Preparation method of full-alkaline synthetic melamine urea-formaldehyde resin and wood impregnation method thereof
A technology for synthesizing melamine urea-formaldehyde resin and alkalinity, which can be used in wood impregnation, wood treatment, pressure impregnation, etc. It can solve the problems of limited performance improvement, unfavorable impregnation of solid wood, initial viscosity and excessive molecular weight, and achieve the effect of small molecular weight
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[0029] A kind of preparation method of all-alkaline synthetic melamine urea-formaldehyde resin dipping liquid, comprises the following steps:
[0030] S10, after mixing 900-1200 parts by weight of formaldehyde solution, 4-8 parts by weight of sodium hydroxide solution, 20-120 parts by weight of melamine and 225-500 parts by weight of urea, adjust the temperature to 60-90 ° C, React at constant temperature for 0.5-5 hours, keep the pH between 7-10;
[0031] S11, maintaining a constant temperature reaction temperature of 60-90°C, then adding 150-475 parts by weight of urea, 90-300 parts by weight of maltodextrin or polyvinyl alcohol or starch, and reacting for 0.5-5 hours;
[0032] S12, adding 10-300 parts by weight of ammonia water and 2-30 parts by weight of triethylenetetramine, stirring for 5-20 minutes, cooling down to room temperature and discharging.
[0033] As a further improvement, the concentration of the formaldehyde solution is 35-40 wt%.
[0034] As a further imp...
Embodiment 1
[0044] With 1000 parts by weight of 37wt% formaldehyde solution, 7 parts by weight of 10wt% sodium hydroxide solution, 450 parts by weight of urea and 70 parts by weight of melamine, adjust the temperature to 70°C and react at a constant temperature for 1 hour; keep the constant temperature reaction at 70°C temperature, then add 150 parts by weight of urea, 100 parts by weight of maltodextrin, react for 1.2 hours; add 150 parts by weight of ammonia water, 15 parts by weight of triethylenetetramine, stir for 10 minutes, cool down and discharge; add boric acid after cooling Sodium, ammonium borate, and quaternary ammonium copper form a mixed solution, so that the weight percentages of sodium borate, ammonium borate, and quaternary ammonium copper in the mixed solution are respectively 3wt%, 3wt%, and 3wt%, fully stirring and dissolving; after sawing the log Put the wooden blocks into the kiln for drying until the moisture content is 12-18%, and leave the kiln for later use; put t...
Embodiment 2
[0047] With 900 parts by weight of 37wt% formaldehyde solution, 6 parts by weight of 10wt% sodium hydroxide solution, 400 parts by weight of urea and 60 parts by weight of melamine, adjust the temperature to 75 ° C, and react at a constant temperature for 1.2 hours; keep the constant temperature reaction at 70 ° C temperature, then add 150 parts by weight of urea, 90 parts by weight of maltodextrin, react for 1.2 hours; add 100 parts by weight of ammonia water, 10 parts by weight of triethylenetetramine, stir for 8 minutes, cool down and discharge; add boric acid after cooling Sodium, ammonium borate, and quaternary ammonium copper form a mixed solution, so that the weight percentages of sodium borate, ammonium borate, and quaternary ammonium copper in the mixed solution are respectively 1wt%, 1wt%, 1wt%, fully stirred and dissolved; after the log is sawed Put the wooden blocks into the kiln for drying until the moisture content is 12-18%, and leave the kiln for later use; put ...
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