Asymetric membrane FeAl intermetallic compound porosint filter element and application thereof
A technology of intermetallic compounds and filter elements, which is applied in the fields of filtration and separation, chemical instruments and methods, and gas dust removal, etc. It can solve the problems of serious corrosion of washing equipment, long purification process, and many processes, and achieve good high-temperature oxidation/sulfurization resistance. , Expand the scope of the use of the environment, shorten the effect of the process
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Embodiment 1
[0050] Example 1 Preparation of filter element
[0051] The Fe powder with an average particle size of 100μm and the Al powder with an average particle size of 90μm are mechanically mixed according to the ratio of Fe-30at% Al (that is, the number of Fe atoms is 70% of the total number of atoms), and then the ordinary molding method is used at 240MPa The sheet blank (¢350×4.0mm) is pressed under the pressure of the same. Sintering in a vacuum atmosphere, the vacuum degree is controlled at 1.0×10 -1 ~1.0×10 -2 Pa. First sinter at 130°C for 45 minutes to remove adsorbed water. Subsequently, medium temperature solid phase diffusion was performed at a temperature of 520°C for 60 minutes. The final high-temperature component homogenization and structure stabilization treatment temperature is 1050° C., the time is 120 minutes, and the cooling process produces a FeAl intermetallic compound porous support with a maximum pore size of 35 μm and a porosity of 43%.
[0052] Fe and Al powders...
Embodiment 2
[0055] Example 2 Preparation of filter element
[0056] Fe powder with an average particle size of 5μm and Al powder with an average particle size of 10μm are mechanically mixed according to the ratio of Fe-60at% Al, and then pressed into a sheet blank (¢300×3.5 mm). Sintering in a vacuum atmosphere, the vacuum degree is controlled at 1.0×10 -1 ~1.0×10 -2 Pa. First, heat at 150°C for 50 minutes; then, carry out intermediate temperature solid phase diffusion at 560°C for 120 minutes. The final high-temperature component homogenization and structure stabilization treatment temperature is 1100°C, and the time is 30 minutes. A FeAl intermetallic compound porous support with a maximum pore diameter of 12 μm and a porosity of 38% was prepared.
[0057] Fe and Al powders with an average particle diameter of 1.0 μm are uniformly mixed at a ratio of Fe-60 at% Al to prepare a powder mixture; ethylene glycol and polyvinyl alcohol are mixed at a mass ratio of 1:1 as organic additives. The ...
Embodiment 3
[0060] Example 3 Preparation of filter element
[0061] Fe powder with an average particle size of 40μm and Al powder with an average particle size of 30μm are mechanically mixed at the ratio of Fe-40at% Al, and then compressed by cold isostatic pressing at a pressure of 180MPa, and the core rod taper is 1.8 °, after manual demolding, a tubular shaped blank (Ф50*300mm) with a slightly taper inner diameter (3°) is obtained. Adopt vacuum atmosphere for sintering, the vacuum degree is controlled at 1.0×10 -1 ~1.0×10 -2 Pa. First, heat at 120°C for 30 minutes to remove the adsorbed water; then, carry out medium-temperature solid phase diffusion at 600°C for 120 minutes. The final temperature of high-temperature component homogenization and structure stabilization treatment is 1200 DEG C, and the time is 90 minutes to prepare a FeAl intermetallic compound porous support.
[0062] Fe and Al powders with an average particle size of 1.5μm are mixed according to the ratio of Fe-40at% Al t...
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