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High-density polyethylene conductive material and preparation method thereof

A technology of high-density polyethylene and conductive materials, which is applied in the field of plastic materials, can solve problems affecting the mechanical properties of plastics, and achieve the effects of stable resistance, improved elastic modulus, and uniform temperature

Inactive Publication Date: 2019-12-27
淮安正天新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since the addition of conductive materials to resin materials will affect the mechanical properties of plastics, improving the mechanical properties of conductive materials has become a current research hotspot.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] A high-density polyethylene conductive material, raw materials include: 70 parts by weight of high-density polyethylene, 3 parts of carbon black, 2 parts of glass fiber, 1 part of ethylene vinyl acetate copolymer, 2 parts of phenolic resin, potassium titanate crystal 1 part of whisker, 3 parts of filler, 2 parts of stabilizer, 1 part of coupling agent, 1 part of plasticizer, and 1 part of antioxidant.

[0018] Wherein, the filler is calcium carbonate. Described stabilizer is calcium stearate. The coupling agent is a silane coupling agent. The antioxidant is 2,6-di-tert-butyl-4-methylphenol.

[0019] The preparation method of above-mentioned high-density polyethylene conductive material, comprises the following steps:

[0020] Step 1, mixing high-density polyethylene, glass fiber, ethylene-vinyl acetate copolymer, phenolic resin, potassium titanate whiskers and a coupling agent to obtain a mixture A;

[0021] Step 2, sending the mixture A into a twin-screw extruder, ...

Embodiment 2

[0026] A high-density polyethylene conductive material, raw materials include: 73 parts of high-density polyethylene, 4 parts of carbon black, 3 parts of glass fiber, 1 part of ethylene vinyl acetate copolymer, 3 parts of phenolic resin, potassium titanate crystal 2 parts of whisker, 4 parts of filler, 3 parts of stabilizer, 2 parts of coupling agent, 1 part of plasticizer, and 2 parts of antioxidant.

[0027] Wherein, the filler is calcium sulfate. The stabilizer is calcium ricinoleate. The coupling agent is a silane coupling agent. The antioxidant is tert-butyl hydroquinone.

[0028] The preparation method of above-mentioned high-density polyethylene conductive material, comprises the following steps:

[0029] Step 1, mixing high-density polyethylene, glass fiber, ethylene-vinyl acetate copolymer, phenolic resin, potassium titanate whiskers and a coupling agent to obtain a mixture A;

[0030] Step 2, sending the mixture A into a twin-screw extruder, melt extrusion and gr...

Embodiment 3

[0035] A high-density polyethylene conductive material, raw materials include: 77 parts by weight of high-density polyethylene, 6 parts of carbon black, 3 parts of glass fiber, 2 parts of ethylene vinyl acetate copolymer, 3 parts of phenolic resin, potassium titanate crystal 2 parts of whisker, 5 parts of filler, 4 parts of stabilizer, 2 parts of coupling agent, 2 parts of plasticizer, and 1 part of antioxidant.

[0036] Wherein, the filler is talcum powder. Described stabilizer is zinc stearate. The coupling agent is a silane coupling agent. The antioxidant is 2,6-di-tert-butyl-4-methylphenol.

[0037] The preparation method of above-mentioned high-density polyethylene conductive material, comprises the following steps:

[0038] Step 1, mixing high-density polyethylene, glass fiber, ethylene-vinyl acetate copolymer, phenolic resin, potassium titanate whiskers and a coupling agent to obtain a mixture A;

[0039] Step 2, sending the mixture A into a twin-screw extruder, mel...

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Abstract

The invention discloses a high-density polyethylene conductive material and a preparation method thereof. The conductive material is prepared from the following raw materials: high-density polyethylene, carbon black, glass fibers, an ethylene-vinyl acetate copolymer, phenolic resin, potassium titanate whiskers, filler, a stabilizer, a coupling agent, a plasticizer and an antioxidant. The preparation method comprises the following steps: firstly, mixing the high-density polyethylene, the glass fiber, the ethylene-vinyl acetate copolymer, the phenolic resin, the potassium titanate whisker and the coupling agent; and feeding the mixture into a double-screw extruder, carrying out melt extrusion granulation, mixing the mixed particles with carbon black, a filler, a stabilizer, a plasticizer andan antioxidant, then feeding the mixture into a single-screw extruder, and carrying out melt extrusion granulation to obtain the product. The high-density polyethylene is used as a main material, andmeanwhile, the acrylic resin, the glass fibers and the potassium titanate whiskers are added, so that the conductive material is stable in resistance and uniform in temperature.

Description

technical field [0001] The invention belongs to the technical field of plastic materials, and in particular relates to a high-density polyethylene conductive material and a preparation method thereof. Background technique [0002] High-density polyethylene (HDPE) is a white powder or granular product, non-toxic, tasteless, crystallinity is 80% to 90%, softening point is 125 to 135°C, and the service temperature can reach 100°C; hardness, tensile strength And creep is better than low-density polyethylene; wear resistance, electrical insulation, toughness and cold resistance are better; chemical stability is good, at room temperature, insoluble in any organic solvents, acid, alkali and various salts Corrosion; the film has low permeability to water vapor and air, low water absorption; poor aging resistance, environmental stress cracking resistance is not as good as low-density polyethylene, especially thermal oxidation will reduce its performance. [0003] Conductive material...

Claims

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Application Information

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IPC IPC(8): C08L23/06C08L23/08C08L61/06C08K13/04C08K7/14C08K3/04C08K5/13C08K5/098C08K7/08
CPCC08K2201/001C08L23/06C08L2205/03C08L2207/062C08L23/0853C08L61/06C08K13/04C08K7/14C08K3/04C08K5/13C08K5/098C08K7/08
Inventor 李铜玲
Owner 淮安正天新材料科技有限公司
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