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Nano-composite polypropylene composite material with high thermal conductivity, and preparation method thereof

A technology of nanocomposite and composite materials, which is applied in the field of nanocomposite polypropylene composite materials with high thermal conductivity and its preparation. It can solve the problems of increased working temperature, poor heat dissipation performance, and low thermal conductivity, and achieve thermal conductivity and thermal performance. Improvement, high thermal conductivity, excellent thermal conductivity effect

Inactive Publication Date: 2021-06-25
HARBIN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In recent years, with the continuous development of industry and technology, ordinary polymer materials are difficult to meet the needs of the future development of electric power and electronics industries, especially the sharp increase in operating frequency, the rapid accumulation and increase of heat generated by electronic equipment, and the temperature of the working environment. Rapidly changing to high temperature direction, in order to ensure the normal operation of electronic components with high reliability for a long time, it is necessary to prevent the continuous rise of the working temperature, so the ability to dissipate heat in time becomes an important factor affecting its service life, and develop polymer materials with high thermal conductivity It is an urgent problem that researchers need to solve
[0003] Polypropylene has the advantages of light weight, corrosion resistance, easy processing, good mechanical balance, and low price. The second largest general-purpose plastic of ethylene, but the thermal conductivity of polypropylene is low, only 0.24W / m·k, and the heat dissipation performance is poor, which is difficult to meet the rapid development of modern industry and technology

Method used

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  • Nano-composite polypropylene composite material with high thermal conductivity, and preparation method thereof
  • Nano-composite polypropylene composite material with high thermal conductivity, and preparation method thereof
  • Nano-composite polypropylene composite material with high thermal conductivity, and preparation method thereof

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preparation example Construction

[0029] The preparation method of the high thermal conductivity functionalized nano zeolite / polypropylene composite material of the present invention mainly includes the following two steps:.

[0030] (1) Disperse amino-functionalized nano-zeolite particles in a solvent, add quantitative 3,5-diaminobenzoic acid and triphenyl phosphite, react at 110°C for 6 hours under a nitrogen atmosphere, centrifuge, wash, and dry Obtain hyperbranched polyarylamide graft functionalized nano zeolite particles;

[0031] (2) Disperse the functionalized nano-zeolite particles grafted with hyperbranched polyaramid into ethanol solvent, and oscillate ultrasonically for 30 minutes; then heat the rheometer to 110°C, start the motor and put a certain amount of polypropylene pellets Carry out smelting, and after the pellets are fully melted, the nano-zeolite ethanol solution grafted with hyperbranched polyaramid and functionalized is added to the silo for mixing according to a certain doping ratio; aft...

Embodiment 1

[0035] The preparation method of the high thermal conductivity functionalized 4A type zeolite / polypropylene polymer composite material in this example is as follows:

[0036] Pretreatment: Take 10g of 4A zeolite, mix it with 25ml of absolute ethanol, put it into a planetary ball mill and grind it for 10 hours to make the particles reach the nanometer level and disperse evenly, and then follow the ethanol: KH550: water = 7: The ratio of 2:1 is configured as 10ml solution A, 10g4A nano-zeolite particles are added to 250ml ethanol solution, after ultrasonic vibration for 30min, it is placed in a three-necked beaker, and then solution A is added to the three-necked beaker, at 65℃ The reaction was carried out for 10 h under a nitrogen atmosphere, and the obtained product was centrifuged, washed, and vacuum-dried to obtain an amino-functionalized 4A nano-zeolite.

[0037] (1) Disperse amino-functionalized 4A nano-zeolite particles in a solvent, add quantitative 3,5-diaminobenzoic ac...

Embodiment 2

[0044] The preparation method of the high thermal conductivity functionalized NaY type zeolite / polypropylene polymer composite material in this embodiment is as follows:.

[0045] Pretreatment: Take 10g of NaY zeolite, mix it with 25ml of absolute ethanol, and put it into a planetary ball mill for 10 hours of grinding, so that the particles reach the nanometer level and disperse evenly, and then according to ethanol: KH550: water = 7: The ratio of 2:1 is configured as 10ml solution A. Add 10g NaY nano-zeolite particles to 250ml ethanol solution. After ultrasonic vibration for 30min, put it in a three-necked beaker, then add solution A to the three-necked beaker, and heat at 65℃ React for 10 h under a nitrogen atmosphere, and the obtained product is centrifuged, washed, and vacuum-dried to obtain an amino-functionalized NaY nano-zeolite.

[0046] (1) Disperse amino-functionalized NaY-type nano-zeolite particles in a solvent, add quantitative 3,5-diaminobenzoic acid and tripheny...

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Abstract

The invention discloses a nano-composite polypropylene composite material with high thermal conductivity. The nano-composite polypropylene composite material comprises, by mass, 80-95% of polypropylene and 5-20% of hyperbranched aromatic polyamide grafted nano zeolite particles. The invention also discloses a preparation method of the high-thermal-conductivity nano-composite polypropylene. The hyperbranched aromatic polyamide grafted nano zeolite particles and the polypropylene are used as raw materials to obtain the high-thermal-conductivity functionalized nano zeolite particle / polypropylene polymer composite material, the composite material has very high thermal conductivity, and compared with a traditional filler direct blending method, the thermal conductivity and the heat engine performance are obviously improved. The polypropylene composite material disclosed by the invention has excellent heat-conducting property, and the heat conductivity and mechanical property of a polymer matrix can be greatly improved under the condition of low heat-conducting filler mixing amount, so that the polypropylene composite material has wide application value in the fields of machinery, cables, chemical engineering and the like. The preparation method disclosed by the invention is simple and easy to operate, strong in controllability and capable of realizing large-scale production.

Description

technical field [0001] The invention belongs to the technical field of electrical insulating materials, and relates to a nanocomposite polypropylene composite material with high thermal conductivity and a preparation method thereof. Background technique [0002] In recent years, with the continuous development of industry and technology, ordinary polymer materials are difficult to meet the needs of the future development of electric power and electronics industries, especially the sharp increase in operating frequency, the rapid accumulation and increase of heat generated by electronic equipment, and the temperature of the working environment. Rapidly changing to high temperature direction, in order to ensure the normal operation of electronic components with high reliability for a long time, it is necessary to prevent the continuous rise of the working temperature, so the ability to dissipate heat in time becomes an important factor affecting its service life, and develop po...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08L87/00C08G83/00C09K5/14
CPCC08L23/12C08G83/001C09K5/14
Inventor 韩柏侯尚振
Owner HARBIN UNIV OF SCI & TECH
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