Preparation method for thermoset resin/waste rubber powder/waste tire fiber composite material
A fiber composite material and waste rubber powder technology, applied in the field of environmental materials, can solve the problems of serious pollution of the atmosphere and surrounding environment, failure to reflect the use value, waste of fiber materials, etc., and achieve good industrialization prospects, broaden utilization methods, and low cost Effect
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Embodiment 1
[0029] (1) Mix 30 parts of styrene monomer and 30 parts of 80-mesh waste rubber powder evenly, seal and place for 24 hours; weigh 3 parts of γ-methacryloxypropyltrimethoxysilane in a certain amount of distilled water , made into a 1%wt aqueous solution, adding 110 parts of waste tire fibers to the aqueous solution of γ-methacryloxypropyltrimethoxysilane, soaked for 30min, and then dried in an oven at 105°C for 3 hours before use .
[0030] (2) 40 parts of calcium carbonate, 100 parts of unsaturated polyester resin, 4 parts of 1,1-bis(tert-butyl peroxide)-3,3,5-trimethylcyclohexane were pre-mixed successively, and then Add the waste rubber powder and waste fiber processed in step (1), and put it into an internal mixer for mixing evenly;
[0031] (3) The rubber compound obtained in step (2) was molded at a temperature of 145° C. for 12 minutes.
[0032] The mechanical properties of the sample obtained in Example 1 are measured as follows: tensile strength 16.2Mpa; flexural mod...
Embodiment 2
[0035](1) Mix 10 parts of acrylamide monomer with 10 parts of 120 mesh waste rubber powder; stir 6 parts of phenolic resin and 20 parts of waste tire fiber with a mixer;
[0036] (2) 40 parts of white carbon black, 100 parts of epoxy resin, 80 parts of hexahydrophthalic anhydride, 3 parts of dimethylbenzylamine are pre-mixed successively, and 50 parts of glass fiber and 20 parts of 200 mesh nitrile rubber are added, Mix evenly with an open mill, then add the treated waste rubber powder and waste fiber, mix evenly and set aside;
[0037] (3) The rubber compound obtained in (2) was molded at a temperature of 160° C. and a pressure of 7 MPa for 60 minutes.
[0038] The mechanical properties of the sample obtained in Example 2 are measured as follows: tensile strength 35.2Mpa; flexural modulus 2219.0MPa; flexural strength 63.7MPa; unnotched impact strength 19.8KJ / m 2 .
Embodiment 3
[0040] (1) Mix 20 parts of methacrylic acid monomer, 10 parts of methyl methacrylate monomer and 60 parts of 200 mesh waste rubber powder; weigh 3 parts of γ-diethylenetriaminotriethoxy A 1%wt aqueous solution made of silane, add 150 parts of waste fiber to the γ-diethylenetriaminotriethoxysilane aqueous solution, soak for 120min, then dry in an oven at 105°C for 3 hours before use .
[0041] (2) Pre-mix 10 parts of magnesium oxide, 100 parts of phenolic resin, and 8 parts of hexamethylenetetramine in sequence, then add the waste rubber powder and waste fiber treated in (1), and put them in a kneader to knead evenly ;
[0042] (3) Inject the compound obtained in (2) at a temperature of 140°C.
[0043] The mechanical properties of the sample obtained in Example 3 are measured as follows: tensile strength 23.3Mpa; flexural modulus 1600.0Mpa; flexural strength 56.3Mpa; unnotched impact strength 23.3KJ / m 2 .
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