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Flame-retardant thermoplastic polyester resin composition

A thermoplastic polyester and resin composition technology, which is applied in the field of flame-retardant thermoplastic polyester resin composition, can solve problems such as hydrolysis, thermal decomposition deterioration, difficulty in molding processed products, and decrease in melt viscosity, achieving excellent laser printability, Well-balanced to improve the effect of exudation suppression

Inactive Publication Date: 2019-07-26
ANHUI MEIJIA NEW MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, molded products of polyester resin such as used PET bottles collected from the market and polycarbonate resin such as optical discs are often deteriorated due to hydrolysis, thermal decomposition, etc.
For example, even if the material obtained by pulverizing these molded products is attempted to be remolded, it cannot be molded at all due to a significant drop in melt viscosity, or even if it can be molded, it is easily damaged due to weak mechanical strength. It is very difficult to withstand practical molded products

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A flame-retardant thermoplastic polyester resin composition of the present invention comprises the following raw materials in parts by weight: 80 parts of crystalline polyester resin, 10 parts of amorphous resin, 5 parts of antistatic agent, and 2 parts of organophosphorus flame retardant .

[0019] The crystalline polyester resin is polyethylene terephthalate, polybutylene terephthalate.

[0020] The amorphous resin is polyphenylene ether resin.

[0021] The antistatic agent is polyethylene glycol-based polyamide, polyester amide, polyethylene glycol methacrylate copolymer, ethylene oxide / propylene oxide copolymer, methacrylate copolymer containing quaternary ammonium base substances and high molecular weight polyethylene glycol.

[0022] The organic phosphorus flame retardant is a mixture of phosphoric acid ester, phosphorous acid ester, phosphoric acid ester, organic phosphorus salt, phosphorus heterocyclic compound and polymer phosphorus (phosphonic) ester.

[00...

Embodiment 2

[0026] A flame-retardant thermoplastic polyester resin composition of the present invention comprises the following raw materials in parts by weight: 20 parts of crystalline polyester resin, 50 parts of amorphous resin, 5 parts of antistatic agent, and 30 parts of organophosphorus flame retardant .

[0027] The crystalline polyester resin is polyethylene terephthalate, polybutylene terephthalate.

[0028] The amorphous resin is polyphenylene ether resin.

[0029] The antistatic agent is polyethylene glycol-based polyamide, polyester amide, polyethylene glycol methacrylate copolymer, ethylene oxide / propylene oxide copolymer, methacrylate copolymer containing quaternary ammonium base substances and high molecular weight polyethylene glycol.

[0030] The organophosphorous flame retardant is a mixture of phosphoric acid ester, phosphorous acid ester, phosphoric acid ester, organic phosphorous salt and phosphorus heterocyclic compound.

[0031] The molecular weight of the organo...

Embodiment 3

[0034] A flame-retardant thermoplastic polyester resin composition of the present invention comprises the following raw materials in parts by weight: 50 parts of crystalline polyester resin, 40 parts of amorphous resin, 5 parts of antistatic agent, and 5 parts of organophosphorus flame retardant .

[0035] The crystalline polyester resin is polyethylene terephthalate, polybutylene terephthalate.

[0036] The amorphous resin is polyphenylene ether resin.

[0037] The antistatic agent is polyethylene glycol-based polyamide, polyester amide, polyethylene glycol methacrylate copolymer, ethylene oxide / propylene oxide copolymer, methacrylate copolymer containing quaternary ammonium base substances and high molecular weight polyethylene glycol.

[0038] The organic phosphorus flame retardant is a mixture of phosphoric acid ester, phosphorous acid ester, phosphoric acid ester, organic phosphorus salt, phosphorus heterocyclic compound and polymer phosphorus (phosphonic) ester.

[00...

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PUM

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Abstract

The invention discloses a flame-retardant thermoplastic polyester resin composition. The flame-retardant thermoplastic polyester resin composition comprises the following raw materials in parts by weight: 20-80 parts of crystalline polyester resin, 10-50 parts of non-crystalline resin, 5-30 parts of an anti-static agent, and 2-30 parts of an organic phosphorus flame retardant. The flame-retardantthermoplastic polyester resin composition is a polyester resin composition of a crystalline material, and has good low-warp. Seepage inhibition of the flame retardant is improved, so the flame-retardant thermoplastic polyester resin composition can be suitably used as a forming material of a home appliance, an electric device, an OA part and the like, and useful in the industry. The resin composition is easily endowed with high flame resistance by a phosphorus compound, and has not environmental toxicity. The flame-retardant thermoplastic polyester resin composition has excellent retention stability in a processing temperature of a wide range, and has high flame retardance, high mechanical strength, excellent electrical characteristics, less mould deposit, and excellent laser printability.Especially, viewed from good and excellent balance of these characteristics, the flame-retardant thermoplastic polyester resin composition is promising, wide in applicability, and suitable for popularization and application, and has very extensive market prospect.

Description

technical field [0001] The invention relates to a polyester resin composition, in particular to a flame-retardant thermoplastic polyester resin composition. Background technique [0002] Polyester resins, a type of resin most frequently used in containers, sheets, films, fibers, and injection molded products, most commonly use antimony oxide or antimony triacetate as a catalyst during its preparation. Antimony catalyst has excellent advantages in color, and productivity is high due to high activity during esterification (ES) and polycondensation (P.C), but due to its toxicity, control of antimony as a material harmful to human body , and thus, the development of new catalysts that are safe to the human body and environmentally friendly is widely required. In Japan, polyester resins have been produced by utilizing germanium catalysts as an alternative to such limitations. However, since the price of germanium catalysts can be ten times or higher than that of antimony cataly...

Claims

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Application Information

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IPC IPC(8): C08L67/02C08L71/12C08L71/02C08L77/12C08L77/00C08L33/14C08L101/02C08L85/02C08K5/00C08K5/521C08K5/524
CPCC08K2201/014C08L67/02C08L71/12C08L2201/02C08L2201/22C08L2203/20C08L2205/02C08L2205/025C08L2205/035C08L71/02C08L77/12C08L77/00C08L33/14C08L101/02C08L85/02C08K5/0066C08K5/521C08K5/524
Inventor 王方银张雪梅王峰范宽政
Owner ANHUI MEIJIA NEW MATERIAL
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