Method for preparing underwear with antibacterial effect by utilizing electrostatic spinning method
An electrospinning method and underwear technology, applied in underwear, baby underwear, rayon manufacturing, etc., can solve the problems of not being able to discharge in time, poor ventilation effect, etc.
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Embodiment 1
[0065] Step 1) Dissolve chitosan in a mixed solvent of 0.1 mol / L sodium acetate and 0.2 mol / L acetic acid (molar ratio of chitosan: acetate is 3:1), stir until completely dissolved, add 2 times of acetate The molar amount of laurylaldehyde was stirred for 1h, and the pH of the system was adjusted to 4-5 by adding 0.1 mol / L NaOH solution, and the NaBH 4 (NaBH 4 : The molar ratio of laurylaldehyde is 3:1) Slowly add dropwise to the above solution within 1h, until the pH of the reaction system rises to 5-6, react for 1h, adjust the pH of the system to 9-10 with NaOH solution, until precipitation Afterwards, filter, wash the precipitate with water to neutrality, and then extract it with ethanol in a Soxhlet extractor for more than 12 hours to remove the remaining lauric aldehyde and inorganic salts, dry and pulverize to obtain hydrophobically modified chitosan, the average particle size less than 2 microns;
[0066] The chitosan aqueous solution of hydrophobic modification is di...
Embodiment 2
[0074] Step 1) Dissolve chitosan in a mixed solvent of 0.1 mol / L sodium acetate and 0.2 mol / L acetic acid (molar ratio of chitosan: acetate is 3:1), stir until completely dissolved, add 2 times of acetate The molar amount of laurylaldehyde was stirred for 4h, and the system was adjusted to pH 4-5 by adding 0.1 mol / L NaOH solution, and the NaBH 4 (NaBH 4 : The molar ratio of laurylaldehyde is 3:1) Slowly add dropwise to the above solution within 1h, until the pH of the reaction system rises to 5-6, react for 1h, adjust the pH of the system to 9-10 with NaOH solution, until precipitation Afterwards, filter, wash the precipitate with water to neutrality, and then extract it with ethanol in a Soxhlet extractor for more than 12 hours to remove the remaining lauric aldehyde and inorganic salts, dry and pulverize to obtain hydrophobically modified chitosan, the average particle size less than 2 microns;
[0075] The hydrophobically modified chitosan was dissolved in 1% v / v aqueous ...
Embodiment 3
[0083] Step 1) Dissolve chitosan in a mixed solvent of 0.1 mol / L sodium acetate and 0.2 mol / L acetic acid (molar ratio of chitosan: acetate is 3:1), stir until completely dissolved, add 2 times of acetate The molar amount of laurylaldehyde was stirred for 3h, and the pH of the system was adjusted to 4-5 by adding 0.1 mol / L NaOH solution, and the NaBH 4 (NaBH 4 : The molar ratio of laurylaldehyde is 3:1) Slowly add dropwise to the above solution within 1h, until the pH of the reaction system rises to 5-6, react for 1h, adjust the pH of the system to 9-10 with NaOH solution, until precipitation Afterwards, filter, wash the precipitate with water to neutrality, and then extract it with ethanol in a Soxhlet extractor for more than 12 hours to remove the remaining lauric aldehyde and inorganic salts, dry and pulverize to obtain hydrophobically modified chitosan, the average particle size less than 2 microns;
[0084] The chitosan aqueous solution of hydrophobic modification is di...
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