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Intelligent waterproof moisture-permeable film and preparation method thereof

A waterproof and moisture-permeable membrane and waterproof and moisture-permeable technology are applied in the field of preparation and modification of functional polymer materials, which can solve the problems of limited application fields, poor mechanical properties of membranes, damage to mechanical properties of polyurethane materials, etc. Improve performance, excellent waterproof and moisture permeability effect

Inactive Publication Date: 2012-07-25
宁波市江北成达色母粒有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] 1. Although the waterproof effect of pure TPU film is good, its moisture permeability is only 2000g / (m2)-1(24h)-1, and its application field is very limited
[0006] 2. The function of waterproof and moisture permeability is single, which cannot meet the requirements of use in all-weather and complex environments such as high temperature, low temperature, strong shear force field, etc.
[0007] 3. The mechanical properties of the membrane are poor and easy to break
[0008] 4. The waterproof and moisture permeability of the membrane is not uniform
[0009] 5. The waterproof and moisture-permeable membrane technology is mostly monopolized by large foreign companies such as Europe and the United States, and the price is expensive
[0010] It is precisely because of the awareness of the above defects that people often add some inorganic fillers such as calcium carbonate, talcum powder, barium sulfate, etc. in the actual use of polyurethane materials to achieve the purpose of reducing the cost of raw materials, but unfortunately such The amount of inorganic filler added is very limited
And when the added amount exceeds a certain value, the mechanical properties of the polyurethane material will be significantly damaged, which can no longer meet the use requirements of related fields.

Method used

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  • Intelligent waterproof moisture-permeable film and preparation method thereof
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  • Intelligent waterproof moisture-permeable film and preparation method thereof

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preparation example Construction

[0038] The present invention also provides a method for preparing an intelligent waterproof and moisture-permeable membrane, which includes the following steps:

[0039] a. Clean and dry the base material for later use;

[0040] b. Add the thermoplastic carrier material, inorganic nanoparticles with two-dimensional microporous or three-dimensional microporous structure, and processing aids to a high-speed mixer at room temperature in a ratio of 100:5-100:0.5-1 by mass. Stirring to obtain functional mixed materials;

[0041] c. The above-mentioned functional mixed material is extruded and granulated using an extruder at an extrusion temperature of 120°C-250°C by a melt blending method to obtain a waterproof and moisture-permeable functional material;

[0042] d. After the above-mentioned spare base material and the above-prepared waterproof and moisture-permeable functional material are uniformly mixed in a mass ratio of 100:5-200, use a single-screw extruder at an extrusion temperatur...

Embodiment 1

[0046] First, the polyamide 1010 of the base material is washed and dried for use.

[0047] Secondly, under normal temperature conditions, add 100g of polyether polyurethane, 50g of molecular sieve, 0.2g of polyethylene wax, 0.1g of calcium stearate, 0.05g of antioxidant 1010 and 0.05g of diphenyl phosphite in a high-speed mixer. After mixing uniformly with the mixer at 1000r / min to obtain the functional mixed material, the parallel twin-screw extruder is used to extrude and granulate the obtained functional mixed material at the extrusion temperature of 180°C to obtain the waterproof and moisture-permeable function. material.

[0048] Then, according to the mass ratio of 100:30, the above-mentioned dried polyamide 1010 and the prepared waterproof and moisture-permeable functional material are put into the barrel of the up-blowing single-screw extruder, and the polyamide 1010 is formed at 230°C. Ether polyurethane is a polyamide-based waterproof and moisture-permeable membrane mad...

Embodiment 2

[0052] First, the polyether polyurethane matrix material is selected for use after cleaning and drying.

[0053] Secondly, under normal temperature, add 100g polyether glycol terephthalate, 10g nano-SiO2, 90g nano-Al2O3, 0.3g polyethylene wax, 0.3g calcium stearate, and 0.1g antioxidant in a high-speed mixer. 1010 and 0.05g of diphenyl phosphite, mixed uniformly under the condition of 1000r / min in a mixer to obtain the functional mixed material, and then use the parallel twin-screw extruder to extrude the obtained functional mixed material at 210℃. , Prepared waterproof and moisture-permeable functional materials.

[0054] Then put the above-mentioned dried polyether polyurethane base material and the above-prepared waterproof and moisture-permeable functional material into the barrel of the up-blowing single-screw extruder according to the mass ratio of 100:100, and shape it at 220°C It is a polyurethane-based waterproof and moisture-permeable membrane using polyether glycol tere...

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Abstract

The invention discloses an intelligent waterproof moisture-permeable film. A matrix material and a waterproof moisture-permeable functional material are prepared into the waterproof moisture-permeable film by using a screw extruder in a film blowing method or a flow casting method. The preparation method comprises the following steps of: firstly cleaning and drying the matrix material for standby application; secondly, squeezing out a thermoplastic carrier material, inorganic nanometer particles and a processing agent at a certain extrusion temperature by using the extruder in a melt mixing method according to a certain mass ratio to prepare the waterproof moisture-permeable functional material; and finally, preparing the product by adopting the film blowing method or the flow casting method at the extrusion temperature condition of 120 DEG C-250 DEG C after mixing the matrix material and the prepared waterproof moisture-permeable functional material according to a mass ratio of 100:5-200. The intelligent waterproof moisture-permeable film has excellent waterproof moisture-permeable function in all weathers, i.e. a preferential temperature and a humidity range and has the characteristics of simple production technology, low cost of raw materials and high production efficiency.

Description

Technical field [0001] The invention relates to the technical field of preparation and modification of functional polymer materials, in particular to a waterproof and moisture-permeable membrane, in particular to an intelligent waterproof and moisture-permeable membrane and a preparation method thereof. Background technique [0002] At present, most of the waterproof and moisture-permeable materials with relatively good performance on the market are mainly thermoplastic polyurethane. Polyurethane (PU) is a macromolecular material containing urethane groups in its molecular chain. According to whether the molecular chain is cross-linked or not, it can be divided into thermoplastic polyurethane (TPU) and cross-linked polyurethane (CPU). Generally speaking, polyurethane is mainly obtained by the gradual addition polymerization of polyols, isocyanates and small molecule chain extenders. By controlling the molar ratio of isocyanate and hydroxyl, functional polymer materials with exce...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/00C08L77/02C08L77/06C08L75/04C08L75/06C08L75/08C08L67/00C08L67/02C08K7/24C08K7/26
Inventor 张建银杨晓鹏杨积位
Owner 宁波市江北成达色母粒有限公司
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