Preparation method, product and application of a self-supporting metal-doped iron nitride electrode
A metal-doped, self-supporting technology, applied in the field of electrochemistry, can solve the problems of complex electrode preparation process, high equipment requirements, poor safety performance, etc., and achieve the effect of simple and easy process, high selectivity and low cost.
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0038] Example 1 Preparation of self-supporting nickel-doped iron nitride electrode
[0039] (1) Preparation of self-supporting porous iron oxide: the iron foil with an area of 19.6 square millimeters was ultrasonically cleaned with acetone and ethanol respectively to remove organic matter on the surface, and then dried with nitrogen, and the dried iron foil was used as an anode, and another A platinum sheet with an area of 19.6 square millimeters is used as the cathode, and a platinum sheet containing 0.1mol / L NH 4 F and 1mol / L H 2 The ethylene glycol solution of O is used as the electrolyte, and the iron foil is oxidized for 40 minutes by using a 40V DC constant voltage. After the oxidized iron foil is cleaned, it is dried with nitrogen to obtain a porous iron oxide with iron as the conductive substrate, such as figure 1 Shown is the scanning electron micrograph (SEM) figure of the porous iron oxide, and it can be seen that the iron oxide generated on the surface of the...
Embodiment 2
[0042] Example 2 Preparation of self-supporting cobalt-nickel-doped iron nitride electrode
[0043] (1) Preparation of self-supporting porous iron oxide: the iron foil with an area of 19.6 square millimeters was ultrasonically cleaned with acetone and ethanol respectively to remove organic matter on the surface, and then dried with nitrogen, and the dried iron foil was used as an anode, and another A platinum sheet with an area of 39.2 square millimeters is used as the cathode, and a platinum sheet containing 0.1mol / L NH 4 F and 1mol / L H 2 The ethylene glycol solution of O is used as the electrolyte, and the iron foil is oxidized for 120 minutes by 20V DC constant voltage, and the oxidized iron foil is cleaned and dried with nitrogen to obtain porous iron oxide with iron as the conductive substrate;
[0044] (2) Electrodeposition of cobalt-nickel metal: the porous iron oxide prepared in step (1) is used as the cathode, and the platinum sheet is used as the anode, containi...
Embodiment 3
[0049] Example 3 Preparation of self-supporting cobalt-doped iron nitride electrode
[0050] (1) Preparation of self-supporting porous iron oxide: the iron foil with an area of 7 square millimeters was ultrasonically cleaned with acetone and ethanol respectively to remove organic matter on the surface, and then dried with nitrogen, and the dried iron foil was used as an anode, and another A platinum sheet with an area of 21 square millimeters is used as the cathode, and a platinum sheet containing 0.1mol / L NH 4 F and 1mol / L H 2 The ethylene glycol solution of O was used as the electrolyte, and the iron foil was oxidized for 10 minutes by 65V DC constant voltage, and the oxidized iron foil was cleaned and dried with nitrogen to obtain porous iron oxide with iron as the conductive substrate;
[0051] (2) Electrodeposition of cobalt metal: the porous iron oxide prepared in step (1) is used as the cathode, and the platinum sheet is used as the anode, and electrodeposition is ...
PUM
| Property | Measurement | Unit |
|---|---|---|
| electric potential / voltage | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
Login to View More