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A polytetrafluoroethylene composite material for packing and method for preparing packing thereof

A technology of polytetrafluoroethylene and composite materials, applied in the field of sealing materials, can solve the problems of limited shape and volume, affecting packing sealing performance and durability, equipment service life, and comprehensive performance needs to be improved.

Active Publication Date: 2022-05-13
JUHUA GROUP TECH CENT
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The current PTFE packing can improve a certain defect by adding specific fillers, but the overall performance needs to be improved. The high temperature performance, wear problems, and wear and corrosion problems of equipment have not been greatly improved, which affects the The sealing performance and durability of the packing and the service life of the equipment
CN 106594281 A discloses a polytetrafluoroethylene packing. The outer layer of the packing is made of polytetrafluoroethylene material, the inner core of the packing is made of silicon rubber, and the outer layer and the inner core are made of a polytetrafluoroethylene film. The core is isolated, so that it has good elasticity, can maintain good sealing performance, and can maintain good corrosion resistance at the same time, but because the outer layer is made of pure polytetrafluoroethylene, it is easy to wear and the upper limit of the service temperature is low
CN103574035 A discloses a polytetrafluoroethylene fiber packing, which is composed of the following components in parts by weight: 100 parts of polytetrafluoroethylene, 80-100 parts of graphite, 1-3 parts of isopropyl trioctanoyl titanate, 2-4 parts of harsh nickel; CN 1724607 A discloses a graphite-filled polytetrafluoroethylene fiber packing, the dispersed polytetrafluoroethylene resin accounts for 50%-82%, and the rest is natural graphite; both of them are obtained by adding a large amount of graphite Improve thermal conductivity, high-speed resistance and low creep performance, and the performance is better than that of pure PTFE fiber packing. However, due to the limitation of the characteristics of graphite itself, when used in environments with high requirements such as high strength, there are still Insufficient properties such as anti-wear and anti-extreme pressure
CN 108360260 A discloses a packing, a preparation method of the packing and the first impregnating liquid used for preparing the packing. The fluorine-containing polymer emulsion such as polytetrafluoroethylene added with functional filler additives is impregnated into the The surface of ramie fiber, flax fiber, aramid fiber, polyester fiber, acrylic fiber, carbon fiber or cotton fiber is dried to make packing, but due to the non-stickiness of fluorine-containing materials, when used in high-strength environments, fluorine-containing coatings Layers are easily detached from the fibers causing packing failure
CN 1464023 A discloses a filled polytetrafluoroethylene material for oil sealing parts and its preparation method, wherein the composition includes (the following amounts are parts by weight): 100 parts of suspended polytetraethylene resin, 5.8-6.8 parts of molybdenum disulfide, 8.7-20.5 parts of alkali-free glass fiber, 2.7-5.8 parts of graphite powder, mixed at high speed and then molded and sintered. Excellent performance and other characteristics, but this kind of seal made of polytetraethylene suspension resin can only be prepared by machining after molding and sintering, and the shape and volume are greatly limited, so it is limited by the shape and space where the equipment is used larger

Method used

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  • A polytetrafluoroethylene composite material for packing and method for preparing packing thereof
  • A polytetrafluoroethylene composite material for packing and method for preparing packing thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0018] The dopamine aqueous solution is prepared, the pH value is adjusted, molybdenum disulfide, aluminum oxide, tetrapod zinc oxide, carbon nanotubes, and clay are respectively placed in the dopamine aqueous solution for immersion, stirring, filtering, and drying. 100 parts of polytetrafluoroethylene dispersed resin powder (parts by weight, the same below) and 20 parts of the above-mentioned processed molybdenum disulfide, 1 part of aluminum oxide, 1 part of tetraacicular zinc oxide, 3 parts of carbon nanotubes, 3 parts of clay 24 parts of aviation kerosene (No. 3 jet fuel) were added and mixed evenly, the speed of the agitator was 30rmp during mixing, and the time was 30min; then the mixed raw materials were placed at 30°C for 24h for aging; then the matured The raw materials are added to the mold for pre-compression, the pre-compression pressure is 2MPa, and a cylindrical mold blank with good appearance is formed; then the mold blank is put into a pusher for pushing at a te...

Embodiment 2

[0020] The dopamine aqueous solution is prepared, the pH value is adjusted, and the molybdenum disulfide, aluminum oxide, tetrapod zinc oxide, carbon nanotubes, and clay that have been treated with fluorine gas fluoride are respectively immersed in the dopamine aqueous solution, stirred, filtered, and then dried. Mix 100 parts of polytetrafluoroethylene dispersed resin powder and 5 parts of molybdenum disulfide, 5 parts of aluminum oxide, 10 parts of tetraacicular zinc oxide, 5 parts of carbon nanotubes and 5 parts of clay after the above-mentioned treatment, and then add 24 Parts of aviation kerosene (No. 3 jet fuel) were uniformly mixed, and the mixer speed was 30rmp during mixing, and the mixing time was 30min; then the mixed raw materials were placed at 30°C for 24h for aging; then the matured raw materials were added to the mold for pre-treatment. The pre-pressing pressure is 2MPa to form a cylindrical mold blank with good appearance; then the mold blank enters the pusher ...

Embodiment 3

[0022]Prepare a dopamine aqueous solution, adjust the pH value, respectively put 10 parts of molybdenum disulfide, 10 parts of aluminum oxide, 5 parts of tetrapod zinc oxide, 1 part of carbon nanotube, and 1 part of clay into the dopamine aqueous solution for immersion and stirring. Mix the above suspension with polytetrafluoroethylene emulsion containing 100 parts of polytetrafluoroethylene dispersion resin evenly, add coagulant for coagulation, dehydrate and dry; add 24 parts of aviation kerosene (No. 3 jet fuel) to the above materials Mixing, when mixing, the speed of the agitator is 30rmp, and the time is 30min; then the mixed raw materials are placed at 30°C for 24h for aging; then the matured raw materials are added to the mold for pre-compression, and the pre-compression pressure is 2MPa to form the appearance Good cylindrical mold blank; then put the mold blank into a pusher for pushing at a temperature of 60°C, after pushing, it will be rolled into a film by a calender...

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Abstract

The invention discloses a polytetrafluoroethylene composite material for packing and a method for preparing the packing. The polytetrafluoroethylene composite material for packing consists of the following components in parts by weight: polytetrafluoroethylene dispersion resin 100 Parts, 5-20 parts of molybdenum disulfide, 1-10 parts of tetraacicular zinc oxide, 1-10 parts of aluminum oxide, 1-5 parts of carbon nanotubes, 1-5 parts of clay; the method for preparing packing consists of the following steps Composition: (1) mix polytetrafluoroethylene dispersed resin and various fillers evenly; (2) add booster oil to fully mix and heat and mature; (3) press into billets; (4) push extrusion and calendering; (5) ) high temperature deoiling and stretching and shaping; (6) split into fibers and weave packing. The polytetrafluoroethylene packing of the present invention has excellent thermal conductivity and heat resistance, high temperature stress relaxation resistance, acid and alkali resistance, chemical reagents and self-lubrication performance, good sealing performance, long service life and less wear on equipment, It can be used for pumps or valves with high pressure, high temperature, high speed and dynamic sealing.

Description

technical field [0001] The invention belongs to the field of sealing materials, and in particular relates to a polytetrafluoroethylene composite material for packing and a method for preparing the packing. Background technique [0002] Packing (woven packing) is also called sealing packing, which is usually braided by softer wires, usually square or rectangular in cross-sectional area, and round strips are filled in the sealing cavity to achieve sealing. The stuffing seal was originally made of cotton and other fibers plugged in the leakage channel to prevent liquid leakage, and it was mainly used as a shaft seal for water lifting machinery. Due to the wide range of packing sources, easy processing, low price, reliable sealing and simple operation, it is still used today. Now packing is widely used in shaft seals of centrifugal pumps, compressors, vacuum pumps, mixers and ship propellers, piston pumps, reciprocating compressors, reciprocating shaft seals of refrigerators, a...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L27/18C08K13/06C08K9/04C08K9/02C08K3/30C08K3/22C08K7/00C08K3/04C08K3/34
CPCC08K13/06C08K9/04C08K9/02C08K3/30C08K3/22C08K7/00C08K3/041C08K3/346C08K2003/2227C08K2003/2296C08K2201/011C08K2201/017C08K2003/3009C08L2201/08C08L27/18
Inventor 邵春明孙洪阳王海连高艳林蒋晓璐
Owner JUHUA GROUP TECH CENT