A kind of high ductility cement-based composite material and preparation method thereof
A composite material and cement-based technology, applied in physical treatment, textiles and papermaking, fiber types, etc., can solve problems such as poor fracture toughness, building hazards, and easy cracking, and achieve the effect of improving strength and toughness
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[0037] Preparation examples of starting materials and intermediates
[0038] raw material
[0039] The cement is PO5 2.5 cement;
[0040] Fly ash is first-grade fly ash;
[0041] The mineral powder is S105 mineral powder;
[0042] The water reducing agent is a high-efficiency polycarboxylate water reducing agent;
[0043] Starch ether is potato starch ether;
[0044] Polyoxyethylene polyoxypropylene block copolymer, CAS No. 9003-11-6, molecular weight 102.132;
[0045] Fatty alcohol polyoxyethylene ether phosphate potassium salt, model MOA3PK;
[0046] The higher alcohol phosphate salt is cetostearyl alcohol phosphate salt;
[0047] The emulsifier is fatty alcohol polyoxyethylene ether, the model is AE09.
preparation example 1
[0050] The preparation method of modified polyvinyl alcohol fiber:
[0051] A1. Mix 10kg polyoxyethylene polyoxypropylene block copolymer, 10kg fatty alcohol polyoxyethylene ether phosphate potassium salt, and 10kg higher alcohol phosphate ester salt, then add 2000kg emulsifier and mix to obtain dispersant;
[0052] A2. Soak the polyvinyl alcohol fiber in acetone solution, and after heating and refluxing for 5 hours, take out the polyvinyl alcohol fiber, wash it twice with clean water, and then dry it at 100°C to constant weight;
[0053] A3. Mix the polyvinyl alcohol fiber after A2 treatment with the dispersant obtained from A1, the solid-liquid ratio is 1:200, shake at room temperature for 0.5h, and the shaking speed is 135r / min, then take out the sample and dry it to constant weight at 100℃ , to obtain modified polyvinyl alcohol fibers
preparation example 2
[0055] The preparation method of modified polyoxymethylene fiber:
[0056] B1. Wash the polyoxymethylene fiber with absolute ethanol, and then vacuum dry the polyoxymethylene fiber at 90°C for 2 hours;
[0057] B2. Treat the POM fiber cleaned by B1 in a plasma processor for 60s. The processing parameters of the plasma processor are: air atmosphere, 400W power, and a distance between two electrodes of 3mm;
[0058] B3. The polyoxymethylene fibers treated by B2 are immediately immersed in nano-SiO with a mass concentration of 3% 2 In the aqueous solution, and at 60 °C, the reaction was oscillated for 3 hours at a speed of 135 r / min, and then the polyoxymethylene fiber was taken out, washed three times with clean water, and dried at 90 °C to constant weight to obtain the modified polyoxymethylene fiber.
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