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Polyphenyl ether compound used for solar battery connecting box

A technology for solar cells and polyphenylene ethers, applied in the fields of polyphenylene ether compositions and halogen-free flame retardant polyphenylene ether compositions, can solve problems such as difficulty in meeting performance requirements, and achieve good rigidity, good flame retardant performance, and insulating performance. excellent effect

Inactive Publication Date: 2010-08-18
BEIJING UNIV OF CHEM TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Although there are many types of modified PPO, they still cannot meet the needs of different fields. For example, solar cell junction boxes require materials with high fluidity, good rigidity, good low-temperature toughness, good flame retardancy, excellent insulation performance, and weather resistance. Good and other characteristics, but the current modified PPO materials are difficult to meet the performance requirements of such products

Method used

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  • Polyphenyl ether compound used for solar battery connecting box

Examples

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Comparison scheme
Effect test

Embodiment 1

[0028] With 70 parts by weight of polyphenylene ether resin (intrinsic viscosity 0.45dL / g), 30 parts by weight of high-impact polystyrene resin (melt flow rate 4g / 10min), 3 parts by weight of low-density polyethylene, 12 parts by weight The liquid organophosphate flame retardant (tetraphenyl bisphenol A diphosphate) of part, the antioxidant 1010 of 0.5 part by weight, the antiultraviolet agent zinc oxide of 0.2 part by weight stirred 4 minutes in high-speed mixer; Mixed The uniform material is put into the twin-screw extruder for melt extrusion and granulation. The length-to-diameter ratio of the twin-screw extruder is 40, the screw speed is 320rpm / min, the feeding speed is 300rpm / min, and the temperature of each section of the screw barrel is 240-285°C. Machine diced.

Embodiment 2

[0030] With 60 parts by weight of polyphenylene ether resin (intrinsic viscosity 0.5dL / g), 40 parts by weight of high-impact polystyrene resin (melt flow rate 2g / 10min), 1 part by weight of low-density polyethylene, 11 parts by weight The liquid organophosphate flame retardant (tetraphenylbisphenol A diphosphate) of part, the antioxidant 168 of 1.0 part by weight, the anti-ultraviolet agent titanium dioxide of 0.5 part by weight stirred 4 minutes in high-speed mixer; Mix homogeneously The materials are put into the twin-screw extruder for melt extrusion and granulation. The length-to-diameter ratio of the twin-screw extruder is 40, the screw speed is 320rpm / min, the feeding speed is 300rpm / min, and the temperature of each section of the screw barrel is 240-285°C. Machine diced.

Embodiment 3

[0032] With 80 parts by weight of polyphenylene ether resin (intrinsic viscosity 0.3dL / g), 20 parts by weight of high-impact polystyrene resin (melt flow rate 10g / 10min), 5 parts by weight of low-density polyethylene, 5 parts by weight The solid organophosphate flame retardant (tetraphenyl bisphenol A diphosphate) of part, the antioxidant DLTP of 0.6 part by weight, the antiultraviolet agent carbon black of 0.1 part by weight stirred 4 minutes in high-speed mixer; Mixed The uniform material is put into the twin-screw extruder for melt extrusion and granulation. The length-to-diameter ratio of the twin-screw extruder is 40, the screw speed is 320rpm / min, the feeding speed is 300rpm / min, and the temperature of each section of the screw barrel is 240-285°C. Machine diced.

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Abstract

The invention discloses a polyphenyl ether compound used for a solar battery connecting box, comprising the following components in parts by weight: 60-80 parts of polyphenyl ether resin, 20-40 parts of high impact polystyrene resin, 1-5 parts of polyolefine resin, 5-12 parts of phosphorus flame retardant, 0.5-1 part of antioxygen and 0.1-0.5 part of anti-ultraviolet agent. The polyphenyl ether compound has the advantages of better rigidity, good low-temperature toughness, good flame retardant property, good insulating property, good weather resistance, easy processing shaping and the like. Products meet the requirements of the ROHS standard. The invention is suitable for producing the components of electronic and electrical products, such as the solar battery connecting box and the like.

Description

technical field [0001] The invention relates to a polyphenylene ether composition used in a solar cell junction box, in particular to a halogen-free flame-retardant polyphenylene ether composition with improved fluidity and toughness, and belongs to the field of polymer alloys. Background technique [0002] Pure polyphenylene ether (PPO) resin has good mechanical properties, electrical properties, heat resistance, flame retardancy and chemical stability, etc., but its melt viscosity is high, and its processability is extremely poor. Unmodified PPO resin It cannot be molded by injection method, which greatly limits its application. Both PPO and PS are amorphous polymers with very good compatibility and can form alloys in a wide range of blending ratios. However, due to the high rigidity of the PPO molecular chain, it is very sensitive to the notched impact strength, so HIPS can be used to improve its notched impact strength. However, the effect of simply adding HIPS to toug...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L71/12C08L51/04C08L23/00C08L23/06C08L23/08C08L23/16C08K13/02C08K3/04C08K3/22
Inventor 李刚戴伍国袁文信春玲何亚东李庆春闫宝瑞
Owner BEIJING UNIV OF CHEM TECH
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