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Preparation method of zinc-rich anticorrosive composite coating

A composite coating and zinc-rich technology, applied in anti-corrosion coatings, polyurea/polyurethane coatings, coatings, etc., can solve the problems of easy falling off of the coating film and low adhesion, and achieve improved water and oil repellency and electrical insulation High, low curing shrinkage effect

Inactive Publication Date: 2021-04-06
贾琛
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem to be solved by the present invention: the present invention provides a method for preparing a zinc-rich anticorrosive composite coating for the problems of low adhesion of traditional anticorrosion coatings and easy drop of the coating film under the impact of external force

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032]In parts by weight, weigh 60 parts of glycerol, 0.3 parts of methyltriethoxysilane, and 10 parts of nano-zinc oxide with a particle diameter of 20nm, add methyltriethoxysilane to glycerol, and Stir at a speed of 200r / min for 10min to obtain a modified solution. Add nano-zinc oxide to the modified solution, place it in a magnetic stirrer at room temperature and stir at a speed of 300r / min for 1h, filter with suction to obtain a solid, and place the solid in In an oven, dry at 70°C for 1 hour, and then grind in a grinder for 10 minutes to obtain modified nano-zinc oxide powder;

[0033] Then weigh 20 parts of epoxy resin, 6 parts of dimethyl polysiloxane, 60 parts of cyclopentanone, 1 part of vinyltriethoxysilane, 0.3 part of dibutyl dilauric acid in parts by weight Tin, add dimethylpolysiloxane and vinyltriethoxysilane to cyclopentanone, stir at 200r / min for 20min at room temperature to obtain a silane cyclopentanone solution, mix epoxy resin, dibutyl di Add tin laurate ...

Embodiment 2

[0036] In parts by weight, weigh 65 parts of glycerol, 0.4 part of methyltriethoxysilane, and 15 parts of nano-zinc oxide with a particle diameter of 25nm, add methyltriethoxysilane to glycerol, and Stir at a speed of 220r / min for 15min to obtain a modified solution. Add nano-zinc oxide to the modified solution, place it in a magnetic stirrer at room temperature and stir at a speed of 350r / min for 2h, and filter with suction to obtain a solid. Dry in an oven at 75°C for 2 hours, and then grind in a grinder for 15 minutes to obtain modified nano-zinc oxide powder;

[0037] Then weigh 25 parts of epoxy resin, 7 parts of dimethyl polysiloxane, 70 parts of cyclopentanone, 2 parts of vinyltriethoxysilane, 0.4 part of dibutyl dilauric acid in parts by weight Tin, add dimethylpolysiloxane and vinyltriethoxysilane to cyclopentanone, stir at 250r / min for 25min at room temperature to obtain a silane cyclopentanone solution, mix epoxy resin, dibutyl di Tin laurate was added to the silan...

Embodiment 3

[0040] In parts by weight, weigh 70 parts of glycerol, 0.5 part of methyltriethoxysilane, and 20 parts of nano-zinc oxide with a particle size of 30nm, add methyltriethoxysilane to glycerol, and Stir at a speed of 240r / min for 20min to obtain a modified solution. Add nano-zinc oxide into the modified solution, place it in a magnetic stirrer at room temperature and stir at a speed of 400r / min for 3h, filter with suction to obtain a solid, and place the solid in In an oven, dry at 80°C for 3 hours, and then grind in a grinder for 20 minutes to obtain modified nano-zinc oxide powder;

[0041] Then weigh 30 parts of epoxy resin, 8 parts of dimethylpolysiloxane, 80 parts of cyclopentanone, 3 parts of vinyltriethoxysilane, 0.5 part of dibutyl dilauric acid in parts by weight Tin, add dimethylpolysiloxane and vinyltriethoxysilane to cyclopentanone, stir at 300r / min for 30min at room temperature to obtain a silane cyclopentanone solution, mix epoxy resin, dibutyl di Add tin laurate t...

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Abstract

The invention relates to a preparation method of a zinc-rich anticorrosive composite coating, and belongs to the technical field of anticorrosive coatings, epoxy resin is used as a raw material to prepare the zinc-rich anticorrosive composite coating, the epoxy resin has very strong mechanical strength and wear resistance, and the epoxy resin contains a large amount of epoxy groups and can form very strong adhesion with a substrate; and the zinc-rich anticorrosive composite coating is prepared by modifying epoxy resin with organic silicon, the organic silicon and the epoxy resin have good complementarity in performance, an organic silicon chain segment is introduced through reaction of an active end group of a polysiloxane molecule and an epoxy group and a hydroxyl group in an epoxy resin molecule, the crosslinking degree of a cured product can be effectively increased, the zinc-rich anticorrosive composite coating is prepared by adding the polysulfone resin, a benzene ring of a rigid group is contained in a molecular chain of the polysulfone resin, and a sulfuryl group on a main chain forms a large conjugated structure, so that the coating has good stability and impact strength.

Description

technical field [0001] The invention relates to a preparation method of a zinc-rich anticorrosion composite coating, which belongs to the technical field of anticorrosion coatings. Background technique [0002] There are various types of corrosion of steel structures in marine engineering: galvanic corrosion, cavitation corrosion, abrasion corrosion and impact corrosion, hydrogen evolution corrosion, oxygen absorption corrosion, etc. Heavy-duty anti-corrosion coatings that are widely used mainly include: epoxy anti-corrosion coatings, fluorocarbon anti-corrosion coatings, polyurethane anti-corrosion coatings, rubber anti-corrosion coatings, organic (inorganic) silicon resin coatings, polyurea elastomer anti-corrosion coatings, glass flake heavy Anti-corrosion coatings and organic (inorganic) zinc-rich coatings. For the protection of marine metal substrates, methods such as the use of corrosion-resistant materials, the addition of corrosion inhibitors, metal surface modifica...

Claims

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Application Information

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IPC IPC(8): C09D5/10C09D187/00C09D181/06C09D175/04C09D7/62C08G81/00
CPCC08G81/00C08G2150/90C08K2003/0893C08K2003/2296C08K2201/011C08L2201/08C08L2205/035C09D5/106C09D175/04C09D181/06C09D187/005C09D7/62C09D7/67C08L81/06C08L75/04C08L71/02C08K9/06C08K3/22C08K3/08C08L87/005
Inventor 贾琛
Owner 贾琛