A kind of intelligent superhydrophobic material and its preparation method and application
A super-hydrophobic and intelligent technology, applied in the field of materials, can solve the problems of polluting the environment, harmful to human health, etc., and achieve the effect of high adsorption efficiency, low production cost, and improved roughness
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0033] Example 1 Preparation of a smart superhydrophobic material S-3D-C-BiOCl@MS
[0034] (1) Preparation of S-3D-C-BiOCl@MS
[0035] Weigh 9.70 g of bismuth nitrate pentahydrate and dissolve it in 400 mL of 1 mol / L nitric acid under magnetic stirring conditions. When the bismuth nitrate was completely dissolved, 20 mL of 6 mol / L hydrochloric acid was added dropwise to the beaker and kept stirring for 2 h. After 2 h, the obtained white precipitate was separated with a centrifuge and washed with deionized water until neutral. Subsequently, 50 mL of 99.8% glacial acetic acid was added, left to stand for 4 h, centrifuged and washed with deionized water until neutral, and then dried in an oven at 60 ° C for 12 h to obtain hydroxylated 3D-C- BiOCl microspheres.
[0036] 0.750 g of 3D-C-BiOCl microspheres were weighed and placed in a beaker, and 30 mL of absolute ethanol and 225 μL of APTES were added thereto. The beaker was then placed in a water bath at 60°C for activation, a...
Embodiment 2
[0050] Example 2 Application of smart superhydrophobic material S-3D-C-BiOCl@MS in separation of oil-water mixture
[0051] 1. In order to investigate the practical application of superhydrophobic materials for oil spill cleaning, the situation of separating mixed oil from the mixture under natural conditions was simulated. Selective adsorption experiments were carried out by mixing n-hexane (light oil) and dichloromethane (heavy oil) stained with Sudan III with water, and the results were as follows: Figure 5 . like Figure 5 (a)-(b), the n-hexane phase floats above the water phase. When the material is in contact with it, the n-hexane is absorbed by the sponge under the capillary action, thereby realizing the static separation of n-hexane and water. as a comparison Figure 5 (c)-(d), the dichloromethane phase sinks below the water phase, and when the material is in contact with the dichloromethane, the dichloromethane is quickly sucked into the interior by the sponge, re...
Embodiment 3
[0054] Example 3 Application of intelligent superhydrophobic material S-3D-C-BiOCl@MS in catalytic degradation of water-soluble pollutants or oil-soluble pollutants
[0055] 1. The photocatalytic degradation ability of S-3D-C-BiOCl@MS material to water-soluble pollutants and oil-soluble pollutants was examined. The result is as Figure 8 , Figure 8 (a) Equipment for photocatalytic degradation experiments. Take a piece (1cm×1cm×1cm) of S-3D-C-BiOCl@MS material and place it in a reaction cell filled with 100mL, 10μg / mL, pH=10 methylene blue aqueous solution. The reaction cell system was placed in a dark place for 30 minutes to achieve the self-adsorption-desorption equilibrium of the material to methylene blue. After 30 min, the reaction cell was placed under the irradiation of a 500W xenon lamp to simulate sunlight. Take 4mL of methylene blue solution every 60min of irradiation and measure the content of methylene blue in the solution by ultraviolet spectrophotometer. The...
PUM
Login to View More Abstract
Description
Claims
Application Information
Login to View More