Mg Alloys Containing Misch Metal Manufacturing Method of Wrought Mg Alloys Containing Misch Metal, and Wrought Mg Alloys Thereby
a technology of misch metal and manufacturing method, which is applied in the field of magnesium alloys with misch metals, can solve the problems of az91 alloys having a difficult time being applied to parts exposed to a high temperature (150° c), a number of blowholes in products, and generating blisters on the surface of products, etc., to achieve excellent mechanical properties, high strength, and inhibit deformation of magnesium matrix
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embodiment 1
[0056]A molten metal of a magnesium alloy composition as given in the following Table 1 was prepared, and a cast was obtained by casting. More specifically, a carbon crucible was heated in an electric induction furnace at a temperature of 700° C. Magnesium was fused in the carbon crucible, and then other addictives were added. Thereby, a molten alloy was formed and poured into a mold, which was pre-heated up to 1200° C. Thereby, the cast was formed.
[0057]In the composition specified in Table 1, B refers to at % of a cerium-based misch metal. A secondary phase generated by addition of element B is a Mg12Ce phase. FIG. 1 is a scanning electron microscope photograph of Alloy 3, and shows that an alpha magnesium structure and the Mg12Ce phase form a network structure. Because the structures forming the network structure were stable at a high temperature and thus inhibited deformation of the alpha magnesium structure, they exhibited a high strength at a high temperature. Thus, as an amou...
embodiment 2
[0060]FIG. 2 is a photograph of a molten metal, in which 2 wt % calcium (Ca) is added to Alloy 9 of Table 1 and fused in air, and shows that a magnesium alloy composition can be fused and cast in air by adding calcium (Ca) to the magnesium alloy composition (e.g. Alloy 9). As can be seen from FIG. 2, it could be found that a thick oxide was not formed on a surface of the molten metal when the magnesium alloy composition was fused in air.
embodiment 3
[0061]
TABLE 2Composition (at %)Hardness Value (Hv)Generation of CrackAlloy 12165◯Alloy 12 + Ni0.3169ΔAlloy 12 + Cu0.3190XAlloy 12 + Sn0.3176XAlloy 12 + Al0.3185ΔAlloy 12 + Mn0.3195XAlloy 12 + Si0.3191X◯: Generation of the crackΔ: Slight generation of the crackX: No generation of the crack
[0062]In the magnesium alloy with the misch metal according to the present invention, as described, the Mg12Ce phase generated by adding the cerium (Ce)-based misch metal to magnesium (Mg) was an intermetallic compound and had brittleness. Hence, when the Mgl2Ce phase had a fraction higher than a magnesium matrix, the magnesium alloy has a property that an elongation was lowered. Therefore, in the current embodiment, an attempt was made to improve the property by adding a specific element. In Embodiment 3, Alloy 12 having the highest fraction of the Mg12Ce phase was selected from the compositions given in Table 1, and then it was examined how much the brittleness of the secondary phase was dependent...
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