F-Si acrylate copolymer and use method thereof as paint sealant
A silicon acrylate and copolymer technology, which is applied in the field of polymer synthesis, can solve the problems of low surface energy of fluorine-containing films, lower surface energy of coating films, and unsatisfactory problems, so as to improve suspension stability, ultraviolet protection function and Improved washing resistance and shortened drying time
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Embodiment 1
[0020] 1. Preparation of fluorosilicone acrylate copolymer
[0021] 1) Dissolve 0.3% of sodium lauryl sulfate and OP-101.2% in water with 20% of the total monomers, add them to the emulsification kettle, and then add 29% of monomer styrene, 20% of methyl methacrylate, 29% butyl acrylate, 1% acrylic acid, 7.5% trifluoroethyl methacrylate, 6.5% trimethylhydroxysilane, 3% nanomaterials, 1.5% emulsifier and 0.5% initiator. Stir quickly to emulsify evenly. A stable milky white emulsion is obtained for use.
[0022] 2) Deionized water of 110% of the total monomer is added to the reactor, and the temperature is raised to about 40°C under stirring. Take 1 / 9 of the emulsion and put it into the reactor, add 0.5% of the initiator potassium persulfate, and slowly increase the temperature to 65°C to initiate seed polymerization. When the emulsion turns blue and no obvious reflux occurs, start to evenly add the remaining initiator and emulsion, and keep the temperature at about 80°C. Control ...
Embodiment 2
[0027] 1. Preparation of fluorosilicone acrylate copolymer
[0028] 1) Dissolve 0.3% sodium dodecylbenzene sulfonate and OP-101.5% composite emulsifier in 20% of the total monomers in water, add them to the emulsification kettle, and then add a quantitative monomer methyl methacrylate 30 %, methyl acrylate 18%, butyl acrylate 30%, trifluoroethyl acrylate 7.5%, N-methylolacrylamide 2%, trimethylhydroxysilane 5.2%, nanomaterials 3%, emulsifier 1.5% and Initiator 0.5%, stir quickly to make it emulsify evenly, and obtain a stable milky white emulsion for use.
[0029] 2) Add deionized water of 100% of the total monomer amount into the reactor, stir and raise the temperature to about 40°C. Take 1 / 9 of the emulsion and put it into a four-necked bottle, add 1 / 2 of the amount of the initiator potassium persulfate, and slowly increase the temperature to 67°C to initiate seed polymerization. When the emulsion turns blue and no obvious reflux occurs, start to evenly add the remaining initia...
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