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Conductive ink with temperature-limiting properties, preparation method and heating tile

A kind of conductive ink and characteristic technology, applied in the direction of ink, electric heating device, ohmic resistance heating, etc., can solve the problem of short cycle life of heating tiles, and achieve the effect of stable self-limiting temperature effect, preventing circuit overheating, and high cycle life.

Active Publication Date: 2022-01-11
清远市简一陶瓷有限公司 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The main purpose of the present invention is to provide a conductive ink with temperature-limiting characteristics and its preparation method, aiming to improve the technical problem of short cycle life of existing heating tiles

Method used

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  • Conductive ink with temperature-limiting properties, preparation method and heating tile
  • Conductive ink with temperature-limiting properties, preparation method and heating tile
  • Conductive ink with temperature-limiting properties, preparation method and heating tile

Examples

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preparation example Construction

[0041] A preparation method of conductive ink with temperature-limiting characteristics, comprising the steps of:

[0042] S1. According to the following mass percentages, 12%-40% of carbon-based conductive filling materials, 5%-8% of conductive auxiliary materials, 7%-13% of temperature-limiting materials, 10%-28% of resin bonding materials, and 9.5% of additives 14% and 28% to 50% of the solvent are mixed and ball milled for more than 30 minutes to make the grinding and dispersion to a particle size of <10um to obtain the conductive ink with a viscosity of 80 to 120pa·s with temperature-limiting characteristics;

[0043] The conductive auxiliary material is nickel-chromium alloy powder, the temperature-limiting material is titanium diboride heat-sensitive conductive material, and the Curie temperature of the titanium diboride heat-sensitive conductive material is 60-80°C;

[0044] The conductive ink with temperature-limiting characteristics has a resistivity of 2.3-2.6Ω·mm a...

Embodiment 1

[0057] A preparation method of conductive ink with temperature-limiting characteristics, comprising the steps of:

[0058] S1. According to the following mass percentages, 15% of carbon-based conductive filler material, 6% of nickel-chromium alloy powder conductive auxiliary material, 10% of temperature-limiting material (titanium diboride heat-sensitive conductive material), 15% of resin adhesive material, isopropyl Tris(dioctylpyrophosphate acyloxy) titanate coupling agent 0.6%, stearic acid 1.5%, ammonium polyphosphate flame retardant 8.9%, propylene glycol diacetate 17% and isophorone 26% After mixing, ball mill for more than 30 minutes to make it grind and disperse to a particle size of <10um to obtain a conductive ink with temperature-limiting characteristics;

[0059] The particle size of the nickel-chromium alloy powder is 35 μm, the fluidity is 28s / 50g, and the bulk density is 6.5g / cm 3 ;

[0060] The carbon-based conductive filling material is prepared from raw mat...

Embodiment 2

[0068] A preparation method of conductive ink with temperature-limiting characteristics, comprising the steps of:

[0069] S1. According to the following mass percentages, 18% of carbon-based conductive filler material, 7% of nickel-chromium alloy powder conductive auxiliary material, 11% of temperature-limiting material (titanium diboride heat-sensitive conductive material), 18% of resin adhesive material, isopropyl Tris(dioctyl pyrophosphate acyloxy) titanate coupling agent 1%, stearic acid 1%, ammonium polyphosphate flame retardant 8%, tripropylene dibutyl ether 36%, ball milled for more than 30min after mixing, Make it grind and disperse to a particle size of <10um to obtain a conductive ink with temperature-limiting characteristics;

[0070] The particle size of the nickel-chromium alloy powder is 40 μm, the fluidity is 23s / 50g, and the bulk density is 5g / cm3;

[0071] The carbon-based conductive filling material is prepared from raw materials with the following mass per...

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Abstract

The present invention relates to the technical field of conductive ink, in particular to a conductive ink with temperature-limiting characteristics, a preparation method and a heating tile, which are prepared from the following raw materials in mass percentage: 12% to 40% of carbon-based conductive filling material, 5% of conductive auxiliary material % to 8%, temperature-limiting material 7% to 13%, resin bonding material 10% to 28%, additive 9.5% to 14%, solvent 28% to 50%; the conductive auxiliary material is nickel-chromium alloy powder, and the The temperature-limiting material is titanium diboride heat-sensitive conductive material, and the Curie temperature of the titanium diboride heat-sensitive conductive material is 70-90°C. By adding titanium boride heat-sensitive conductive material and nickel-chromium alloy powder, the conductive ink has a self-limiting temperature function, and the self-limiting temperature effect is stable, preventing circuit damage and heat attenuation caused by circuit overheating. Moreover, when used as a heating tile, the conductive ink also has the characteristics of high cycle life and fatigue resistance. The PTC effect of the conductive ink can withstand multiple overheating shocks without failure.

Description

technical field [0001] The invention relates to the technical field of conductive ink, in particular to a conductive ink with temperature-limiting characteristics, a preparation method and a heating tile. Background technique [0002] Heating film is one of the commonly used heating materials for heating ceramics. The heating film contains a layer of graphene film resistors, which are printed on PET films with graphene resistor paste. When external substances such as water vapor infiltrate into the heating film during the use of the heating ceramics, the water vapor will cause some metal components to rust, and the rusted components may be damaged. When some debris falls and covers the heating film, the heating film will Local high temperature will be generated in this area. Generally, the accumulated heat temperature of thin film resistors cannot exceed the softening point temperature of the substrate (below 130°C), otherwise overheating will cause the heating film (PET fil...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D11/52C09D11/102C09D11/106C09D11/03H05B3/14
CPCC09D11/52C09D11/102C09D11/106C09D11/03H05B3/141
Inventor 区邦熙李志林邓波苏伟劲朱联烽李志豪
Owner 清远市简一陶瓷有限公司
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