High oil absorption composite material containing cellulose waste filler and preparation method thereof
A composite material and waste technology, which is applied in the field of high oil absorption composite material and its preparation, can solve the problems of many reaction steps, small oil absorption rate, re-oil leakage, etc., and achieves excellent oil absorption performance, high oil absorption rate and fast oil absorption rate. Effect
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[0040] The preparation method of the substrate acrylate copolymer high oil-absorbing resin is as follows:
[0041] ① Ingredients according to the above proportions;
[0042] ② Stir and emulsify, add deionized water and emulsifier to the reaction device, and stir and emulsify for 15 to 20 minutes;
[0043] ③Put oxygen through nitrogen for 15-30 minutes and then connect to nitrogen balloon protection;
[0044] ④ In the method of adding comonomer and part of the initiator or part of the comonomer and initiator, the dripping speed is subject to maintaining the set reaction temperature, and the dripping time is 0.75 to 1 hour;
[0045] ⑤ Add the remaining initiator, comonomer and initiator dropwise, the reaction temperature is controlled at 70~90℃, and the reaction time is 5~9 hours;
[0046] ⑥ The acrylate copolymer emulsion product (A) is sealed and stored away from light for later use.
[0047] The detection indexes of the acrylate copolymer emulsion product (A) are as follow...
Example Embodiment
[0081] Example 1
[0082] (1) Synthetic acrylate copolymer super oil-absorbing resin
[0083] The formulas are measured by weight percentage: deionized water = 69.85, SDS + Tween 60 = 1.357, dodecyl methacrylate + vinyl acetate = 26.20, N-methylol ammonium + acrylic acid = 0.94, potassium persulfate = 0.22; add the first two items into a four-necked reaction flask with electric stirring, a condenser, a dropping balance funnel and a thermometer, heat up to 40-50 °C and stir for 15 minutes, add comonomer, stir for 30 minutes, pass through After 15 minutes of nitrogen deoxygenation, it was protected by a nitrogen balloon; the temperature was raised to 80±2°C, and 1 / 4 of the potassium persulfate aqueous solution was added. The rate of addition should be that the reaction temperature is stabilized at 85±2°C; after 7 hours of reaction, the temperature rises to 90°C and the temperature is lowered after 1 hour of reaction, and the product emulsion (A) is sealed and protected from lig...
Example Embodiment
[0088] Example 2
[0089] (1) Emulsion copolymerization into acrylate copolymer super oil-absorbing resin
[0090] Formula: distilled water, OP-10, sodium dodecyl sulfonate, methacrylic acid, N-methylol acrylamide, isooctyl acrylate, butyl acrylate and ammonium persulfate, the proportions by weight are 69.66 , 1.00, 0.37, 046, 0.54, 13.9, 13.9 and 0.17. Steps: in a glass, mix the monomer and crosslinking agent evenly, pass nitrogen and remove oxygen as (D), and use a small amount of water to prepare a solution of the initiator as (E); add dispersion medium and emulsifier with electric stirring. , a condenser tube, a balanced dropping funnel and a four-necked reaction flask of a thermometer, heat and stir for 15 minutes, then add 1 / 4 of (D), stir for 30 minutes with nitrogen, add 1 / 4 of (E) after oxygen exhaustion Protected by a nitrogen balloon; heat up to 75±2°C and react for 40 minutes; then add the reserved (D) and (E) dropwise respectively, the rate of addition is based ...
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