Low phonon energy gain medium and related active devices

a low phonon energy and active device technology, applied in the field of low phonon energy gain medium and to active devices, can solve the problems of low compatibility of fluoride glasses with silica optical fibers, disadvantages as far as phonon energy, and high principal optical phonon energy, and achieve good control over the size of tin oxide clusters

Inactive Publication Date: 2005-09-29
UNIV OF HIGHFIELD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0017] Gain media according to the present invention may be manaufactured by sol-gel techniques, which offer good control over the tin oxide cluster sizes. However, other techniques may be suitable for fabricating the gain medium.

Problems solved by technology

Unfortunately, silica has a high principal optical phonon energy, which arises from contributions from vibrations of the Si—O bond, in the vicinity of 1000 cm−1 [5].
Therefore, although silica is a useful host material as regards its compatibility with commonly used fibers, it is disadvantageous as far as phonon energy is concerned
However, fluoride glasses have low compatibility with silica optical fibers, and it is difficult to fabricate low loss fibers directly from fluoride glasses.

Method used

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  • Low phonon energy gain medium and related active devices
  • Low phonon energy gain medium and related active devices
  • Low phonon energy gain medium and related active devices

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Embodiment Construction

Manufacture of the Gain Media

[0030] Optical gain media described in the following embodiments and examples are of the glass ceramic type comprising a silica host material which contains clusters of tin oxide at which active ions are concentrated.

[0031] Samples of the gain medium have been made by a sol-gel technique. Sol-gel processing techniques are known for producing glasses and glass ceramics. The techniques involve first rib a solution (sol) of precursor molecules in a solvent The molecules react together to form a wet gel, from which a dryer xerogel is created by evaporation. The xerogel is then heated, or sintered, according to a thermal cycle, to produce the end glass or glass ceramic material.

[0032] In the present case, the sol was formed by co-gelling a number of precursors in a solvent. Tetraethoxysilane (TEOS, Si(OCH2CH3)4) provided silicon for silica, dibutyl tin-diacetate (Sn(CH2CH2CH2CH3)2(OOCCH3)2) provided tin, and active ions, in this case of the rare earth met...

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Abstract

Using sol-gel techniques, an optical gain medium has been fabricated comprising a glass ceramic host material that includes clusters of crystalline oxide material, especially tin oxide, and that is doped with active ions concentrated at the clusters. The active ions are preferentially located at the nanoclusters so that they experience the relatively low phonon energy of the oxide and are insensitive to the phonon energy of the host. A host with a high phonon energy, such as silica, can therefore be used without the usual drawback of reduced carrier lifetimes through enhanced nonradiative decay rates.

Description

BACKGROUND OF THE INVENTION [0001] The invention relates to a low phonon energy gain medium and to active devices comprising such a gain medium. [0002] Optical gain media are well-known as forming the basis of both lasers and optical amplifiers. Many gain media are solid-state and comprise a host material doped with active dopant ions, such as rare earth ions. Silica is a particularly common host material for amplifiers, partly because the material is widely used in optical fibers. A silica amplifier is highly compatible with silica transmission fiber they can be coupled together with low losses. [0003] An integrated fiber laser may be fabricated from such a gain medium by additionally including a photosensitive dopant such as tin. The photosensitivity of tin allows optical gratings to be written directly into the fibers to provide the necessary cavity mirrors. Co-doping of silica fibers with the rare earth ions erbium or ytterbium for gain, and tin for photosensitivity, has been us...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C03B19/12C03B37/016C03C10/14C03C13/00C03C13/04H01S3/067H01S3/16H01S3/17
CPCC03B19/12C03B37/016C03B2201/30C03B2201/34C03C13/006Y10S65/901H01S3/0637H01S3/06716H01S3/1603H01S3/169H01S3/17C03C13/046
Inventor TAYLOR, ELIZABETHBRAMBILLA, GILBERTOCHIODINI, NORBERTOPALEARI, ALBERTOSPINOLO, GIORGIOMORAZZONI, FRANCASCOTTI, ROBERTO
Owner UNIV OF HIGHFIELD
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