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Fermentation and infiltration vaporization coupling technique for producing ethanol

A technology of pervaporation and pervaporation membrane, applied in the field of fuel ethanol preparation, can solve the problems of increasing yeast mortality, unstable fermentation process, and decreasing fermentation rate, and achieve the improvement of pollution phenomenon, the promotion of cell activity and density, and the elimination of inhibition. Effect

Active Publication Date: 2008-08-06
NANJING UNIV OF TECH
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Problems solved by technology

[0003] The cellulose fermentation system contains 15% to 40% solids (unfermentable lignin), which will cause serious pollution to the downstream pervaporation separation process. In previous reports, the biofermentation reactor The reactants must be pretreated by microfiltration before they can enter the pervaporation separation process. Such a process not only has high operating costs and is unacceptable to the industry, but also increases the possibility of bacterial contamination, which will affect the further metabolism of the bacteria. It also increases the mortality rate of the yeast, resulting in a decrease in the fermentation rate, and it will also be accompanied by a serious accumulation of inhibitors, resulting in an unstable fermentation process

Method used

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  • Fermentation and infiltration vaporization coupling technique for producing ethanol

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Embodiment 1

[0019] After the straw is processed by steam explosion and enzymatically hydrolyzed, the slurry is made into the fermentation tank 1, and after microbial fermentation at a temperature of 30°C for 30 hours, when the volume concentration of ethanol in the liquid phase in the tank is detected to reach 3%, the vacuum pump 9 is turned on to control Valves 3 and 5, the clear liquid in the fermentation tank enters the storage tank 4 through the sheet-type inorganic separation membrane separator, and the clear liquid in the storage tank 4 is transported into the pervaporation separator through the feed pump 6, and the vacuum degree is maintained at 500Pa. The ethanol in the liquid continuously enters the tubular polydimethylsiloxane / ceramic composite pervaporation membrane and is vaporized into the cooler 8 to be collected, and the collected ethanol concentration reaches 35v%.

Embodiment 2

[0021] After the corn is acid-treated and enzymatically hydrolyzed, the slurry is made into the fermenter 1, and after microbial fermentation at 40°C for 46 hours, when the volume concentration of ethanol in the liquid phase in the tank reaches 8%, the vacuum pump 9 is turned on and the control valve 3 is turned on. and 5, the clear liquid in the fermentation tank enters the storage tank 4 through the sand steel plate filter type separator, and the clear liquid in the storage tank 4 is transported into the pervaporation separator through the feed pump 6, and the vacuum degree is maintained at 200Pa, and the clear liquid in the clear liquid The ethanol continuously enters into the tubular MFI series molecular sieve pervaporation membrane and is vaporized into the cooler 8 to be collected, and the collected ethanol concentration reaches 69v%.

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Abstract

The invention belongs to a separation technique of fermentation and pervaporation coupling to produce alcohol, which is characterized in that the separating technique comprises separating solid suspension mater and liquid part in a fermentation tank, transporting liquid part to a pervaporation steaming film separator through a pump, and lowering clogging at the bottom of the fermentation tank through the circulation of permeation residual liquid. The improved fermentation technique is more suitable for the connection of pervaporation technique, which increases the matching degree between fermentation and pervaporation coupling, and leads the integral production technique in downstream pervaporation technique to be more stable. The separation technique not only lowers the possibility of infecting bacteria through a new process flow, but also lowers film pollution in the process of downstream pervaporation separation, which lays an industrial foundation for the process of improving fermentation productivity and continuously fermenting. The distinctive characteristics of the method are that the method has low production cost and convenient employment, which has industrialized prospect.

Description

technical field [0001] The invention relates to a production method for producing fuel ethanol by fermentation of biomass, in particular to the transformation of a pretreatment process in which the fermentation process is coupled with pervaporation to produce ethanol, and belongs to the field of fuel ethanol preparation. Background technique [0002] Biomass fermentation to prepare fuel ethanol has attracted the attention of countries all over the world, especially the use of cellulose (such as crop straw) as a fermented product to ferment fuel ethanol is an inevitable trend in the development of fuel ethanol, so the development of fuel ethanol through cellulose fermentation The technical route has become a hot topic of widespread concern to scientists from all over the world. The large accumulation of metabolites (ethanol) in the fermentation process has a greater feedback inhibition effect on the fermentation process, which will seriously affect the yield of ethanol. In r...

Claims

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Application Information

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IPC IPC(8): C12P7/06C12M1/12
CPCY02E50/10
Inventor 金万勤卫旺相里粉娟徐南平
Owner NANJING UNIV OF TECH
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