Charge control members
A technology of charge control and components, applied in the direction of electrical components, circuits, semiconductor/solid-state device manufacturing, etc., can solve problems such as circuit breakdown
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[0083] The present invention will now be described more specifically but not exclusively with reference to Examples and Comparative Examples. Physical properties were measured as described below.
[0084] (1) Surface resistivity
[0085] The surface resistivity is 1.0×10 6 For samples of Ω / □ or larger, a constant voltage meter (Model 300-1A, manufactured by Kikusui Corporation), an ammeter (Model 616, manufactured by Keithley Corporation) and a sample cell (Model 1608A, manufactured by Yokogawa-HP Made by the company) Measured according to JISK-6911 when a voltage of 100V is applied, and the surface resistivity is less than 1.0×10 6 The sample of Ω / □ was measured in accordance with JISK-7194 using Loresta HP manufactured by Mitsubishi Chemical Corporation.
[0086] (2) Charge amount of glass substrate
[0087] The surface potential of the glass substrate after being in contact with the sample was measured at a temperature of 23°C and a relative humidity of 50% with a surfa...
Synthetic example 1
[0091] Graft copolymer synthesis example
[0092] 23 parts by weight of 1,3-butadiene, 30 parts by weight of butyl acrylate, 12 parts by weight of methoxy polyethylene glycol methacrylate, 0.016 parts by weight of dicumyl hydroperoxide, 0.006 parts by weight of formaldehyde Sodium sulfoxylate, 0.0015 parts by weight of ethylenediaminetetraacetic acid iron (III), 0.2 parts by weight of sodium pyrophosphate, 2.0 parts by weight of potassium oleate and 200 parts by weight of deionized water are added to a pressure-resistant container with agitator, temperature and pressure gauge. reactor, and then stirred at 60 °C for 10 hours. After polymerization, a rubbery main chain polymer latex having an average particle diameter of 80 nm was obtained in 99% yield.
[0093] 35 parts by weight of methyl methacrylate as ethylenically unsaturated monomer mixture, 0.3 parts by weight of n-octyl mercaptan, 0.018 parts by weight of dicumyl hydroperoxide, 0.007 parts by weight of sodium formald...
Embodiment 1~6 and comparative example 1~6
[0095] The ingredients listed in Table 1 were dry-blended together with a Henschel mixer, and then melt-extruded with a φ45 mm twin-screw extruder (PCM-45, manufactured by Ikegai Iron Works Co., Ltd.) to obtain a pellet, The latter was dried and fed into an injection molding machine (IS-75, manufactured by Toshiba Machine Co., Ltd.) to prepare a flat plate to be used for measuring physical properties. The results are summarized in Table 1.
[0096] Table 1
[0097]
[0098] Notes:
[0099] (1) Polyamide 46: Stanyl TS 300, manufactured by DSM JSR Enplar.
[0100] (2) Polyphthalamide: Polyamide 6T / 6I / 66, manufactured by Amoco Company, trade name is Amodel.
[0101] (3) Polycarbonate: Yupiron S-2000, manufactured by Mitsubishi Gas Chemical Corporation.
[0102] (4) Polyethylene terephthalate: SA135, manufactured by Mitsui Chemicals.
[0103] (5) Polybutylene terephthalate: Julanecks 2002, manufactured by Polyplastics.
[0104] (6) Polyphenylene sulfide: Fortlon KPS W-214...
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