Unlock instant, AI-driven research and patent intelligence for your innovation.

A method and device for treating flue gas containing nitrogen oxides

A nitrogen oxide and flue gas technology, applied in microorganism-based methods, chemical instruments and methods, biochemical cleaning devices, etc., can solve the problems of ammonia escape, pollution, and high investment costs, achieve efficient removal, avoid poisoning, The effect of improving carbon sequestration efficiency

Active Publication Date: 2021-08-06
CHINA PETROLEUM & CHEM CORP +1
View PDF22 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the reaction still needs to be carried out at a relatively high temperature in the presence of a catalyst, and there are problems such as ammonia escape.
[0004] The flue gas denitrification processes disclosed in Chinese patents CN103768903A, CN103768932A, and CN103768934A require a flue gas temperature of 300-400°C, and large-scale transformation of the boiler requires high investment costs.
However, the catalyst prepared by the invention belongs to the vanadium-tungsten series catalyst, and ammonium metavanadate becomes V after calcining. 2 o 5 , V 2 o 5 It is a highly toxic substance that will cause serious pollution during production and use

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A method and device for treating flue gas containing nitrogen oxides
  • A method and device for treating flue gas containing nitrogen oxides
  • A method and device for treating flue gas containing nitrogen oxides

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] (1) In a 10L photobioreactor, add 6L of the prepared microalgae medium, adjust the pH of the microalgae medium to 10 with NaOH, and insert 0.9L of Chlorella kessleri FSH-Y3 seed solution for cultivation. Into the flue gas, CO in the flue gas 2 The content of NO is 5v%, the NO content is 0.03v%, and the ventilation volume is 0.5vvm. The light intensity of the culture was 5000 Lux, the culture temperature was 25 °C, the light period was 24 h, and the light-dark time ratio was 14:10. In the collected exhaust gas, CO 2 The removal rate is 85%, and the NO removal rate is 80%.

[0043] (2) After culturing for 5 days, the microalgal cells and filtrate were harvested by centrifugation. Dry cell weight and lipid content were determined. The dry weight of algal powder was measured after vacuum freeze-drying to constant weight at -60°C, the biomass yield was calculated, and the total lipid content was measured by the n-hexane:ethyl acetate method. After testing, the dry cell ...

Embodiment 2

[0046] (1) In a 10L photobioreactor, add 6L of the prepared microalgae medium, adjust the pH of the microalgae medium to 11 with NaOH, and insert 1.0L of Chlorella kessleri FSH-Y3 seed solution for cultivation. Into the flue gas, CO in the flue gas 2 The content of NO is 10v%, the NO content is 0.05v%, and the ventilation volume is 0.5vvm. The light intensity of the culture was 5000 Lux, the culture temperature was 25 °C, the light period was 24 h, and the light-dark time ratio was 14:10. CO collected in exhaust gas 2 The removal rate is 80%, and the NO removal rate is 75%.

[0047] (2) After 6 days of culture, microalgal cells and filtrate were harvested by centrifugation. Dry cell weight and lipid content were determined. The dry weight of algal powder was measured after vacuum freeze-drying to constant weight at -60°C, the biomass yield was calculated, and the total lipid content was measured by the n-hexane:ethyl acetate method. After testing, the dry cell weight can ...

Embodiment 3

[0050] (1) In a 10L photobioreactor, add 6L of the prepared microalgae medium, adjust the pH of the microalgae medium to 12 with NaOH, and insert 1.2L of Chlorella kessleri FSH-Y3 seed solution for cultivation. Into the flue gas, CO in the flue gas 2 The content of NO is 40v%, the NO content is 0.05v%, and the ventilation volume is 0.3vvm. The light intensity of the culture was 5000 Lux, the culture temperature was 25 °C, the light period was 24 h, and the light-dark time ratio was 14:10. CO collected in exhaust gas 2 The removal rate is 60%, and the NO removal rate is 75%.

[0051] (2) After 6 days of culture, microalgal cells and filtrate were harvested by centrifugation. Dry cell weight and lipid content were determined. The dry weight of algal powder was measured after vacuum freeze-drying to constant weight at -60°C, the biomass yield was calculated, and the total lipid content was measured by the n-hexane:ethyl acetate method. After testing, the cell dry weight can ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention relates to a method for treating flue gas containing nitrogen oxides. High-pH microalgae, collect exhaust gas; (2) separate solid-liquid from the culture system in step (1), harvest microalgae cells and filtrate respectively; (3 insert denitrifying bacteria in the filtrate, pass through step (1) to discharge The gas is denitrified to obtain purified gas. The present invention also provides a device for processing flue gas containing nitrogen oxides. The present invention mainly adopts a biological method to remove CO in the flue gas 2 , NO X , without the use of catalysts and a large amount of chemical reagents, it has the advantages of good removal effect, low treatment cost, economical and environmental protection.

Description

technical field [0001] The invention belongs to the technical field of flue gas treatment, and in particular relates to a method and a device for treating flue gas containing nitrogen oxides. Background technique [0002] Nitrogen oxides (NOx) have N 2 O, NO, NO 2 , N 2 O 3 , N 2 O 4 and N 2 O 5 and other forms, and can cause a variety of hazards, such as photochemical smog with volatile organic compounds (VOC) in the atmosphere, which can cause strong irritation to the eyes and throat, and cause headaches and respiratory diseases. cause death. my country's NOx emissions have exceeded 20 million tons for many consecutive years, 21.94 million tons in 2010, 24.043 million tons in 2011, 23.378 million tons in 2012, 22.273 million tons in 2013, and 20.78 million tons in 2014. It has shown a continuous downward trend since the beginning of the year, but its pollution situation is still severe. On September 12, 2014, three ministries and commissions including the National...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): B01D53/84B01D53/56B01D53/62C12N1/12C12M1/04C12P3/00C12R1/89
CPCY02P20/151Y02P20/59Y02A50/20Y02C20/40
Inventor 赵磊师文静刘洋
Owner CHINA PETROLEUM & CHEM CORP