3results about How to "Improve radiation stability" patented technology

This application discloses a crystal, a rare-earth-doped crystal, its preparation method, and its applications, belonging to the field of crystal materials. The chemical formula of the crystal is [Gd(L)]. 1.5 (DMA)] n Formula I; in Formula I, L is a ligand formed by deprotonated benzene polycarboxylic acid; benzene polycarboxylic acid is selected from any one of terephthalic acid, phthalic acid, and isophthalic acid; DMA is N , N -Dimethylacetamide; n ∞ represents continuous repetition and infinite extension. The crystal is rare-earth doped, and the chemical formula of the rare-earth doped crystal is [Gd]. 1‑x% (L) 1.5 (DMA)] n :x% Ln 3+ Equation II; in Equation II, x = 0.1~10; Ln 3+ Selected from Tb 3+ Or Eu 3+ Any one of the following. It has potential application value in fields such as fluorescent materials, multicolor display materials, long afterglow materials, X-ray detection and imaging materials, radiation detection dosimeters, and optical information encryption. The preparation method used in this application can be easily achieved through solution reaction under relatively mild conditions, with low cost and strong industrial feasibility.

This invention relates to a staggered covalent organic framework thin film, its preparation method, and its application, belonging to the field of thin film technology. The invention first dissolves an amine monomer in acetic acid solution to obtain an aqueous solution; then dissolves an aldehyde monomer in mesitylene to obtain an organic solution; finally, the aqueous and organic solutions are added to the aqueous and organic phase chambers of a diffusion cell, respectively, for interfacial polymerization. After the reaction, the membrane material is removed, washed, and dried to obtain the staggered covalent organic framework thin film. This film forms a staggered stacked structure and constructs sub-nanometer transport channels with pore sizes of approximately 0.5 nm to 0.7 nm. Through a synergistic mechanism of Donnan repulsion and hydrogen bonding interactions, it maintains structural stability under extreme environments of high acidity, strong corrosion, and high radiation, achieving highly efficient selective permeation of protons and efficient retention of metal ions in high-level radioactive waste liquids.

The application discloses a lanthanide-actinide heterometallic coordination polymer material and a preparation method and application thereof, and belongs to the technical field of metal organic polymer materials. 2+ The lanthanide-actinide heterometallic coordination polymer material is prepared through precise integration in a one-dimensional structure. The preparation method is simple in operation and easy to realize repeated preparation. The prepared lanthanide-actinide heterometallic coordination polymer material has both characteristic luminescence of lanthanide elements and structure guiding characteristics of actinide ions, is highly ordered in structure and has excellent radiation stability. Compared with other scintillators, the prepared lanthanide-actinide heterometallic coordination polymer material has sensitive scintillation response to X rays, high light output and excellent energy resolution, and has great potential in X ray imaging.