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Preparation method of hydrophilic polypropylene hollow fiber microporous membrane

A polypropylene, microporous membrane technology, applied in chemical instruments and methods, membranes, membrane technology and other directions, can solve the problems of expensive pharmaceuticals, poor practical operability, toxic solvents, etc., and achieves long-lasting hydrophilicity. The modification conditions are easy to control and the hydrophilization effect is obvious.

Active Publication Date: 2021-04-30
江西爱科道环境科技发展有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The preparation process of the invention is relatively complicated, and the solvent used in the solvent extraction is toxic, and its waste liquid will also pollute the environment, which is not conducive to environmental protection
[0004] In the patent CN 103933880A, a hydrophilic silane coupling agent is used to graft polypropylene raw materials to obtain a hydrophilic polypropylene hollow fiber membrane, but the grafting preparation process is complicated, resulting in large environmental pollution, expensive chemicals, and difficult to realize industrial production
[0005] In patent CN1792419, the prepared polyolefin hollow fiber microfiltration membrane is soaked in alcohol or surfactant, and then dies with membrane-making solution containing aldehydes, polyvinyl alcohol, polyethylene glycol or polyvinylpyrrolidone. end filtration or cross-flow filtration, and then make polyvinyl alcohol and aldehydes undergo cross-linking reaction and fix on the surface of the polymer membrane. Excessive polyvinyl alcohol buildup and low pure water flux
This method is relatively complicated to operate, requires high control precision, and is not practically operable, making it difficult to apply on a large scale.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0022] A kind of preparation method of hydrophilic polypropylene hollow fiber microporous membrane is characterized in that: comprise the steps:

[0023] Step 1, preparing polypropylene primary fibers by melting method;

[0024] In this embodiment, in step 1, the temperature process conditions in each section of the spinning machine when preparing polypropylene primary fibers are 140°C-240°C, the temperature of the spinneret is 80±5°C, and the winding speed is 370-420m / min, the heat treatment temperature is 120°C, and the time is 2h.

[0025] Step 2, preparation of fluorocarbon surfactant solution;

[0026] In this embodiment, the step 2 prepares a fluorocarbon surfactant solution, weighs 1-5g of fluorocarbon surfactant in a beaker, adds an appropriate amount of dichloromethane, stirs until completely dissolved, and then uses distilled water to prepare 1- 5g / L solution.

[0027] Step 3, hydrophilization treatment of polypropylene nascent fibers;

[0028] In this embodimen...

Embodiment 1

[0035] Step 1: Preparation of polypropylene spun fibers by melting method

[0036] Polypropylene primary fiber is prepared by melt spinning method. The temperature process conditions in each section of the spinning machine are 140°C-240°C, the temperature of the spinneret is 80±5°C, the winding speed is 370-420m / min, and the heat treatment temperature is 120°C. ℃, the time is 2h.

[0037] The second step: Fluorocarbon surfactant solution preparation

[0038] Accurately weigh 1g of fluorocarbon surfactant into a beaker, add a certain amount of dichloromethane, stir at room temperature until completely dissolved, and then prepare a solution with a concentration of 1g / L with distilled water.

[0039] Step 3: Hydrophilic treatment of polypropylene as-spun fibers

[0040] Soak the polypropylene primary fiber obtained by melt spinning in the first step into the fluorocarbon surfactant solution prepared in the second step, soak it for 2 hours, take it out and dry it naturally for t...

Embodiment 2

[0047] Step 1: Preparation of polypropylene spun fibers by melting method

[0048] Polypropylene primary fiber is prepared by melt spinning method. The temperature process conditions in each section of the spinning machine are 140°C-240°C, the temperature of the spinneret is 80±5°C, the winding speed is 370-420m / min, and the heat treatment temperature is 120°C. ℃, the time is 2h.

[0049] The second step: Fluorocarbon surfactant solution preparation

[0050] Accurately weigh 2g of fluorocarbon surfactant into a beaker, add a certain amount of dichloromethane, stir at room temperature until completely dissolved, and then prepare a solution with a concentration of 2g / L with distilled water.

[0051] Step 3: Hydrophilic treatment of polypropylene as-spun fibers

[0052]Soak the polypropylene primary fiber obtained by melt spinning in the first step into the fluorocarbon surfactant solution prepared in the second step, soak it for 2 hours, take it out and dry it naturally for th...

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Abstract

The invention belongs to the technical field of water treatment via polypropylene hollow fiber microporous membranes, and particularly relates to a preparation method of a hydrophilic polypropylene hollow fiber microporous membrane. The preparation method comprises the following steps: step 1, preparing polypropylene nascent fibers by using a melting method; 2, preparing a fluorocarbon surfactant solution; 3, carrying out hydrophilization treatment on the polypropylene nascent fibers; 4, performing heat treatment, stretching and heat setting to obtain a polypropylene hollow fiber microporous membrane; and step 5, conducting hydrophilic modification on the polypropylene hollow fiber microporous membrane. Through secondary hydrophilic modification of the polypropylene nascent fibers and the formed polypropylene hollow fiber microporous membrane, hydrophilic groups introduced to the surfaces of membrane filaments, and hydrophilic groups are introduced to the internal structures of the membrane filaments, so the hydrophilization effect of the membrane is more obvious, and hydrophilicity lasting time is longer; and a modification process is carried out in a water phase, reaction conditions are mild, the modification process and the modification conditions are easy to control, and operation steps are simple.

Description

technical field [0001] The invention belongs to the technical field of polypropylene hollow fiber microporous membrane water treatment, and in particular relates to a preparation method of a hydrophilic polypropylene hollow fiber microporous membrane. Background technique [0002] Membrane separation technology is an advanced technology developed in recent years with high efficiency and low energy consumption. It is widely used in petrochemical wastewater treatment, black and odorous water treatment, seawater desalination and other fields due to its convenient maintenance and simple operation. Among them, hollow fiber Membranes have the advantages of high packing density per unit volume, high filtration and separation efficiency, small equipment, simple structure, and easy operation, and have a wide range of applications in separation technologies such as microfiltration, ultrafiltration reverse osmosis, nanofiltration, and membrane bioreactors. application. Polypropylene h...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D67/00B01D69/02B01D69/08B01D71/26
CPCB01D71/26B01D69/02B01D69/08B01D67/0002B01D67/0081B01D2325/36Y02A20/131
Inventor 王晓龙李丹郑先强刘沐之谷国军武彪
Owner 江西爱科道环境科技发展有限公司