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Reinforcing material of permeable hydraulic degraded unconsolidated rock and reinforcing method thereof

A technology for reinforcing materials and loose rocks, which is applied in the field of reinforcing materials for permeable hydraulically deteriorated loose rocks. It can solve the problems of affecting the permeability of protective agents, it is difficult to avoid soluble salts, and the curing time of reinforcing agents is long, so as to avoid corrosion. Effects of calcium rock, shortening of curing time, and improvement of reinforcement strength

Inactive Publication Date: 2009-12-23
ZHEJIANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] 1. The problem of soluble salts. In osmotic water-based protective agents, inorganic materials are often introduced in the form of salt solutions, so it is difficult to avoid bringing in soluble salts, which will cause damage to salt crystals;
[0004] 2. The problem of reinforcement strength. Due to the solvation of water, after the inorganic salt solution penetrates into the micropores of the rock, what is precipitated is often a powdery substance that is not cross-linked with each other, and the reinforcement effect is not strong;
[0005] 3. The problem of permeability. In order to reduce the harm of soluble salts, insoluble or slightly soluble inorganic substances are often used. However, this conventional solution penetrates very little active ingredient, so it is mostly made into a paste, which affects the protective agent. permeability
However, the reinforcing agent is slightly acidic, which may cause corrosion to calcium-containing rocks. At the same time, the preparation process is more complicated, and the curing time of the reinforcing agent is longer.

Method used

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  • Reinforcing material of permeable hydraulic degraded unconsolidated rock and reinforcing method thereof
  • Reinforcing material of permeable hydraulic degraded unconsolidated rock and reinforcing method thereof
  • Reinforcing material of permeable hydraulic degraded unconsolidated rock and reinforcing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] 1. Solution configuration: Weigh 0.47g of phosphorus pentoxide, use 35ml of ethanol as solvent, then add 1.5ml of ethyl orthosilicate mineralization coupling agent to make A alcohol solution; take 4.80g of calcium oxide, and use 25ml of ethyl Diol is used as a solvent, and it is prepared into B alcohol solution by heating. Mix the two solutions A and B, and ultrasonically disperse for 15 minutes under airtight conditions. The mixed solution was used within 1 hour.

[0036] 2. Reinforcement strength test: Accurately weigh 80g of granular calcium carbonate (sieved with 100 mesh) and 80g of powdered calcium carbonate (sieved with 1000 mesh), mix well, add 20ml of water, and continue to mix fully. move in In a 39.8mm×80mm stainless steel compaction mold, a 566g compaction hammer with a height of 277mm was compacted 50 times. After demoulding, the sample was placed in an open indoor environment to dry naturally. Obtain shaped loose rock imitation samples. In the same wa...

Embodiment 2

[0042] The method is the same as in Example 1, changing the solution formulation and the dissolved amount of phosphorus and calcium.

[0043] Solution preparation: Weigh an appropriate amount of phosphorus pentoxide (see Table 1 for dosage), add 35ml of ethanol solvent, and then add 1.5ml of tetraethyl orthosilicate mineralization coupling agent to prepare a series of A alcohol solutions; Calcium (see Table 1 for dosage), then weigh 0.35g of acrylic emulsion dispersant and 0.45g of magnesium fluorosilicate hardener, add 25ml of ethylene glycol solvent, and prepare series B alcohol solutions by heating. Mix the two solutions A and B in the order listed in Table 1, and disperse ultrasonically for 15 minutes under airtight conditions. After the mixed solution is uniformly mixed with calcium carbonate particles and powder for reinforcement operation within 30 minutes, the obtained samples are uniformly placed in an open indoor environment for 30 days, and then the compressive stre...

Embodiment 3

[0047] With embodiment 2, just change the standing time of sample.

[0048] Solution preparation: Weigh 2.38g of phosphorus pentoxide, use 35ml of ethanol as solvent, and then add 1.5ml of ethyl orthosilicate to make A alcohol solution; successively weigh 0.35g of acrylic acid emulsion, 0.45g of magnesium fluorosilicate, 3.0g Calcium oxide, with 25ml ethylene glycol as solvent, is prepared into B alcohol solution through heating. Mix the two solutions A and B, and ultrasonically disperse for 15 minutes under airtight conditions. The mixed solution was mixed and consolidated with calcium carbonate particles and powder within 30 minutes, and the obtained samples were placed in an open indoor environment for a certain number of days (see Table 2), and then the compressive strength and surface hardness were tested. The obtained data are also listed in In Table 2, it can be seen from Table 2 that as the storage time increases, the compressive strength and surface hardness of the r...

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Abstract

The invention discloses a reinforcing material of a permeable hydraulic unconsolidated rock. The reinforcing material comprises the following components: low carbon alcohol solution A with a phosphorus source substance as a main solute, wherein, a mineralized coupling agent is dissolved; polyhydroxy low carbon alcohol solution B with a calcium source substance as a main solute, wherein, a hardener and a dispersant are dissolved; and aqueous solution C with ammonium salt as a solute. Penetration operation is performed on the unconsolidated rock by natural flow, spraying, brush coating, soaking or applying methods. The alcohol solution A and the solution B can be mixed and permeated or sequentially permeated respectively, and then the aqueous solution C is permeated after permeation is finished. The reinforcing material has the advantages of easily available raw materials, mild preparation conditions, simple use method, good compatibility with the rock, acid corrosion resistance, obvious reinforcing effect, water soak resistance, no pollution and environmental protection.

Description

technical field [0001] The invention belongs to the field of stone materials and stone cultural relics protection materials, and in particular relates to a reinforcement material for permeable hydraulically degraded loose rock and a reinforcement method thereof. Background technique [0002] Our country has a long history, and many stone cultural relics and ancient buildings are threatened by natural weathering, many of which are already in an endangered state, and are in urgent need of protective materials with excellent performance for reinforcement and protection. At present, most of the commonly used surface protection materials are organic materials. These materials form a network structure dominated by organic substances through cross-linking reactions, and have a certain reinforcement strength. However, the shortcomings of organic materials are also obvious, mainly manifested in short service life, poor weather resistance, and poor compatibility with rocks. Some organ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B41/45
Inventor 张秉坚潘昌初
Owner ZHEJIANG UNIV
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