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A kind of preparation method of papermaking sludge reuse agent

A papermaking sludge and catalyst technology, applied in sludge treatment, chemical instruments and methods, water/sludge/sewage treatment, etc., can solve the problem of solid waste polluting the environment, low interest rate of preparing sludge plates, and inability to efficiently use sewage problems such as mud, to achieve the effect of improving the utilization rate of raw materials, improving the retention rate of raw materials, and saving papermaking pulp

Active Publication Date: 2021-08-03
青岛祥泽化学科技有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] During the papermaking process, with the flow of sewage circulating water, a large amount of fine fibers, calcium carbonate, talcum powder, starch, sizing agent, etc. are lost with the water, and the lost materials will be polluted by anaerobic bacteria in the water body for a long time and become sludge , the formation of solid waste not only wastes a lot of raw materials, but also seriously pollutes the environment.
[0003] For the treatment of existing papermaking sludge, most of them adopt filter press landfill incineration or use papermaking sludge to prepare other low-interest sludge boards, etc. The treatment method of filter press landfill cannot essentially eliminate pollution, and incineration will produce A large amount of flue gas causes new pollution. The interest rate of preparing sludge plates is low and sludge cannot be used efficiently, which affects economic benefits and is not suitable for industrial production. What is more important is that the above treatment methods cannot make full use of raw materials for The purpose of making paper, saving costs and improving paper quality

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  • A kind of preparation method of papermaking sludge reuse agent
  • A kind of preparation method of papermaking sludge reuse agent
  • A kind of preparation method of papermaking sludge reuse agent

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Embodiment 1

[0034] The invention provides a preparation method of a papermaking sludge recycling agent, which specifically adopts the following steps:

[0035] (1) Mix polyvinyl alcohol and methacrylic acid with a molar ratio of 1: (1.1-1.3) and p-toluenesulfonic acid with a molar ratio of polyvinyl alcohol and methacrylic acid mixture of (0.005-0.015): 1 And stir evenly, put it in a closed container and react at 130-165°C in a nitrogen atmosphere for 2-3h, and cool down to room temperature to obtain a mixture of polyvinyl alcohol methacrylate and polyvinyl alcohol dimethacrylate;

[0036] (2) in the mixture of polyvinyl alcohol methacrylate and polyvinyl alcohol dimethacrylate gained in step (1), add excess deionized water and be (0.03 -0.05):1 cationic monomer DMC, then add acrylamide with a molar ratio of (0.02-0.03:)1 to the mixture of polyacryl alcohol and methacrylic acid, and stir the mixture evenly;

[0037] (3) Add ammonium persulfate with a molar ratio of (0.017-0.026): 1 to th...

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Abstract

The invention discloses a preparation method of papermaking sludge recycling agent, which adopts polyvinyl alcohol and methacrylic esterification reaction to generate polymer ester, and then polymerizes with cationic monomer DMC and acrylamide under the action of initiator ammonium persulfate It is a high-molecular polymer, and the surface is grafted with chitosan to obtain a recycling agent, which can efficiently recover fine fibers, calcium carbonate, talcum powder, starch, sizing agents, etc. in papermaking sludge lost with circulating water Papermaking raw materials can not only save papermaking pulp, improve the retention rate and utilization rate of raw materials and improve the quality of paper products, but also reduce the amount of sludge generated, thereby saving energy and cost of sludge treatment, which is beneficial to industrial production .

Description

technical field [0001] The invention relates to the technical field of clean production and waste treatment, in particular to a preparation method of a papermaking sludge recycling agent. Background technique [0002] During the papermaking process, with the flow of sewage circulating water, a large amount of fine fibers, calcium carbonate, talcum powder, starch, sizing agent, etc. are lost with the water, and the lost materials will be polluted by anaerobic bacteria in the water body for a long time and become sludge , the formation of solid waste not only wastes a lot of raw materials, but also seriously pollutes the environment. [0003] For the treatment of existing papermaking sludge, most of them adopt filter press landfill incineration or use papermaking sludge to prepare other low-interest sludge boards, etc. The treatment method of filter press landfill cannot essentially eliminate pollution, and incineration will produce A large amount of flue gas causes new pollu...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F11/00C08F290/12C08F220/34C08F220/56C02F103/28
CPCC02F11/00C02F2103/28C08F290/12C08F220/34C08F220/56
Inventor 刘阳杜祥森陈立莹
Owner 青岛祥泽化学科技有限公司