Solid tantalum electrolytic capacitor and manufacturing method thereof

A tantalum electrolytic capacitor and solid technology, which is applied in the field of solid tantalum electrolytic capacitors and its preparation, can solve the problems of poor conductivity and achieve the effects of increasing conductivity, reducing equivalent series resistance, and excellent thermal conductivity

Inactive Publication Date: 2012-08-08
UNIV OF ELECTRONICS SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] Although manganese dioxide is regarded as a potential capacitor electrode material, manganese dioxide has poor conductivity and has been replaced by some organic compounds with higher conductivity than manganese dioxide. The electrolyte resistance R has a great influence on the high frequency characteristics of the capacitor, therefore, it is necessary to use a higher conductivity electrolyte to increase the performance of the capacitor

Method used

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  • Solid tantalum electrolytic capacitor and manufacturing method thereof
  • Solid tantalum electrolytic capacitor and manufacturing method thereof
  • Solid tantalum electrolytic capacitor and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] based on figure 1 Be explained. Wherein, the conductive layer 3 is polyaniline doped with 1wt% composite carbon nanotubes, and the composite carbon nanotubes are multi-walled carbon nanotubes whose surface is uniformly attached with nanoparticles having a shell core structure with a diameter of 30 nm. The core-structured nanoparticles are 10-nm-diameter magnetic Fe 3 o 4 The particles are nanoparticles whose core surface is coated with carbon black, and the length of the multi-walled carbon nanotubes is 20 μm.

[0041] The preparation method is as follows:

[0042] ① Press nano-tantalum metal particles into blocks, plant cylindrical tantalum wires in the formation of tantalum particles, and sinter them into porous tantalum anode bodies under high temperature and vacuum conditions;

[0043] ② Anodize the sintered tantalum anode body to form a layer of Ta on its surface 2 o 5 Dielectric coating;

[0044] ③ Evenly disperse the composite carbon nanotubes in the mixed...

Embodiment 2

[0053] The conductive layer 3 is polythiophene doped with 5wt% composite carbon nanotubes, the composite carbon nanotubes are multi-walled carbon nanotubes with a diameter of 40nm and nanoparticles with a core-shell structure uniformly attached to the surface, wherein the composite carbon nanotubes have a core-shell structure The nanoparticles are magnetic Fe with a diameter of 25 nm 3 o 4 The particles are nanoparticles whose core surface is coated with a gold shell layer, and the length of the multi-walled carbon nanotubes is 30 μm.

[0054] The preparation method is as follows:

[0055] ① Press nano-tantalum metal particles into blocks, plant cylindrical tantalum wires in the formation of tantalum particles, and sinter them into porous tantalum anode bodies under high temperature and vacuum conditions;

[0056] ② Anodize the sintered tantalum anode body to form a layer of Ta on its surface 2 o 5 Dielectric coating;

[0057] ③ Evenly disperse the composite carbon nanotu...

Embodiment 3

[0062] The conductive layer 3 is polypyrrole doped with 10wt% composite carbon nanotubes, the composite carbon nanotubes are single-walled carbon nanotubes with a diameter of 60nm and nanoparticles with a core-shell structure uniformly attached to the surface, wherein the composite carbon nanotubes have a core-shell structure The nanoparticle is a nanoparticle with a magnetic nickel particle with a diameter of 30nm as the core and a copper shell layer on the surface, and the length of the single-walled carbon nanotube is 40μm.

[0063] The preparation method is as follows:

[0064] ① Press nano-tantalum metal particles into blocks, plant cylindrical tantalum wires in the formation of tantalum particles, and sinter them into porous tantalum anode bodies under high temperature and vacuum conditions;

[0065] ② Anodize the sintered tantalum anode body to form a layer of Ta on its surface 2 o 5 Dielectric coating;

[0066] ③ Evenly disperse the composite carbon nanotubes in the...

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Abstract

The invention discloses a solid tantalum electrolytic capacitor comprising a tantalum anode body, an Ta2O5 dielectric envelope, a conducting layer, a graphite layer and a silver coating, wherein the Ta2O5 dielectric envelope is positioned on the surface of the tantalum anode body, the conducting layer is positioned on the Ra2O5 dielectric envelope, and the graphite layer and the silver coating are coated on the conducting layer. The solid tantalum electrolytic capacitor is characterized in that the conducting layer is a mixed system of composite carbon nano tubes and high-polymer conducting materials, the length directions of the composite carbon nano tubes are perpendicular to the surface of the tantalum anode body, the composite carbon nano tubes are carbon nano tubes with the surfaces uniformly attached with nano particles in a shell-core structure, and the nano particles in the shell-core structure are nano particles using magnetic nano particles as cores, wherein the surfaces of the nano particles are coated with conducting shell layers. Because the directionally arranged composite carbon nano tubes are adopted in the conducting layer, the conductivity of the conducting layer is increased, and the equivalent series resistance of the capacitor is reduced, thereby the high-frequency characteristic of the capacitor is improved.

Description

technical field [0001] The invention relates to the technical field of capacitors, in particular to a solid tantalum electrolytic capacitor and a preparation method thereof. Background technique [0002] In recent years, with the downsizing and weight reduction of electronic devices, small and high-capacity high-frequency capacitors are required, so solid electrolytic capacitors in which a solid electrolytic layer is formed of a solid conductive compound have been proposed. [0003] A solid electrolytic capacitor includes, for example, an Al (aluminum) or Ta (tantalum) metal anode body, a dielectric oxide film formed by oxidation treatment on the surface of the anode body, and a solid conductive compound such as MnO 2 (manganese dioxide), conductive high molecular polymer to the oxide film, and the cathode layer in close contact with the oxide film. Compared with paper dielectric capacitors and film capacitors, electrolytic capacitors are smaller in size and higher in capac...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01G9/15H01G9/025H01G9/028
Inventor 于军胜邢国秀崔立强蒋亚东
Owner UNIV OF ELECTRONICS SCI & TECH OF CHINA
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