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Method for producing long-chain dicarboxylic acid by continuous fermentation

A technology of long-chain dibasic acid and dibasic acid, which is applied in the field of continuous fermentation to produce long-chain dibasic acid, which can solve the problems of increasing the risk of bacterial contamination and increasing costs, and achieves increased yield, guaranteed continuous production, and increased yield Effect

Pending Publication Date: 2019-06-11
CATHAY R&D CENT CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the patent CN201510802343.4 discloses a method and device for continuous fermentation to produce long-chain dibasic acids, the fermentation liquid not only needs to add a membrane filtration device but also be coupled with the seed tank, and the continuous fermentation can be realized by regularly replenishing fresh seed liquid process, which not only increases the cost, but also increases the risk of contamination

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] Seed medium: 3.0% sucrose, 0.60% corn steep liquor, 1.0% yeast extract, KH 2 PO 4 1.2%, urea 0.30%.

[0054] Fermentation medium: glucose 3.0%, corn steep liquor 0.60%, yeast extract 0.30%, potassium nitrate 1.1%, potassium dihydrogen phosphate 0.80%, urea 0.20%, ammonium sulfate 0.15% and sodium chloride 0.10%.

[0055] There are two kinds of feed medium: one is carbasundecane; the other is a solution containing nutrient salt (glucose 0.2%, yeast extract 0.1%, corn steep liquor 0.15%, potassium dihydrogen phosphate 0.012%, urea 0.015%, The remainder is water; said percentage is mass-to-volume ratio, g / 100mL).

[0056] The shake flask seed cultivation process is to inoculate the glycerol tube strain of Candida tropicalis into a 500mL Erlenmeyer flask containing the seed medium (filling volume 50mL), the initial pH is 6.3, and culture at 29°C and 220rpm shaker for 1.5 days .

[0057] The seed tank culture process is to get the shake flask seeds and insert them in the...

Embodiment 2

[0070] Seed medium: 1% sucrose, 0.30% corn steep liquor, 0.6% yeast extract, KH 2 PO 4 0.8%, urea 0.25%.

[0071]Fermentation medium: 2.0% glucose, 0.20% corn steep liquor, 0.25% yeast extract, 0.05% potassium nitrate, 0.07% potassium dihydrogen phosphate, 0.15% urea, 0.20% ammonium sulfate and 0.12% sodium chloride.

[0072] There are two kinds of feeding medium: one is carbon dodecane; the other is a solution containing nutrient salt (yeast extract 0.1%, ammonium sulfate 0.05%, corn steep liquor 0.05%, potassium dihydrogen phosphate 0.008%, urea 0.01% , and the rest are water; said percentages are mass-to-volume ratios, g / 100mL).

[0073] The shaking flask seed cultivation process is to inoculate the glycerol tube strain of Candida tropicalis into a 500mL Erlenmeyer flask containing the seed medium (filling volume 60mL), the initial pH is 6.5, and culture at 32°C and 250rpm shaker for 1 day .

[0074] The seed tank culture process is to get the shake flask seeds and inse...

Embodiment 3

[0087] Seed medium: 3% sucrose, 1% corn steep liquor, 0.2% yeast extract, KH 2 PO 4 0.9%, urea 0.5%.

[0088] Fermentation medium: glucose 5%, corn steep liquor 0.7%, yeast extract 0.3%, potassium nitrate 0.55%, potassium dihydrogen phosphate 0.60%, urea 0.20%, ammonium sulfate 0.20% and sodium chloride 0.15%.

[0089] There are two kinds of feeding medium: one is carbon tridecane; the other is a solution containing nutrient salt (0.5% glucose, 0.15% ammonium sulfate, 0.10% corn steep liquor, 0.008% potassium dihydrogen phosphate, 0.007% urea, The remainder is water; said percentage is mass-to-volume ratio, g / 100mL).

[0090] The shake flask seed cultivation process is to inoculate the glycerol tube strain of Candida tropicalis into a 500mL Erlenmeyer flask containing the seed medium (filling volume 100mL), the initial pH is 6.0, and culture at 200rpm shaker at 30°C for 2 days .

[0091] The seed tank cultivation process is to get the shake flask seeds and insert them in t...

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Abstract

The invention discloses a method for producing long-chain dicarboxylic acid by continuous fermentation. After fermentation for 100-150 hours, continuous fed-batch of a substrate is carried out, and continuous fed-batch of anutrient salt-containing solution is carried out at the same time; and the dilution rate during the fermentation is 0.001-0.006 h<-1>, preferably 0.0016-0.0054 h<-1>. The methodensures the long-term activity of the thallus on the basis of not increasing any equipment, thereby ensuring the continuous production of the long-chain dicarboxylic acid, greatly increasing the productivity of the long-chain dicarboxylic acid, and increasing the yield.

Description

technical field [0001] The invention relates to a method for continuously fermenting and producing long-chain dibasic acids. Background technique [0002] Long-chain dibasic acid (LDCA, HOOC (CH 2 )nCOOH, n≥7) has a wide range of applications. It can be used as a raw material to synthesize special nylon (polyamide), high-grade spices, high-grade hot-melt adhesives, cold-resistant plasticizers, high-grade lubricating oils, high-grade antirust agents, high-grade paints and coatings Wait. [0003] Generally speaking, long-chain dibasic acids can be produced by chemical synthesis or biological fermentation. The chemical synthesis method has a long synthetic route and strict reaction conditions. It needs to be carried out under high temperature and high pressure conditions, and the catalyst requirements are relatively strict. Therefore, on an industrial scale, there are few long-chain dibasic acids synthesized by chemical methods, only dodecane A few varieties such as long-cha...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C12P7/44C12N1/16C12R1/74
Inventor 路飞徐敏刘修才
Owner CATHAY R&D CENT CO LTD