02B5/20G03F7/004
CPCG03F7/004G02B5/20C09B33/147C09B35/035G03F7/0007G03F7/032G03F7/105G03F7/027
Inventor 阿部悠太坂本昌平清水宏明平佐美幸齐藤纱也佳
Owner TOYO INK SC HOLD CO LTD
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