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Carbon-based seaweed silicon-selenium suspended fertilizer, preparation method thereof and application of carbon-based seaweed silicon-selenium suspended fertilizer in selenium enrichment and cadmium reduction of rice

A technology of carbon-based seaweed and seaweed silicon, which is applied in the fields of application, rice cultivation, liquid fertilizer, etc., can solve the problems of single nutrient composition, influence on fertilizer efficiency, and lack of ingredients, etc., to reduce plant cadmium absorption, reduce rice cadmium absorption, use method simple effect

Pending Publication Date: 2022-04-05
SOUTH CHINA AGRI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, most of the silicon and selenium fertilizers currently on the market have single nutritional components and need to be used in conjunction with other fertilizers to meet the nutrient requirements of crops during growth; and the lack of components that can control nutrient release may easily cause premature loss of nutrients
At the same time, conventional selenium fertilizers are susceptible to valence changes due to external pH and redox environments, thereby affecting fertilizer efficiency and even producing toxic effects. In addition, conventional silicon fertilizers also have poor solubility under weakly acidic to neutral conditions, and the solution is prone to polymerization. Shen's question
Although zero-valent nano-selenium can overcome the potential toxicity of excessive selenium to crops, its corresponding bioavailability is not as good as that of acid radical ions and organic amino acids.

Method used

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  • Carbon-based seaweed silicon-selenium suspended fertilizer, preparation method thereof and application of carbon-based seaweed silicon-selenium suspended fertilizer in selenium enrichment and cadmium reduction of rice
  • Carbon-based seaweed silicon-selenium suspended fertilizer, preparation method thereof and application of carbon-based seaweed silicon-selenium suspended fertilizer in selenium enrichment and cadmium reduction of rice
  • Carbon-based seaweed silicon-selenium suspended fertilizer, preparation method thereof and application of carbon-based seaweed silicon-selenium suspended fertilizer in selenium enrichment and cadmium reduction of rice

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] Embodiment 1: Preparation of different carbon-based seaweed silicon selenium suspensions

[0049] Suspending agent 1 is prepared by the following steps:

[0050] (1) Add 10kg of kaolin, 2.5kg of trimeric gulose-mannose-gulose and 2.5kg of tetrameric mannose into 238L of secondary water in sequence, and fully stir and dissolve at 50-60°C to obtain seaweed carbon base crosslinker solution.

[0051] (2) Dissolve 52.93L 100g / L Na at 25-35°C 2 SeO 3 (Sodium selenite) solution is mixed with 52.93L 0.1mol / L riboflavin, and add 40.31kg K 3 [Fe(CN) 6 ] (potassium ferricyanide).

[0052] (3) Add 211.72L 5.89mol / L H at 45-55°C 2 SiO 3 (Silicic acid) solution and an appropriate amount of 4.81mol / L ammonia mixture solution, so that the total mass of the silicon-selenium sol after fully stirring and mixing is 900kg, and the silicon-selenide sol is obtained.

[0053] (4) Add the seaweed carbon-based cross-linking agent solution prepared in step (1) to the silicon-selenium sol ...

Embodiment 2

[0109] Embodiment 2: Preparation of different carbon-based seaweed silicon selenium suspension fertilizers

[0110] According to the results of Example 1, select a stable and representative suspending agent solution for the next step of fertilizer preparation.

[0111] Suspension compound fertilizer A: mix 900kg suspending agent 1 with 87.5kg KH 2 PO 4 , 87.5kg NH 4 h 2 PO 4 Fully stir evenly under the condition of 50-60°C.

[0112] Suspension Compound Fertilizer B: Mix 900kg of Suspending Agent 3 with 87.5kg of KH 2 PO 4 , 87.5kg NH 4 h 2 PO 4 Fully stir evenly under the condition of 50-60°C.

[0113] Suspension compound fertilizer C: mix 900kg suspending agent 4 with 87.5kg KH 2 PO 4 , 87.5kg NH 4 h 2 PO 4 Fully stir evenly under the condition of 50-60°C.

[0114]Suspension Compound Fertilizer D: Mix 900kg Suspended Agent 5 with 87.5kg KH 2 PO 4 , 87.5kg NH 4 h 2 PO 4 Fully stir evenly under the condition of 50-60°C.

[0115] Suspension Compound Fertili...

Embodiment 3

[0134] Embodiment 3: Potted rice leaf spray test

[0135] This experiment was carried out in the network room of the College of Resources and Environment, South China Agricultural University, Guangzhou City, Guangdong Province in January 2019. The soil properties used in the test are as follows: organic matter 26.97g / kg, total nitrogen 1.18g / kg, total phosphorus 0.57g / kg, total potassium 11.18g / kg, total cadmium 2.41mg / kg, alkaline nitrogen 92.14mg / kg, available Phosphorus 32mg / kg, available potassium 112.23mg / kg, available cadmium 1.16mg / kg, pH 5.45. The tested rice variety is Tianyou 998 (Yueshendao 2004008). The seeds were soaked in clear water at 35°C for 2 days, and then cultured for 1 day after accelerated germination. After cultivating for about 30 days, transplant them into plastic pots, and fill each pot with 10kg of soil. Each treatment was repeated in 3 pots, with 3 clumps in each pot and 3 plants in each clump. The experiment set up 8 treatments:

[0136] T1, c...

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Abstract

The invention discloses a carbon-based seaweed silicon-selenium suspended fertilizer, a preparation method thereof and application of the carbon-based seaweed silicon-selenium suspended fertilizer in selenium enrichment and cadmium reduction of rice. The fertilizer is prepared by dispersing a seaweed carbon-based cross-linking agent and selenite in a silicic acid sol and ammonia mixture solution to form a suspending agent, adding a macroelement fertilizer, and fully mixing. Silicic acid colloid, seaweed carbon-based material and clay substance are mutually crosslinked to form a similar network compact space and become a fluid with stable dynamics, so that functional substances in the suspended fertilizer can be stably dispersed in the fertilizer for a long time. According to the method, the seaweed carbon-based silicon-selenium suspended fertilizer which is high in silicon and selenium content, high in effectiveness, high in stability and excellent in suspension property and gives consideration to macro-element supply can be prepared. In the tillering stage and the filling stage, the fertilizer is applied to rice growing in cadmium-contaminated soil in a leaf surface spraying mode and a rhizosphere ditching annular application mode respectively, the cadmium absorption of the rice is reduced by 21.0%-63.9%, and the selenium content of the rice is increased by 42.0%-119%.

Description

technical field [0001] The invention relates to the fields of crop cultivation, plant nutrition, and fertilizer industry, in particular to a carbon-based seaweed silicon-selenium suspension fertilizer, a preparation method thereof, and an application in enriching selenium and reducing cadmium in rice. Background technique [0002] Cadmium (Cd) is a biological non-essential toxic element, which can damage human bones, liver, kidneys and other organs, and also has the risk of teratogenic and carcinogenic. The biological half-life of cadmium is 10 to 30 years; even if the intake is stopped, a high proportion of cadmium will remain in the human body. Cadmium can enter and accumulate in the human body through the food chain from polluted soil and water, causing chronic poisoning. Rice (Oryza sativa L.) is the staple food of Chinese residents, and it is also the main source of cadmium exposure for the general population. The whole country has 2786km 2 According to the survey co...

Claims

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Application Information

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IPC IPC(8): C05G3/00C05G5/27A01G22/22
CPCY02P60/21
Inventor 沈宏杨旭健陈诗韵
Owner SOUTH CHINA AGRI UNIV
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