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Preparation method of full-alkaline synthetic melamine urea-formaldehyde resin and wood impregnation method thereof

A technology for synthesizing melamine urea-formaldehyde resin and alkalinity, which can be used in wood impregnation, wood treatment, pressure impregnation, etc. It can solve the problems of limited performance improvement, unfavorable impregnation of solid wood, initial viscosity and excessive molecular weight, and achieve the effect of small molecular weight

Active Publication Date: 2019-07-16
同威信达技术(江苏)股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Although the utilization rate of the wood-plastic composite method using broken wood is high, it is a waste of the mechanical support and restraint performance of the natural three-dimensional structure of the wood itself. The weather resistance of impregnated solid wood to adverse environmental factors such as water intrusion and sun exposure is lower than that of broken wood composite materials. significantly high, so for cheap fast-growing forest solid wood, it should make full use of the natural structure of solid wood and adopt impregnation modification
However, the initial viscosity and molecular weight of traditional glue are too large, which is not conducive to impregnating solid wood.
In the past, some physical or chemical methods were often used to violently expand wood pores or increase external pressure, such as high-pressure steam drying, high-pressure glue impregnation and other wood treatment methods. However, these treatment processes still have uneven wood treatment and limited performance improvement. , and additional production cost

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0029] A kind of preparation method of all-alkaline synthetic melamine urea-formaldehyde resin dipping liquid, comprises the following steps:

[0030] S10, after mixing 900-1200 parts by weight of formaldehyde solution, 4-8 parts by weight of sodium hydroxide solution, 20-120 parts by weight of melamine and 225-500 parts by weight of urea, adjust the temperature to 60-90 ° C, React at constant temperature for 0.5-5 hours, keep the pH between 7-10;

[0031] S11, maintaining a constant temperature reaction temperature of 60-90°C, then adding 150-475 parts by weight of urea, 90-300 parts by weight of maltodextrin or polyvinyl alcohol or starch, and reacting for 0.5-5 hours;

[0032] S12, adding 10-300 parts by weight of ammonia water and 2-30 parts by weight of triethylenetetramine, stirring for 5-20 minutes, cooling down to room temperature and discharging.

[0033] As a further improvement, the concentration of the formaldehyde solution is 35-40 wt%.

[0034] As a further imp...

Embodiment 1

[0044] With 1000 parts by weight of 37wt% formaldehyde solution, 7 parts by weight of 10wt% sodium hydroxide solution, 450 parts by weight of urea and 70 parts by weight of melamine, adjust the temperature to 70°C and react at a constant temperature for 1 hour; keep the constant temperature reaction at 70°C temperature, then add 150 parts by weight of urea, 100 parts by weight of maltodextrin, react for 1.2 hours; add 150 parts by weight of ammonia water, 15 parts by weight of triethylenetetramine, stir for 10 minutes, cool down and discharge; add boric acid after cooling Sodium, ammonium borate, and quaternary ammonium copper form a mixed solution, so that the weight percentages of sodium borate, ammonium borate, and quaternary ammonium copper in the mixed solution are respectively 3wt%, 3wt%, and 3wt%, fully stirring and dissolving; after sawing the log Put the wooden blocks into the kiln for drying until the moisture content is 12-18%, and leave the kiln for later use; put t...

Embodiment 2

[0047] With 900 parts by weight of 37wt% formaldehyde solution, 6 parts by weight of 10wt% sodium hydroxide solution, 400 parts by weight of urea and 60 parts by weight of melamine, adjust the temperature to 75 ° C, and react at a constant temperature for 1.2 hours; keep the constant temperature reaction at 70 ° C temperature, then add 150 parts by weight of urea, 90 parts by weight of maltodextrin, react for 1.2 hours; add 100 parts by weight of ammonia water, 10 parts by weight of triethylenetetramine, stir for 8 minutes, cool down and discharge; add boric acid after cooling Sodium, ammonium borate, and quaternary ammonium copper form a mixed solution, so that the weight percentages of sodium borate, ammonium borate, and quaternary ammonium copper in the mixed solution are respectively 1wt%, 1wt%, 1wt%, fully stirred and dissolved; after the log is sawed Put the wooden blocks into the kiln for drying until the moisture content is 12-18%, and leave the kiln for later use; put ...

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Abstract

The invention provides a preparation method of full-alkaline synthetic melamine urea-formaldehyde resin and a wood impregnation method thereof. The preparation method comprises the following steps: adding 900-1200 parts by weight of a formaldehyde solution, 4-8 parts by weight of a sodium hydroxide solution, 20-120 parts by weight of melamine and 225-500 parts by weight of urea, then adjusting thetemperature to 60-90 DEG C, carrying out a constant-temperature reaction for 0.5-5 hours, and keeping the pH value to be 7-10; keeping the temperature of the constant-temperature reaction to be 60-90DEG C, then adding 150-475 parts by weight of urea and 90-300 parts by weight of maltodextrin or polyvinyl alcohol or starch, and carrying out a reaction for 0.5-5 hours; and adding 10-300 parts by weight of ammonia water and 2-30 parts by weight of triethylene tetramine, carrying out stirring for 5-20 minutes, and carrying out cooling to room temperature for discharging. During use, wood blocksobtained after log sawing are put into a kiln for drying, sodium borate, ammonium borate and quaternary ammonium copper are added into the melamine formaldehyde resin impregnation liquid obtained by the method, adding the dried wood blocks into the mixed solution obtained by the method for impregnation; and drying the impregnated wood block samples to finally obtain a finished product.

Description

technical field [0001] The invention relates to a preparation method of melamine urea-formaldehyde resin and a wood impregnation method thereof. Background technique [0002] With the rapid development of the economy, people's demand for wood is increasing day by day. The shortage of timber has become a common problem in many countries in the world. Fast-growing and high-yielding wood is favored by more and more manufacturers and researchers because of its short growth cycle, high yield, and good economic benefits. The main species of artificial fast-growing forests in my country are poplar, willow, birch, paulownia and eucalyptus. However, fast-growing wood has disadvantages such as poor material, short fibers, easy deformation, and easy to rot and insects. It cannot meet the requirements of high-grade wood processing industry and lacks application value and economic value. In order to improve the performance of fast-growing wood, thereby expanding the range of use of fa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B27K3/02B27K3/52B27K3/00B27K3/08B27K5/04C08G12/38
CPCB27K3/005B27K3/0214B27K3/08B27K3/52B27K5/04B27K2240/20B27K2240/30C08G12/38
Inventor 张明昕韩志伟胡涛宋烨覃怀莉孟薇
Owner 同威信达技术(江苏)股份有限公司
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