Membrane material for industrial wastewater treatment

A technology of industrial wastewater and membrane materials, which is applied in the direction of adsorption water/sewage treatment, light water/sewage treatment, water/sludge/sewage treatment, etc. It can solve the problem of consumption of amino, no catalytic decomposition of toxic and harmful organic substances, and reduce the treatment of heavy metal ions ability and other issues, to achieve the effect of improving description, improving mechanical properties and performance stability, and improving photocatalytic efficiency

Inactive Publication Date: 2020-06-16
周青英
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this method consumes a large amount of amino groups in the cross-linking process, which reduces the ability to deal with heavy metal ions, and it has no catalytic effect on the decomposition of toxic and harmful organic substances in industrial wastewater.

Method used

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  • Membrane material for industrial wastewater treatment

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Effect test

Embodiment 1

[0034] A membrane material for industrial wastewater treatment, formed by free radical polymerization of the following polymerizable monomers in parts by weight: 3 parts of vinyl-modified boronized black phosphorus quantum dots, vinyl-terminated hyperbranched poly(amine-ester ) 8 parts, β-phenylacryloyl chloride modified 2,4,6-tris(4-aminophenyl)-1,3,5-triazine 1 part.

[0035] The preparation method of the vinyl-modified black phosphorus boride quantum dots comprises the following steps:

[0036] Step S1, put black phosphorus quantum dots, ammonium pentaborate, Tween 20, and ethanol in a polytetrafluoroethylene reaction kettle, keep warm at 150°C for 8 hours, cool to room temperature, remove ethanol by rotary evaporation, and then place in water Disperse, centrifuge, and dry to constant weight at 85°C to obtain boronized black phosphorus quantum dots; the mass ratio of the black phosphorus quantum dots, ammonium pentaborate, Tween 20, and ethanol is 1:0.05:0.1:5;

[0037] St...

Embodiment 2

[0042] A membrane material for industrial wastewater treatment, formed by free radical polymerization of the following polymerizable monomers in parts by weight: 4 parts of vinyl-modified boronized black phosphorus quantum dots, vinyl-terminated hyperbranched poly(amine-ester ) 9 parts, β-phenylacryloyl chloride modified 2,4,6-tris(4-aminophenyl)-1,3,5-triazine 1.5 parts.

[0043] The preparation method of the vinyl-modified black phosphorus boride quantum dots comprises the following steps:

[0044] Step S1, put black phosphorus quantum dots, ammonium pentaborate, Tween 20, and ethanol in a polytetrafluoroethylene reaction kettle, keep warm at 155°C for 9 hours, cool to room temperature, remove ethanol by rotary evaporation, and then place in water Disperse, centrifuge, and dry at 87°C to constant weight to obtain boride black phosphorus quantum dots; the mass ratio of black phosphorus quantum dots, ammonium pentaborate, Tween 20, and ethanol is 1:0.07:0.1:6;

[0045] Step S...

Embodiment 3

[0050] A membrane material for industrial wastewater treatment, formed by free radical polymerization of the following polymerizable monomers in parts by weight: 4.5 parts of vinyl-modified boronized black phosphorus quantum dots, vinyl-terminated hyperbranched poly(amine-ester ) 10 parts, β-phenylacryloyl chloride modified 2,4,6-tris(4-aminophenyl)-1,3,5-triazine 2 parts.

[0051] The preparation method of the vinyl-modified black phosphorus boride quantum dots comprises the following steps:

[0052] Step S1, put black phosphorus quantum dots, ammonium pentaborate, Tween 20, and ethanol in a polytetrafluoroethylene reaction kettle, keep warm at 160°C for 10 hours, cool to room temperature, remove ethanol by rotary evaporation, and then place in water Disperse, centrifuge, and dry at 90°C to constant weight to obtain boronized black phosphorus quantum dots; the mass ratio of the black phosphorus quantum dots, ammonium pentaborate, Tween 20, and ethanol is 1:0.1:0.1:7;

[0053...

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PUM

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Abstract

The invention discloses a membrane material for industrial wastewater treatment. The membrane material is characterized by being prepared from the following polymerizable monomers in parts by weight through free radical polymerization: 3-6 parts of vinyl modified boronized black phosphorus quantum dots, 8-12 parts of vinyl-terminated hyperbranched poly (amine-ester) and 1-3 parts of beta-phenyl acryloyl chloride modified 2, 4, 6-tri (4-aminophenyl)-1, 3, 5-triazine. The invention also discloses a preparation method of the membrane material for industrial wastewater treatment. The membrane material for industrial wastewater treatment disclosed by the invention is good in treatment effect on industrial wastewater containing heavy metal ions, high in efficiency, excellent in mechanical property, corrosion resistance and pollution resistance, and particularly high in capacity of catalyzing decomposition of organic matters in the wastewater and adsorbing and separating the heavy metal ionsin the wastewater.

Description

technical field [0001] The invention relates to the technical field of wastewater treatment, in particular to a membrane material for industrial wastewater treatment and a preparation method thereof. Background technique [0002] In recent years, with the development of the economy and the advancement of global industrialization, a large amount of industrial wastewater and urban domestic sewage containing heavy metals have been discharged into the environment, posing a serious threat to the atmosphere, soil and water environment, especially human health. If it is dealt with, it will cause serious damage to the heart, kidney, liver and other vital organs of the human body. Therefore, seeking effective industrial wastewater treatment technology has become the focus of urgent attention in the industry. [0003] At present, the treatment methods for industrial wastewater containing heavy metals mainly include: chemical precipitation method, electrochemical method, adsorption me...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/26B01J20/28B01J20/30B01D71/54B01J31/02C02F1/44C02F1/28C02F1/30C02F101/20
CPCB01D71/36B01D71/54B01D2325/24B01J20/264B01J20/28033B01J31/0244B01J31/0271B01J35/004C02F1/28C02F1/30C02F1/44C02F2101/20
Inventor 不公告发明人
Owner 周青英
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