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Multi-solid-waste admixture, preparation method thereof and cement mortar
Active Publication Date: 2022-03-25
NORTHEASTERN UNIV
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[0003] my country's annual discharge of iron tailings is hundreds of millions of tons, but the comprehensive utilization rate of iron tailings is less than 30%.
Oil shaledry distillation or direct combustion produces a large amount of ash, 1 ton of raw ore produces about 0.7 to 0.9 tons of semi-coke, which requires a large amount of land to be stacked in the open air, causing secondary pollution such as dust and water, and the pollution problem is prominent
Although there are currently researches on the use of oil shale semi-coke as building materials, due to its low activity, it is difficult to use it in large quantities, and there is a problem of insufficient strength in the later stage
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preparation example Construction
[0045] The present invention provides a preparation method for the multi-solid waste admixture described in the above technical solution, comprising the following steps:
[0046] Mixing the modified oil shale semi-coke-iron tailings and carbide slag for ball milling to obtain a ball mill;
[0048] The invention mixes the modified oil shale semi-coke-iron tailings and calcium carbide slag for ball milling to obtain ball milling material. In the present invention, the ball-to-material ratio of the ball milling is preferably 1:1; the time of the ball milling is preferably 25 to 35 minutes, more preferably 30 minutes, and the effect of the ball milling is not good if the time is short, and the agglomeration effect will be caused if the time is long; The ball milling is preferably carried out in a star ball mill. In the present invention, the prop...
Embodiment 1
[0054] A kind of multi-solid waste admixture, raw material is as follows:
[0056] Iron tailings: the mass content of silicon dioxide in iron tailings is 50-60%, the mass content of aluminum oxide is 8-15%, the mass content of iron oxide is 10-15%, and the mass content of calcium oxide is 8-15%. 15%, the mass content of magnesiumoxide is 5-10%; crush and sieve the particles with a particle size below 0.75mm;
[0057] Calcium carbide slag: the mass content of calcium oxide in calcium carbide slag is 90-95%, the mass content of silicon dioxide is 5-10%, the mass content of aluminum oxide is 1-2%, and the mass content of iron oxide is 1-2%. ;Crush and sieve out particles with a particle size below 0.75mm;
[0069] A kind of multi-solid waste admixture, raw material is the same as embodiment 1. The preparation method is as follows:
[0070] (1) Mix 85g of oil shale semi-coke particles with 15g of iron tailings and calcinate at 600°C for 2 hours to obtain modified oil shale semi-coke-iron tailings powder; modified oil shale semi-coke- In the iron tailings, particles with a particle size greater than 0 and less than or equal to 0.1mm accounted for 40-60wt%, particles with a particle size greater than 0.1mm and less than or equal to 0.3mm accounted for 20-30wt%, and particles with a particle size greater than 0.3mm and less than or equal to 1.5mm Accounting for 20-30wt%;
[0071] (2) Take 20g of calcium carbide slag particles and 100g of modified oil shale semi-coke-iron tailings powder particles and mix them into a star-shaped ball mill (the ratio of ball to material is 1:1) for ball milling for 30 minutes to obtain ball mill powder; The proportion of particles with a particle siz...
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Abstract
The invention provides a multi-solid-waste admixture, a preparation method thereof and cementmortar, and relates to the technical field of civil engineering. The multi-solid-waste admixture provided by the invention comprises the following raw materials in parts by mass: 80-120 parts of modified oil shale semicoke-iron tailings, 15-40 parts of carbideslag, 20-40 parts of high-calciumfly ash, 2-5 parts of an alkaline activator and 1-3 parts of a water reducing agent, the modified oil shale semi-coke-iron tailings are obtained by mixing oil shale semi-coke and iron tailings and calcining the mixture at a high temperature of 500-700 DEG C; the mass ratio of the oil shale semicoke to the iron tailings is (80-100): (10-20). The admixture provided by the invention mainly adopts industrial wastes, effectively solves the problem of accumulation of the oil shale semicoke, the carbideslag and the iron tailings, turns waste into wealth, and has environmental benefits, economic benefits and social benefits; and the later strength of the material can be improved while the large mixing amount of industrial solid waste is realized.
Description
technical field [0001] The invention relates to the technical field of civil engineering, in particular to a multi-solid waste admixture, a preparation method thereof and cementmortar. Background technique [0002] Polyvinyl chloride (PVC) is a widely used chemical product. About 1.5-1.9 tons of carbideslag is discharged per ton of PVC produced. Due to the high transportation costs and the large number of impurities in the carbide slag itself, its comprehensive utilization rate is not high. Landfill or stockpiling is usually used, which is likely to cause surface and groundwaterpollution and cause great damage to the ecological environment. Therefore, calcium carbide slag urgently needs to be treated as a resource to eliminate the negative impact on the ecological environment. [0003] my country's annual discharge of iron tailings is hundreds of millions of tons, but the comprehensive utilization rate of iron tailings is less than 30%. While bringing economic benefits,...
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Application Information
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