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Method for preparing aluminum oxide ceramic filter plate based on aluminum ash

A technology of alumina ceramics and filter plates, which is applied in chemical instruments and methods, filtration separation, membrane filters, etc., can solve the problems of difficult output to meet demand, high production costs, and resource consumption of ceramic filter plates, and achieve fuel consumption less, reduce production costs, and save natural resources

Active Publication Date: 2020-11-24
ZHENGZHOU JINGWEI TECH & IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem to be solved by the present invention is to provide a method for preparing alumina ceramic filter plates based on aluminum ash, in order to solve the problems of resource consumption and production cost of ceramic filter plates in the prior art while realizing the harmless and resourceful utilization of aluminum ash. High cost and technical problems that the output is difficult to meet the demand

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Embodiment 1: the method for preparing alumina ceramic filter plate based on aluminum ash

[0026] Take 40 parts of aluminum ash (containing Al 5%, AlN 8%, Al 2 o 3 82%, SiO 2 0.5%, MgO 0.5%, CaO 0.5%, Fe 2 o 3 0.3%, the rest are chlorine salt and fluorine salt impurities), 60 parts of alumina (purity 99%) are mixed evenly, plus 3 parts of aluminum hydroxide binder, 1 part of aluminum fluoride, the above powder and water according to 1: 1 weight ratio, wet milled to 325 mesh with a ceramic ball mill jar to make a slurry.

[0027] Take a 30PPI polyurethane foam board and soak it in the above slurry. After the slurry is evenly soaked, take out the polyurethane foam board and squeeze out the excess slurry; dry the polyurethane foam board body soaked in the slurry for 24 hours naturally, and then dry it at 150°C 12h.

[0028] Then sintering is carried out at 1450°C. The specific heating system is: the heating rate is 30°C / h in the 0-300°C stage, the heating rate is ...

Embodiment 2

[0030] Embodiment 2: the method for preparing alumina ceramic filter plate based on aluminum ash

[0031] Take 90 parts of aluminum ash (containing Al 3%, AlN 5%, Al 2 o 3 85%, SiO 2 0.3%, MgO 0.5%, CaO 0.3%, Fe 2 o 3 0.3%, the rest are chloride salt and fluoride salt impurities), 10 parts of alumina (alumina purity 99%) are mixed evenly, plus 3 parts of aluminum hydroxide binder, 3.5 parts of aluminum fluoride, the above powder and water according to Mix at a ratio of 4:1, and wet grind to 325 mesh with a ceramic ball mill jar to make a slurry.

[0032] Take a 40PPI polyurethane foam board and soak it in the above slurry; after the slurry is evenly soaked, take out the polyurethane foam board and squeeze out the excess slurry; dry the polyurethane foam board body with the slurry in the air for 24 hours, and then dry it at 150°C for 12 hours .

[0033] Then sintering at 1550°C, the specific temperature rise curve is: 0-300°C, 30°C / h, 300-550°C, 20°C / h, 550-1000°C, 5°C / ...

Embodiment 3

[0035] Embodiment 3: the method for preparing alumina ceramic filter plate based on aluminum ash

[0036] Take 50 parts of aluminum ash (which contains Al 4%, AlN 9%, Al 2 o 3 81%, SiO 2 0.3%, MgO 0.5%, CaO 0.3%, Fe 2 o 3 0.3%, the rest are chloride salt and fluorine salt impurities), 50 parts of alumina (alumina purity ≥ 99%) are mixed evenly, plus 5 parts of aluminum hydroxide binder, 2.5 parts of aluminum fluoride, the above powder and water Mix according to the ratio of 3:2, and wet grind to 325 mesh with a ceramic ball mill jar to make a slurry;

[0037] Take a polyurethane foam board with a density of 60PPI and dip it into the above slurry; after the slurry is evenly soaked, take out the polyurethane foam board and squeeze out the excess slurry;

[0038] Air-dry the polyurethane foam slab body with slurry for 24 hours naturally, and dry it at 150°C for 12 hours;

[0039] Then sintering at 1650°C, the specific heating steps are: 0-300°C, 30°C / h, 300-550°C, 20°C / h,...

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PUM

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Abstract

The invention relates to a method for preparing an aluminum oxide ceramic filter plate based on aluminum ash. According to the method, 40-90% of the aluminum ash and 10-60% of aluminum oxide powder are mainly used as main materials, a binder (1-5% of the weight of the main materials) and an impurity removing agent (0.5-5% of the weight of the aluminum ash) are used as auxiliary materials, and thepowder and water are subjected to wet grinding according to a weight ratio of (1-5): 1 to prepare slurry; a polyurethane foam board is immersed into the slurry to prepare a blank; and airing, drying and oxygen-enriched sintering are performed. The porosity of the obtained aluminum oxide ceramic filter plate is greater than or equal to 85%, the alpha aluminum oxide phase content is greater than orequal to 85%, and the thermal shock resistance is greater than or equal to 5 times. According to the method, aluminum components in the aluminum ash are fully utilized, harmless and resource utilization of the aluminum ash is achieved, natural resources are saved, and the production cost is reduced (metal aluminum burns, a large amount of heat is released, fuel consumption is low in the preparation process, and the price of the raw material of the aluminum ash is far lower than that of alumina or aluminum oxide).

Description

technical field [0001] The invention relates to the technical field of filter material preparation, in particular to a method for preparing an alumina ceramic filter plate based on aluminum ash. Background technique [0002] Aluminum ash is a waste produced in the production process of the aluminum industry. Its main components are simple aluminum, aluminum compounds, silicon oxide, magnesium oxide, sodium salt, potassium salt, fluoride salt, titanium oxide, etc. It is toxic and flammable. The scum produced on the surface of the melt during the transfer, purification and removal of impurities in the electrolytic aluminum process, the scum (salt slag and aluminum ash) generated on the surface of the melt during the transfer, purification and removal of waste aluminum smelting melt, molten salt method The salt slag and secondary aluminum ash produced in the process of recovering metal aluminum from aluminum ash and aluminum slag are included in the 2019 edition of the "Nationa...

Claims

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Application Information

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IPC IPC(8): B01D39/20
CPCB01D39/2068B01D2239/10B01D2239/1208B01D2239/1291
Inventor 王玉于长军冯晓强牛文军乔继才
Owner ZHENGZHOU JINGWEI TECH & IND