Chromium-niobium-boron alloy rare earth casting grinding ball and production process method thereof

A technology for casting grinding balls and production processes, applied in the field of metal grinding media, can solve the problems of increasing the manufacturing cost of grinding ball products, difficult to master micro-alloying technology, and reducing the amount of chromium used, and achieves grain refinement and dense organization. , the effect of improving toughness

Active Publication Date: 2011-08-17
安徽省凤形新材料科技有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0007] However, the above two patents still have certain limitations in production practice. First, although the amount of chromium used is reduced (the chromium content of superhard high-chromium grinding balls is less than or equal to 10%, high-carbon multi-element alloy casting The chromium element content of the grinding ball is less than or equal to 6%
), but still need to add a small amount of rare and precious metal elements such as

Method used

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  • Chromium-niobium-boron alloy rare earth casting grinding ball and production process method thereof

Examples

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Effect test

Embodiment 1

[0041] Specification ? 25mm chromium-niobium-boron alloy rare earth cast grinding ball, its chemical composition is as follows:

[0042] Carbon (C): 2.63 % Silicon (Si): 0.58 %, Manganese (Mn): 0.38 %,

[0043] Chromium (Cr): 4.32%, Phosphorus (P): 0.064%, Sulfur (S): 0.055%;

[0044] Niobium (Nb): 0.055%, Boron (B): 0.12%, Compound Rare Earth Modifier (Re): 0.18%,

[0045] Iron (Fe): 91.39%.

[0046] The manufacturing process of ?25mm chromium-niobium-boron alloy rare earth casting grinding ball is as follows:

[0047] The main raw material used is scrap steel. According to the above formula, the scrap steel is first melted in an intermediate frequency induction furnace, and the temperature is raised to 1480-1520°C, and then chromium (Cr), silicon (Si), manganese (Mn), niobium (Nb), boron ( B) The alloy reaches the required chemical composition. Then put the massive composite rare earth modifier into the molten iron ladle, melt it with molten iron and let it stand for 4 m...

Embodiment 2

[0053] The chemical composition of 60mm chromium-niobium-boron alloy rare earth casting grinding balls is as follows:

[0054] Carbon (C): 1.81%, Silicon (Si): 0.62%, Manganese (Mn): 0.65%,

[0055] Chromium (Cr): 6.32%, Phosphorus (P): 0.059%, Sulfur (S): 0.058%;

[0056] Niobium (Nb): 0.058%, Boron (B): 0.11%, Compound Rare Earth Modifier (Re): 0.2%,

[0057] Iron (Fe): 90.12%.

[0058] The manufacturing process of ?60mm chromium-niobium-boron alloy rare earth casting grinding ball is as follows:

[0059] According to the recipe, the scrap steel is first melted in an intermediate frequency induction furnace, and the temperature is raised to 1480-1520°C, and then chromium (Cr), silicon (Si), manganese (Mn), niobium (Nb), and boron (B) alloys are added to achieve the desired temperature. required chemical composition. Then put the composite heavy rare earth modifier into the molten iron ladle, melt it with molten iron and let it stand for 5 minutes to carry out modificatio...

Embodiment 3

[0065] The chemical composition of 90mm chromium-niobium-boron alloy rare earth casting grinding balls is as follows:

[0066] Carbon (C): 1.52%, Silicon (Si): 0.68%, Manganese (Mn): 0.72%,

[0067] Chromium (Cr): 7.1%, Phosphorus (P): 0.058%, Sulfur (S): 0.055%;

[0068] Niobium (Nb): 0.060%, Boron (B): 0.13%, Compound Rare Earth Modifier (Re): 0.25%,

[0069] Iron (Fe): 89.43%.

[0070] The manufacturing process of 90mm chromium-niobium-boron alloy rare earth casting grinding ball is as follows:

[0071] According to the formula, the steel scrap is first melted in an intermediate frequency induction furnace, and the temperature is raised to 1510-1560°C, and then chromium (Cr), silicon (Si), manganese (Mn), niobium (Nb), and boron (B) alloys are added to achieve the desired temperature. required chemical composition. Then put the composite heavy rare earth modifier into the molten iron ladle, melt it with molten iron and let it stand for 5 minutes to carry out modificatio...

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Abstract

The invention relates to a chromium-niobium-boron alloy rare earth casting grinding ball and a preparation method thereof. The casting grinding ball comprises the following chemical components in percentage by weight: 1.3 to 3.0 percent of carbon, 0.3 to 1.2 percent of silicon, 0.2 to 1.0 percent of manganese, 4.0 to 7.5 percent of chromium, 0.03 to 0.10 percent of niobium, 0.01 to 0.2 percent of boron, less than or equal to 0.10 percent of phosphorus, less than or equal to 0.10 percent of sulphur, 0.15 to 0.3 percent of composite rare earth leavening agent and 86.5 to 93.81 percent of iron. The method comprises the following production operation steps of: smelting, casting, performing heat treatment, and performing mechanical property detection and whipping detection, wherein the heat treatment comprises austenization treatment, oil quenching treatment and low-temperature tempering treatment. The austenization treatment comprises the following four stages that: the temperature of the first stage is 350 DEG C and is kept for 2 hours; the temperature of the second stage is 550 DEG C and is kept for 2 hours; the temperature of the third stage is 800 DEG C and is kept for 2.5 hours; and the temperature of the fourth stage is between 930 and 980 DEG C and is kept for 2.5 hours, wherein the quenching oil temperature is between 50 and 140 DEG C; the quenching time is between 6 and 20 minutes; the low-temperature tempering temperature is between 210 and 280 DEG C; and the tempering time is 8 hours. The hardness of the grinding ball reaches HRc 60 to 64, and the impact toughness is higher than 4 J/cm<2>. The manufacturing cost of the grinding ball is further lowered without the usage of rare and precious metal elements such as molybdenum, nickel, copper, titanium, vanadium, copper and the like.

Description

technical field [0001] The invention relates to a metal grinding medium widely used in powder engineering in metallurgical mines, thermal power energy, building materials, cement, engineering machinery and other industries, namely a chromium-niobium-boron alloy rare earth cast grinding ball and a production process thereof. Background technique [0002] As a grinding medium, grinding balls are widely used in powder engineering in industries such as mining metallurgy, energy thermal power, non-metal processing, building materials, cement, coal-water slurry, and magnetic materials. Due to the need to meet the requirements of different equipment and different working conditions in various industries, the materials for manufacturing grinding balls are various, such as forged steel balls, nodular cast iron grinding balls, chromium alloy casting grinding balls, etc., and the specifications also range from ?6mm to ?150mm. even larger diameters. [0003] Chromium alloy cast grindin...

Claims

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Application Information

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IPC IPC(8): C22C38/60C22C38/36C22C38/32C22C37/10C21D1/18C21D9/00
Inventor 陈宗明陈晓沈茂林冯继林
Owner 安徽省凤形新材料科技有限公司
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