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Expandable selective long-acting water plugging agent and preparation method thereof

A water-blocking agent and selective technology, applied in chemical instruments and methods, drilling compositions, etc., can solve the problems of weak corrosion resistance and scourability, short validity period of water-blocking agent, poor salt resistance of water-blocking agent, etc. , to achieve the effect of temperature resistance and salt resistance adsorption performance, long water blocking validity period and high blocking strength

Active Publication Date: 2020-11-20
BEIJING GEPETTO OIL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

With the increasing difficulty of oilfield exploitation, there are many problems and limitations in the existing chemical water shutoff agents. Non-selective water shutoff often causes false plugging, blocking water and oil at the same time, and sediment water shutoff agents can also Cause serious reservoir damage, affecting production
In addition, the water blocking agent has problems such as poor salt resistance, corrosion resistance and weak scouring performance, resulting in a short validity period of the water blocking agent.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A preparation method of an expandable selective long-acting water blocking agent, comprising the steps of:

[0025] Step 1, prepare polyurethane prepolymer: take by weighing 30 grams of polyethylene glycol (moisture removal in advance), 20 grams of polytetrahydrofuran diol (moisture removal in advance) and put them into a three-necked flask, add 30 grams of toluene diisocyanate (preliminary removal of water) under stirring Remove water), heat up to 80°C, react for 2h, and vacuum degas at 80°C for 0.5h to obtain the polyurethane prepolymer. Weigh 70g of the polyurethane prepolymer, which is the A component.

[0026] Step 2. Preparation of functional liquid: 6 grams of acrylamide, 2 grams of 2-acrylamide-2-methylpropanesulfonic acid, 0.01 grams of azobisisobutylimidazoline, 2 grams of hydrophilic nano-silica, 0.05 1 g of triethanolamine and 3 g of trimethylolpropane were sequentially added into 16.94 g of water and stirred evenly to obtain component B.

[0027] Step 3. P...

Embodiment 2

[0030] A preparation method of an expandable selective long-acting water blocking agent, comprising the steps of:

[0031] Step 1, prepare polyurethane prepolymer: take by weighing 25 grams of polycaprolactone diol (removal of moisture in advance), 35 grams of polycarbonate diol (removal of moisture in advance) and put into a three-necked flask, add 30 grams of 1 under stirring, 6-hexamethylene diisocyanate, heated up to 80°C, reacted for 2h, degassed in vacuum at 80°C for 0.5h to obtain a polyurethane prepolymer, weighed 80 grams of polyurethane prepolymer, which was the A component.

[0032] Step 2. Preparation of functional liquid: 4 grams of acrylamide, 1 gram of acrylic acid, 2 grams of nano-aluminum oxide, 0.01 gram of ammonium persulfate, 0.01 gram of sodium bisulfite, 0.03 gram of dibutyltin dilaurate, 3 grams of three Isopropanolamine was sequentially added into 9.95 g of water and stirred evenly to obtain component B.

[0033] Step 3. Pour component A and component ...

Embodiment 3

[0036] A preparation method of an expandable selective long-acting water blocking agent, comprising the steps of:

[0037] Step 1. Preparation of polyurethane prepolymer: Weigh 50 grams of polytetramethylene ether glycol (remove moisture in advance), put it into a three-necked flask, add 40 grams of methylcyclohexyl diisocyanate under stirring, and heat up to 80°C. React for 2 hours, and vacuum degas at 80° C. for 0.5 hours to obtain a polyurethane prepolymer. Weigh 60 grams of the polyurethane prepolymer, which is component A.

[0038] Step 2. Preparation of functional liquid: 12 grams of acrylamide, 2 grams of 2-acrylamide-2-methylpropanesulfonic acid, 1 gram of acrylic acid, 5 grams of nano-calcium carbonate, 0.05 grams of ammonium persulfate, 1 gram of stannous octoate , 2 grams of 1,4-butanediol were added to 16.95 grams of water in turn, and stirred evenly to obtain component B.

[0039] Step 3. Pour component A and component B liquids into the reactor and stir evenly, ...

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PUM

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Abstract

The invention discloses an expandable selective long-acting water plugging agent and a preparation method thereof. The expandable selective long-acting water plugging agent comprises a component A anda component B, wherein the component A is a polyurethane prepolymer, and accounts for 60-85% of the total mass of the raw materials of the water plugging agent, the component B is a mixed solution formed by mixing 1-20% of a hydrophilic functional monomer, 1-10% of a hydrophilic nano material, 0.01-1% of an initiator, 0.01-5% of a catalyst, 1-10% of a chain extender and water, the content of eachraw material in the component B is the proportion of a single agent in the total mass of the raw materials of the water plugging agent, and the water plugging agent is prepared by mixing the component A and the component B, and polymerizing the polyurethane prepolymer, the hydrophilic functional monomer and the hydrophilic nano material under the combined action of the initiator, the catalyst andthe chain extender. According to the invention, the hydrophilic functional monomer and the hydrophilic nano material are introduced into the traditional polyurethane material, so that the water swelling property, the stability and the plugging capability of the water plugging agent are enhanced, and the water plugging agent has the characteristics of water plugging and no oil plugging, and is suitable for water plugging operation of an oil-water well in a high-water-content block.

Description

technical field [0001] The invention relates to the technical field of oilfield development, in particular to an expandable selective long-acting water shutoff agent and a preparation method thereof. Background technique [0002] Water production from oil wells is a common phenomenon encountered in the middle and late stages of oilfield development, especially in water flooding oilfields. Water output from oil wells will not only reduce production and accelerate equipment corrosion, but also cause damage to the original structure of the formation, aggravate sand production in oil wells, increase the amount of sewage treatment, and slow down the progress of oilfield exploitation. At present, the water shutoff methods in oil fields are mainly mechanical water shutoff method and chemical water shutoff method. Chemical water plugging is currently the most researched and most effective method. The common chemical plugging agents mainly include polyacrylamide polymer gel, resin ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F283/00C08F220/56C08F220/58C08F220/06C08G18/66C08G18/48C08G18/32C08G18/12C08G18/42C08G18/44C08G18/10C08K3/36C08K3/22C08K3/26C09K8/508C09K8/88
CPCC08F283/006C08G18/6677C08G18/4808C08G18/4854C08G18/4833C08G18/12C08G18/6655C08G18/44C08G18/4277C08G18/6674C08G18/10C08K3/36C08K3/22C08K3/26C09K8/5083C09K8/882C09K2208/10C08K2201/011C08K2003/2227C08K2003/265C08F220/56C08F220/585C08G18/3206C08F220/06C08G18/3281
Inventor 曾斌徐太平李栓周京伟丁小惠袁发明
Owner BEIJING GEPETTO OIL TECH
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