Method for realizing shortcut nitration of high ammonia nitrogen wastewater

A short-range nitrification and high-ammonia-nitrogen technology, which is applied in the treatment of high-ammonia-nitrogen wastewater and is stably maintained in the field of high-ammonia-nitrogen wastewater treatment by short-range nitrification, can solve the problem of unrealistic FA concentration control in sewage treatment plants, rare successful applications of biological denitrification, and DO. Concentration is difficult to control stably, etc., to achieve long-term stable nitrosation capacity, reduced control accuracy requirements, and a wide range of applicable conditions.

A short-range nitrification and high-ammonia-nitrogen technology, which is applied in the treatment of high-ammonia-nitrogen wastewater and is stably maintained in the field of high-ammonia-nitrogen wastewater treatment by short-range nitrification, can solve the problem of unrealistic FA concentration control in sewage treatment plants, rare successful applications of biological denitrification, and DO. Concentration is difficult to control stably, etc., to achieve long-term stable nitrosation capacity, reduced control accuracy requirements, and a wide range of applicable conditions.

CN102311166AActive Publication Date: 2012-01-11CHINA PETROLEUM & CHEM CORP +1

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] The first stage of flora cultivation: the enrichment of nitrifying flora, the composition of the enrichment medium used is (NH 4 ) 2 SO 4 (NH 4 + -N initial concentration is 150mg / L, final concentration is 1000mg / L), FeSO 4 ·7H 2 O(Fe 2 + Concentration is 12mg / L), MgSO 4 ·7H 2 O(Mg 2+ Concentration is 18mg / L), NaCl(Na + Concentration is 800mg / L), CaCl 2 (Ca 2+ Concentration is 16mg / L) and KH 2 PO 4 (K + Concentration is 260mg / L). During the enrichment process, NaHCO 3 The solution adjusts the pH. Culture conditions: temperature 24°C; pH 6.0-7.5; SV 15%-20%; DO 4mg L -1 . One cycle per day, the water intake time is 20 minutes, the aeration is 23 hours, the natural settlement is 30 minutes, and the supernatant is removed. Then add the enriched culture solution with the same volume as the supernatant, and operate in a cycle according to this process. During the process, the ammonia nitrogen concentration in the water is detected by the distillation titr...

Embodiment 2

[0031] The first stage of flora cultivation: the enrichment of nitrifying flora, the composition of the enrichment medium used is (NH 4 ) 2 SO 4 (NH 4 + -Initial concentration 150mg / L, final concentration 1000mg / L), FeSO 4 ·7H 2 O(Fe 2 + Concentration is 12mg / L), MgSO 4 ·7H 2 O(Mg 2+ Concentration is 18mg / L), NaCl(Na + Concentration is 800mg / L), CaCl 2 (Ca 2+ Concentration is 16mg / L) and KH 2 PO 4 (K + Concentration is 260mg / L). During the enrichment process, NaHCO 3 The solution adjusts the pH. Culture conditions: temperature 24°C; pH 6.0-7.5; SV 15%-20%; DO 4mg L -1 . One cycle per day, the water intake time is 20 minutes, the aeration is 23 hours, the natural settlement is 30 minutes, and the supernatant is removed. Then add the enriched culture solution with the same volume as the supernatant, and operate in a cycle according to this process. During the process, the ammonia nitrogen concentration in the water is detected by the distillation titration me...

Embodiment 3

[0036] The first stage of flora cultivation: the enrichment of nitrifying flora, the composition of the enrichment medium used is (NH 4 ) 2 SO 4 (NH 4 + -Initial concentration 150mg / L, final concentration 1000mg / L), FeSO 4 ·7H 2 O(Fe 2 + Concentration is 12mg / L), MgSO 4 ·7H 2 O(Mg 2+ Concentration is 18mg / L), NaCl(Na + Concentration is 800mg / L), CaCl 2 (Ca 2+ Concentration is 16mg / L) and KH 2 PO 4 (K + Concentration is 260mg / L). During the enrichment process, NaHCO 3 The solution adjusts the pH. Culture conditions: temperature 24°C; pH 6.0-7.5; SV 15%-20%; DO 4mg L -1 . One cycle per day, the water intake time is 20 minutes, the aeration is 23 hours, the natural settlement is 30 minutes, and the supernatant is removed. Then add the enriched culture solution with the same volume as the supernatant, and operate in a cycle according to this process. During the process, the ammonia nitrogen concentration in the water is detected by the distillation titration me...

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Abstract

The invention discloses a method for realizing shortcut nitration of high ammonia nitrogen wastewater. The method comprises the following steps of: culturing nitrosation dominant flora; and performing ammonia sewage treatment by using the flora as an inoculum, namely adding the cultured nitrosation dominant flora into an aeration reactor to treat the ammonia wastewater, wherein the adding amount of the cultured nitrosation dominant flora accords with a condition that: sludge concentration is 800-2,000mg / L after the cultured nitrosation dominant flora is added; and the treatment conditions arethat: the temperature is 18-40DEG C, the dissolved oxygen is 0.1-3mg / L, and the pH is 7- 9. The unique nitrosation dominant flora culture method is adopted, stable and high-efficiency ammonia nitrogen wastewater treatment effect can be achieved, and the problem of instability of the shortcut nitration in actual application is solved.

Description

technical field [0001] The invention belongs to the technical field of environmental engineering wastewater biological treatment, and in particular relates to a treatment method mainly used for high ammonia nitrogen wastewater, in particular to a method for stably maintaining high ammonia nitrogen wastewater in short-range nitrification. Background technique [0002] The biological denitrification of wastewater mainly relies on the joint action of nitrifying bacteria and denitrifying bacteria in activated sludge, and finally converts various forms of nitrogen in sewage into gaseous nitrogen and escapes from the water. From the perspective of nitrification process, ammonia nitrogen (NH 3 -N) is oxidized to nitrite nitrogen (NO 2 -N) and nitrate nitrogen (NO 3 -N) are two different reactions performed by two separate types of bacteria, which should be separable. From the perspective of denitrification process, NO 2 -N and NO 3 -N can be used as the final electron acceptor...

Claims

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Application Information

Patent Timeline
11 Jan 2012
Publication
CN102311166A
IPC
C02F3/12; C02F3/34
CPC
Y02W10/10
Inventors
高会杰; 李志瑞