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Porous ceramic prepared by using plasma ball milling through low-temperature sintering and preparation method of porous ceramic

A technology of porous ceramics and plasma balls, applied in the field of porous ceramic materials, can solve the problems of low ball milling efficiency, insufficient ball milling energy, uneven mixing, etc., and achieve the effects of low cost, convenient material selection and good thermal stability.

Inactive Publication Date: 2021-03-05
DONGGUAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The plasma ball milling process can introduce cold-field discharge plasma into the mechanical vibration ball mill. With the help of the high-energy non-equilibrium plasma in the ball mill tank and the synergistic effect of the mechanical ball mill, it can promote powder refinement and active activation, which is beneficial to the chemical reaction and improves the ball milling efficiency. Efficiency, lower sintering temperature, thereby overcoming the shortcomings of traditional ball milling such as insufficient energy, low ball milling efficiency, uneven mixing, etc.

Method used

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  • Porous ceramic prepared by using plasma ball milling through low-temperature sintering and preparation method of porous ceramic
  • Porous ceramic prepared by using plasma ball milling through low-temperature sintering and preparation method of porous ceramic
  • Porous ceramic prepared by using plasma ball milling through low-temperature sintering and preparation method of porous ceramic

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preparation example Construction

[0069] refer to figure 1 , in one embodiment of the present invention, the preparation method of above-mentioned porous ceramics, comprises the following steps:

[0070] Step 1: The inorganic mixture is subjected to plasma ball milling to obtain raw materials;

[0071] Step 2: After the raw materials are dried, they are ground with cornstarch, sieved and dried to obtain a billet;

[0072] Step 3: Carrying out pressure-holding treatment on the billet to obtain a green body;

[0073] Step 4: The green body is sintered, kept warm and cooled in a high-temperature furnace to obtain porous ceramics.

[0074] In one embodiment of the present invention, in the plasma ball milling process described in step 1, the ball milling speed can be 800r / min, 900r / min, 1000r / min, 1100r / min, 1200r / min, 1500r / min, 2000r / min, etc. .

[0075] In the plasma ball milling process described in step 1, the ball milling time can be 10min, 15min, 17min, 19min, 20min, 25min, 28min, 30min, 32min, 40min, e...

Embodiment 1

[0092] The preparation method of the porous ceramic of the present embodiment comprises the following steps:

[0093] Pretreatment: The fine powder obtained from the construction waste treatment plant to remove organic and metal materials such as wood chips, steel bars, paper chips, etc., is placed in a planetary ball mill ball mill at 800r / min for 0.8h, and passed through a 30-mesh sieve. The construction waste after this pretreatment, its main component comprises the silica that accounts for construction waste weight percentage and is 47.8wt%, the alumina of 30.1wt%, the iron oxide of 3.0wt%, the calcium oxide of 9.8wt%, 1.8 wt% magnesium oxide, 5.1wt% sodium oxide, 1.2wt% potassium oxide, 1.2wt% loss on ignition.

[0094] Weigh 63wt% of pretreated construction waste, 12wt% of alumina, 18wt% of aluminum fluoride, 5wt% of boron oxide, 1wt% of cerium nitrate and 1wt% of molybdenum oxide to form an inorganic mixture.

[0095] Step 1: The inorganic mixture is subjected to plasma ...

Embodiment 2

[0101] The preparation method of the porous ceramic of the present embodiment comprises the following steps:

[0102] Pretreatment: The fine powder obtained from the construction waste treatment plant to remove organic and metal materials such as wood chips, steel bars, paper chips, etc., is placed in a planetary ball mill ball mill at 500r / min for 2.0h, and passed through a 30-mesh sieve. The construction waste after this pretreatment, its main component comprises the silica that accounts for construction waste weight percentage and is 57.3wt%, the alumina of 17.4wt%, the iron oxide of 3.2wt%, the calcium oxide of 7.2wt%, 6.1 wt% magnesium oxide, 3.0wt% sodium oxide, 1.8wt% potassium oxide, 3.0wt% loss on ignition.

[0103] 38wt% of pretreated construction waste, 46wt% of alumina, 10wt% of aluminum fluoride, 1wt% of boron oxide and 5wt% of molybdenum oxide were weighed to form an inorganic mixture.

[0104] Step 1: The inorganic mixture is subjected to plasma dry ball millin...

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Abstract

The invention provides a porous ceramic with high open porosity and high flexural strength. The porous ceramic is prepared by preparing inorganic mixture powder from construction wastes serving as main raw materials by mainly adopting a plasma ball milling process and then mixing, granulating, forming and sintering the inorganic mixture powder, wherein the mixing refers to mixing of an inorganic mixture with corn starch and activated carbon. According to the preparation method of the porous ceramic, cold field discharge plasma can be introduced into mechanical vibration ball milling by virtueof the plasma ball milling process, and powder refinement and active activation are promoted by virtue of the synergistic effect of high-energy non-equilibrium plasma of gas in a ball milling tank andmechanical ball milling, so a combination reaction is facilitated, ball milling efficiency is improved, and sintering temperature is reduced; and therefore, the defects of insufficient traditional ball milling energy, low ball milling efficiency, non-uniform mixing and the like in the prior art are overcome.

Description

technical field [0001] The invention relates to the field of porous ceramic materials, in particular to a porous ceramic prepared by using plasma ball milling for low-temperature sintering and a preparation method thereof. Background technique [0002] Porous ceramics are a new type of functional material. Due to their excellent properties such as excellent pore structure, good thermal stability, low density and good wear resistance, they are widely used in filtration, heat insulation, heat preservation, sound absorption, catalyst carrier, etc. Many fields have good development prospects. However, the disadvantages of the existing porous ceramic material preparation process, such as high raw material cost and high sintering temperature, severely limit its wide application. [0003] At present, with the continuous process of urbanization, urban construction is developing rapidly, and urban renewal is also in full swing, resulting in a large amount of construction waste. At ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B33/132C04B33/13C04B33/36C04B33/32C04B35/10C04B35/622C04B35/626C04B35/64C04B38/06
CPCC04B33/1324C04B33/131C04B33/1305C04B33/32C04B33/36C04B33/1328C04B35/10C04B35/62204C04B35/62615C04B35/64C04B38/068C04B2235/422C04B2235/3217C04B2235/445C04B2235/3409C04B2235/3229C04B2235/3256C04B2235/443C04B2235/96C04B2235/6562C04B2235/6565C04B2235/6567Y02P40/60
Inventor 花开慧王子鑫张泽钦余勇陈伟杰苏文正陈盛贵范洪波
Owner DONGGUAN UNIV OF TECH
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