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Purification method of sulphur-containing flue-gas

A sulfur-containing flue gas and flue gas technology, applied in chemical instruments and methods, separation methods, filtration and separation, etc., can solve the problems of inability to intercept fine dust in sulfur-containing flue gas, increase energy consumption, and complicate the purification process, etc., to achieve Good resistance to high temperature oxidation/vulcanization, reduced running strength and difficulty, and good pore structure stability

Inactive Publication Date: 2009-03-25
CHENGDU INTERMENT TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] 1. The bag itself is not resistant to high temperature, so a pre-cooler must be used to cool the high-temperature sulfur-containing flue gas, which not only increases energy consumption, but also increases production costs;
[0006] 2. The filtering accuracy of the cloth bag is poor, and it cannot intercept the fine dust in the sulfur-containing flue gas. On the one hand, the valuable resources in the fine dust are wasted, which is not conducive to the recycling of valuable resources in the sulfur-containing flue gas; on the other hand , because a single bag filter cannot meet the quality requirements of the follow-up processing technology for sulfur-containing flue gas, therefore, it must be supplemented by a follow-up dust removal process, that is, further purification by means of dust removal such as Venturi dust collector and electrostatic precipitator, which brings The treatment of a large amount of waste water and the subsequent drying of sulfur-containing flue gas complicate the purification process, reduce production efficiency, and increase production costs
[0007] 3. The separation effect of the bag filter is unstable, and its filtration accuracy has a large attenuation range with the running time, and the service life is short. It needs to be replaced in about 3 to 6 months, which increases the filtration cost.
So far, there is no report on the application of this FeAl intermetallic compound porous material to directly filter sulfur-containing flue gas at high temperature

Method used

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  • Purification method of sulphur-containing flue-gas

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Example 1 The method of the present invention is used to purify sulfur-containing flue gas

[0021] Using an iron-aluminum filter with FeAl intermetallic compound filter material as the filter element, the total amount of 13m 3 The high-temperature sulfur-containing flue gas passes through the cyclone dust collector, and after preliminary slag discharge, it directly enters the iron-aluminum filter; the filtration pressure is controlled at 0.10MPa, and the high-temperature sulfur-containing flue gas passes through the FeAl intermetallic compound filter element to achieve its solid gas In the separation process, the gas after solid-gas separation is absorbed by 4L of sulfuric acid with a concentration of 93%.

[0022] As a comparison, a cloth bag filter is used instead of the FeAl intermetallic compound filter element to filter sulfur-containing flue gas under the same conditions, and the rest of the steps are the same as above.

[0023] The sulfuric acid after absorbing...

Embodiment 2

[0028] Example 2 The method of the present invention is used to purify sulfur-containing flue gas

[0029] Using an iron-aluminum filter with FeAl intermetallic compound filter material as the filter element, the total amount of 13m 3 The high-temperature sulfur-containing flue gas passes through the cyclone dust collector, and after preliminary slag discharge, it directly enters the iron-aluminum filter; the filtration pressure is controlled at 0.40MPa, and the high-temperature sulfur-containing flue gas passes through the FeAl intermetallic compound filter element to achieve its solid gas In the separation process, the gas after solid-gas separation is absorbed by 4L of sulfuric acid with a concentration of 93%. After 2 days of filtration, control the backwash pressure to 0.50MPa, use high-temperature filter air to backwash the FeAl intermetallic compound filter element, and continue to filter after backwashing for 4 minutes; most of the dust will be eliminated at this stage...

Embodiment 3

[0032] Example 3 The method of the present invention is used to purify the sulfur-containing flue gas produced by the smelting of molybdenum concentrate

[0033] The sulfur-containing flue gas produced by the smelting of molybdenum concentrate is purified by the method of the present invention to produce sulfuric acid and recover molybdenum ore. The annual output of sulfuric acid is 25000t. And compared with existing methods, the results are shown in Table 2.

[0034] Table 2

[0035]

[0036] It can be seen from Table 2 that the method of the present invention obviously improves the recovery rate of molybdenum in the smelting of molybdenum concentrate, can produce huge economic benefits, and has broad application prospects.

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PUM

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Abstract

The invention relates to a purification method of sulfur-bearing flue gas, which belongs to the chemical field. The invention solves the technical problem of providing the purification method of sulfur-bearing flue gas with simple process steps. The purification method of sulfur-bearing flue gas comprises the following steps: a, a first dust removal is implemented to the sulfur-bearing flue gas through a cyclone dust collector; and b, the sulfur-bearing flue gas undergoing the first dust removal is filtered by a filter taking FeAl intermetallic compound porous material as a filtering element. Compared with the existing sulfur-bearing flue gas purification method, the invention eliminates the corresponding cooling equipment, shortens the process flow, improves the production efficiency, reduces the environmental pollution, lowers the production cost, and has broad application prospect.

Description

technical field [0001] The invention relates to a method for purifying sulfur-containing flue gas and belongs to the field of chemical industry. Background technique [0002] In my country's high-temperature industries, such as metallurgy, chemical and energy industries, industrial processes such as the separation and combustion of a large amount of petroleum gas, coke oven gas and coal gas, the calcination of sulfur-containing minerals, and the combustion of coal in thermal power plants will generate a large amount of high-temperature Sulfur-containing flue gas (mainly SO 2 and a series of oxide dust), the effective purification of this high-temperature flue gas containing sulfur dioxide has become a key technology to improve product quality, save energy, reduce production costs and reduce environmental pollution. [0003] At present, my country's non-ferrous metal smelters mainly use bag filters to separate solid and gas from this high-temperature sulfur-containing flue ga...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D50/00B01D39/20
Inventor 高麟贺跃辉徐进辉汪涛
Owner CHENGDU INTERMENT TECH
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