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Preparation method of flexible force sensitive sensor

A technology of sensor and flexible force, which is applied in the field of flexible force-sensitive sensor of dendritic coaxial nanostructure conductive polyaniline fiber, which can solve the problem of difficult processing and application of polyaniline micro-nano composite fiber for force-sensitive sensor, difficult processing and molding, etc. problem, to achieve the effect of unbreakable, short response time and low cost

Inactive Publication Date: 2012-09-26
QINGDAO UNIV
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  • Abstract
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  • Claims
  • Application Information

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Problems solved by technology

However, there is no precedent for the use of polyaniline micro-nano composite fibers to prepare force-sensitive sensors.
At the same time, polyaniline also has the disadvantages of high melting point, insoluble, difficult processing and molding of most conductive polymer materials, and is not easy to process and apply.

Method used

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  • Preparation method of flexible force sensitive sensor
  • Preparation method of flexible force sensitive sensor
  • Preparation method of flexible force sensitive sensor

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Embodiment

[0017] This embodiment includes three specific steps of preparing dendritic nanostructured polyaniline coaxial ordered fibers, preparation of a force-sensitive sensor and application of a force-sensitive sensor:

[0018] (1) Preparation of polyaniline coaxial ordered fibers with dendritic nanostructure: Firstly, polyvinylidene fluoride (PVDF) nano ordered fibers were prepared by electrospinning method using a conventional electrospinning device; the prepared mass percentage was 22% PVDF spinning solution, wherein the molecular weight is 250,000 PVDF2.2 grams, 3.8 grams of acetone, 3.8 grams of dimethylformamide, stirred at a constant temperature of 60 ° C for 5 hours to prepare the spinning solution; adjust the emission of the electrospinning device The distance between the pole (needle, inner diameter 0.6 mm) and the receiving pole (steel shaft of the rotating drum) is 10 cm, the spinning voltage is 10 to 14 kV, and the drum speed is 600 rpm; the PVDF nanometer prepared by ele...

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Abstract

The invention belongs to the technical field of sensor preparation and relates to a preparation method of a flexible force sensitive sensor. According to the preparation method, an electrostatic spinning method is firstly adopted for preparing dendritic nanometer structure polyaniline coaxial ordered fibers of insulated high molecular materials of polyvinylidene fluoride (PVDF), PVDF fibers are used as reaction templates to be soaked into polyaniline reaction solution, a conducting polyaniline wrapping layer is formed on the surface of the PVDF fibers by an in-situ polymerization method in a wrapping form, the surface of the conducting polyaniline wrapping layer is subjected to self assembly to form a dendritic nanometer structure through controlling the reaction time, the polymerization temperature and the mol ratio of aniline monomers to doping agents, and coaxial structure polyaniline fibers with larger specific surface are obtained; then, the prepared coaxial structure polyaniline fibers are fixed on a bent plastic film, electrodes are prepared, protecting films are covered and are connected into a constant voltage circuit, and the flexible force sensitive sensor of the nanometer structure conducting polyaniline coaxial ordered fibers is prepared. The preparation method has the advantages that the preparation method is simple and convenient, in addition, the cost is low, the sensor structure is simple, the temperature influence is small, the mechanical property is good, the cracking is avoided, the sensitivity is high, and the response time is short.

Description

Technical field: [0001] The invention belongs to the technical field of sensor preparation, and relates to a method for preparing a flexible force-sensitive sensor, in particular to a method for preparing a dendritic coaxial nanostructure conductive polyaniline fiber flexible force-sensitive sensor by means of electrospinning and in-situ polymerization . Background technique: [0002] The force sensor is a sensing device that detects the interaction force between gases, solids, liquids and other substances. The commonly used materials include semiconductors, metals and synthetic materials. According to the working principle, it is divided into resistance strain sensor, inductive force sensor, capacitor Type force sensor, resonant force sensor, etc. There are various forms of force sensors in the disclosed technology. For example, Chinese patent (application number 01124284.1) discloses a new type of full silicon nitride microstructure resonant beam pressure sensor ; Patent ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01L1/18
Inventor 龙云泽黄蓉唐成春张红娣孙彬徐盛王文修常清
Owner QINGDAO UNIV
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