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Cleaning method for semiconductor materials

A semiconductor and post-cleaning technology, which is applied in semiconductor/solid-state device manufacturing, chemical instruments and methods, detergent compounding agents, etc., can solve the problem of rapid failure of solution cleaning ability, increase the surface roughness of silicon wafers, and environmentally unfriendly chemical reagents etc. to achieve the effect of effectively removing metal ions, promoting saponification reaction, and reducing environmental pollution

Active Publication Date: 2022-06-21
CHONGQING GENORI IND CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Soaking and cleaning is carried out in a strong acid mixture, and APM is used to remove particles, some organic matter and some metals on the surface of the silicon wafer, but this solution will increase the roughness of the silicon wafer surface
HPM and DHF are used to remove metal contamination on the surface of silicon wafers, but HPM uses high-concentration strong acid, which is easy to decompose and volatilize. It has poor stability during use, low service life, and rapid failure of solution cleaning ability.
Therefore, the currently used RCA cleaning process needs to use a lot of chemical reagents that are not friendly to the environment. If used in large quantities, the damage to the environment will be serious
And according to the research report, the SC1 solution can effectively remove the particles on the surface of the semiconductor silicon body, but at the same time it brings another source of foreign metal impurities, such as iron, zinc and aluminum, etc.
Although the SC1 solution can basically remove particles with a particle size larger than 0.5 μm on the surface of the silicon body, it increases the deposition of particles with a particle size smaller than 0.5 μm.

Method used

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  • Cleaning method for semiconductor materials
  • Cleaning method for semiconductor materials
  • Cleaning method for semiconductor materials

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] Alkaline degreasing washes for silicon, quartz, ceramic semiconductor materials:

[0044] Potassium hydroxide 3%, potassium carbonate 3.6%, dipotassium dihydrogen pyrophosphate 2.1%, potassium tripolyphosphate 2%, acetal acetal 4.5%, sodium dodecyl diphenyl ether disulfonate 1.8%, H-662.5 % (Dow Chemical TRITON H-66), aliphatic amine polyoxyethylene ether 2%, and the balance is water; all percentages are calculated by mass and volume percentage, the same below. Immerse several silicon product samples (quartz wafers after etching, silicon wafers, polished silicon wafers, silicon machined surfaces, quartz machined surfaces, respectively P-type monocrystalline silicon, polycrystalline silicon, etc.) Ultrasonic immersion cleaning, the temperature is controlled at 35-50 ℃, cleaning is about 15-20 minutes, and deionized water is rinsed after cleaning. After cleaning, there is no grease residue from the appearance of the product, and there is no obvious foreign matter at 1000...

Embodiment 2

[0048] Alkaline degreasing washes for silicon, quartz, ceramic semiconductor materials:

[0049] Potassium hydroxide 3%, potassium carbonate 4%, dipotassium dihydrogen pyrophosphate 3%, potassium tripolyphosphate 2.8%, acetone acetal 5.2%, sodium dodecyl diphenyl ether disulfonate 1.6%, H-662 %, aliphatic amine polyoxyethylene ether 1.6%, and the balance is deionized water; immerse several silicon product samples (same as Example 1) in the above-mentioned alkaline degreasing lotion, soak and clean with ultrasonic waves, and control the temperature at 35-50 ° C , Clean for about 15-20 minutes, rinse with deionized water after cleaning.

[0050] The samples after the degreasing treatment of Example 1 and Example 2 were detected, figure 1 The appearance diagrams of 2 silicon wafer samples before and after degreasing and cleaning are shown, and the third row is a comparison diagram of a market degreasing solution under the same conditions. figure 2 It is a 1000x high-definition...

Embodiment 3

[0053] Metal ion cleaning solution suitable for silicon, quartz and ceramic semiconductor materials, including acid A cleaning solution, neutral cleaning solution, and acid B cleaning solution, which can treat metal elements on the surface of samples, including 30 metal elements required by the semiconductor industry Metal elements, specifically Al, Sb, As, Ba, Be, Bi, B, Cd, Ca, Cr, Co, Cu, Ga, Ge, Fe, Pb, Li, Mg, Mn, Mo, Ni, K, Na , Sr, Sn, Ti, W, V, Zn, Zr.

[0054] The sample is first soaked and cleaned with acid A lotion at room temperature, the cleaning time is about 15-20 minutes, and then rinsed with deionized water; Clean for about 15-20 minutes, rinse with deionized water after cleaning; finally put it in acid B lotion for immersion cleaning, control the temperature at room temperature, clean for about 15-20 minutes, and rinse with deionized water after cleaning. Among them, the acid A washing solution is: ammonium fluoride 3.9%, fluorosilicic acid 2%, H-951.2% (Ger...

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PUM

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Abstract

The invention relates to a cleaning method for semiconductor materials. The specific steps are as follows: first immerse the semiconductor material in an alkaline degreasing lotion for degreasing treatment, and then rinse it with deionized water; then perform metal ion removal treatment, and sequentially wash the semiconductor material Soak and clean with acidic lotion A, rinse with deionized water after cleaning; then soak and clean with neutral lotion, rinse with deionized water after cleaning; finally soak in acidic B lotion for cleaning, rinse with deionized water after cleaning That's it. The cleaning method provided by the invention greatly reduces the use concentration of strong acid, reduces environmental pollution and corrosivity to human body. The lotion has good stability, does not easily decompose and volatilize, improves the service life of the lotion, is less corrosive to silicon products, and does not increase the Ra of the product after cleaning.

Description

technical field [0001] The invention belongs to the technical field of semiconductor materials, and relates to a cleaning method for semiconductor materials. Background technique [0002] In the manufacturing process of semiconductor devices such as flat panel displays such as TFT liquid crystals, microprocessors, memories, and CCDs, silicon, silicon oxide (SiO 2 ), glass, etc., the surface of the substrate is patterned or formed into a thin film with a size of submicron or even 1 / 4 micron. Therefore, in these manufacturing processes, it is extremely important to remove the tiny contamination on the surface of the substrate to make the surface of the substrate highly clean; the same equipment consumables also need to be highly cleaned, and the control of particulate matter in semiconductor engineering is the key point. Objects, the products used in the project should be cleaned by the cleaning process to remove the factors that affect the particulate matter. With the devel...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L21/02C11D1/83C11D1/14C11D1/00C11D3/04C11D3/06C11D3/10C11D3/20C11D3/39C11D3/60C11D7/26C11D7/60
CPCH01L21/02057C11D1/83C11D3/044C11D3/06C11D3/10C11D3/2096C11D1/14C11D3/046C11D7/264C11D7/261C11D7/263C11D7/267C11D1/00C11D3/042C11D3/3942C11D3/3947C11D1/78C11D1/72C11D1/24C11D2111/22
Inventor 王燕清杨佐东
Owner CHONGQING GENORI IND CO LTD
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